Förster valley-orbit coupling and topological lattice of hybrid moiré excitons

Abstract Hybrid excitons in moiré superlattices of two-dimensional (2D) semiconductors inherit the electric dipole, strong moiré trapping, and stacking optical selection rules from its interlayer part, whereas the intralayer part is intended for enhancing optical coupling strength. Here, we show tha...

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Main Authors: Huiyuan Zheng, Ci Li, Hongyi Yu, Wang Yao
Format: Article
Language:English
Published: Nature Portfolio 2025-05-01
Series:Communications Physics
Online Access:https://doi.org/10.1038/s42005-025-02114-0
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author Huiyuan Zheng
Ci Li
Hongyi Yu
Wang Yao
author_facet Huiyuan Zheng
Ci Li
Hongyi Yu
Wang Yao
author_sort Huiyuan Zheng
collection DOAJ
description Abstract Hybrid excitons in moiré superlattices of two-dimensional (2D) semiconductors inherit the electric dipole, strong moiré trapping, and stacking optical selection rules from its interlayer part, whereas the intralayer part is intended for enhancing optical coupling strength. Here, we show that electron-hole Coulomb exchange, or Förster type multipole-multipole coupling, in the intralayer component qualitatively alters the properties of moiré excitons, enabling their coherent hopping between moiré traps laterally separated over 10 nm and/or across layers, where their kinetic propagation is completely suppressed. Valley-flip hopping channels are found as significant as the valley-conserving ones, leading to rich possibilities to tailor valley-orbit-couplings and introduce non-trivial topology to the moiré exciton superlattice. In twisted MoTe2 where hybrid moiré excitons feature a symmetry protection from radiative recombination, we show that Förster valley-orbit-coupling can give rise to a rich topological phase diagram.
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spelling doaj-art-d073f9b3b48d4489bea2983c51d624252025-08-20T01:49:44ZengNature PortfolioCommunications Physics2399-36502025-05-01811610.1038/s42005-025-02114-0Förster valley-orbit coupling and topological lattice of hybrid moiré excitonsHuiyuan Zheng0Ci Li1Hongyi Yu2Wang Yao3New Cornerstone Science Laboratory, Department of Physics, University of Hong KongSchool of Physics and Electronics, Hunan UniversitySchool of Physics and Astronomy, Sun Yat-sen University (Zhuhai Campus)New Cornerstone Science Laboratory, Department of Physics, University of Hong KongAbstract Hybrid excitons in moiré superlattices of two-dimensional (2D) semiconductors inherit the electric dipole, strong moiré trapping, and stacking optical selection rules from its interlayer part, whereas the intralayer part is intended for enhancing optical coupling strength. Here, we show that electron-hole Coulomb exchange, or Förster type multipole-multipole coupling, in the intralayer component qualitatively alters the properties of moiré excitons, enabling their coherent hopping between moiré traps laterally separated over 10 nm and/or across layers, where their kinetic propagation is completely suppressed. Valley-flip hopping channels are found as significant as the valley-conserving ones, leading to rich possibilities to tailor valley-orbit-couplings and introduce non-trivial topology to the moiré exciton superlattice. In twisted MoTe2 where hybrid moiré excitons feature a symmetry protection from radiative recombination, we show that Förster valley-orbit-coupling can give rise to a rich topological phase diagram.https://doi.org/10.1038/s42005-025-02114-0
spellingShingle Huiyuan Zheng
Ci Li
Hongyi Yu
Wang Yao
Förster valley-orbit coupling and topological lattice of hybrid moiré excitons
Communications Physics
title Förster valley-orbit coupling and topological lattice of hybrid moiré excitons
title_full Förster valley-orbit coupling and topological lattice of hybrid moiré excitons
title_fullStr Förster valley-orbit coupling and topological lattice of hybrid moiré excitons
title_full_unstemmed Förster valley-orbit coupling and topological lattice of hybrid moiré excitons
title_short Förster valley-orbit coupling and topological lattice of hybrid moiré excitons
title_sort forster valley orbit coupling and topological lattice of hybrid moire excitons
url https://doi.org/10.1038/s42005-025-02114-0
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