Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley Data
Oxytetracycline (OTC) is one of the most used broad-spectrum antibiotics for treating both humans and livestock infections. However, when improperly disposed of, OTC poses a significant risk to water bodies due to its inhibitory effect on water nitrification and its impact on the microbiota. Therefo...
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Elsevier
2025-06-01
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| Series: | Data in Brief |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2352340925003592 |
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| author | Kevin Jhon Fernández-Andrade Alex Ariel Fernández-Andrade Luis E. Arteaga-Pérez Joan Manuel Rodriguez-Diaz |
| author_facet | Kevin Jhon Fernández-Andrade Alex Ariel Fernández-Andrade Luis E. Arteaga-Pérez Joan Manuel Rodriguez-Diaz |
| author_sort | Kevin Jhon Fernández-Andrade |
| collection | DOAJ |
| description | Oxytetracycline (OTC) is one of the most used broad-spectrum antibiotics for treating both humans and livestock infections. However, when improperly disposed of, OTC poses a significant risk to water bodies due to its inhibitory effect on water nitrification and its impact on the microbiota. Therefore, various treatments are being investigated to find a sustainable solution for removing oxytetracycline from water. In this sense, adsorption and advanced oxidation processes (AOP) over structured catalytic materials have drawn great attention for their efficiency and selectivity. Important concerns regarding these technical applications are catalyst stability and the proper disposal of adsorbents or catalysts following treatment cycles. Moreover, the elucidation of the underlaying kinetic and thermodynamic mechanisms governing these processes are also of paramount importance for process design and optimization. Accordingly, here we provide a complete dataset on the synthesis and characterization of a novel MOF@Biomass layered hybrid (MIL-53(Al)@RH) for the removal of OTC from water bodies via adsorption and LED-driven photocatalysis. The MIL-53(Al)@RH was synthetized by a microwave-assisted solvothermal method enabling the in-situ hybridization of MIL-53(Al) on rice husk (RH) as a biomass support. The dataset contains information on the physicochemical properties of pristine materials (MIL-53(Al) and rice husk), MIL-53(Al)@RH, and a Carbon-Al obtained via pyrolysis of the saturated MIL-53(Al)@RH (after adsorption). Moreover, data on BATCH adsorption experiments and photocatalytic elimination of oxytetracycline with MIL-53(Al)@RH is also provided. Adsorption data include information on the effect of MIL-53(Al)@RH dosage, solution pH, and kinetics measurements at different initial concentrations of OTC. In addition, data on the photocatalytic activity of MIL-53(Al)@RH is included for different oxidant doses (H2O2), OTC concentrations using a Led-light source. |
| format | Article |
| id | doaj-art-d00d2b289dff453eab35d44c367ff79b |
| institution | DOAJ |
| issn | 2352-3409 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Data in Brief |
| spelling | doaj-art-d00d2b289dff453eab35d44c367ff79b2025-08-20T03:10:24ZengElsevierData in Brief2352-34092025-06-016011162810.1016/j.dib.2025.111628Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley DataKevin Jhon Fernández-Andrade0Alex Ariel Fernández-Andrade1Luis E. Arteaga-Pérez2Joan Manuel Rodriguez-Diaz3Facultad de Posgrado, Universidad Técnica de Manabí, Urbina Avenue and Che Guevara, 130105, Portoviejo, Ecuador; Laboratory of Gas Chromatography and Analytical Pyrolysis, Fac. of Engineering, Universidad del Bío-Bío, Concepción, Chile; Laboratorio de Análisis Químicos y Biotecnológicos, Instituto de Investigación, UTM, 130105, Portoviejo, EcuadorLaboratory of Thermal and Catalytic Processes (LPTC), Wood Engineering Department, University of Bío-Bío, Concepción, 4030000, ChileDepartment of Chemical Engineering, Faculty of Engineering, Universidad de Concepcion, Chile; Corresponding authors.Laboratorio de Análisis Químicos y Biotecnológicos, Instituto de Investigación, UTM, 130105, Portoviejo, Ecuador; Departamento de Procesos Químicos, Biotecnología y Alimentos, Facultad de Ingenierías y Ciencias Aplicadas, Universidad Técnica de Manabí, 130105, Portoviejo, Ecuador; Corresponding authors.Oxytetracycline (OTC) is one of the most used broad-spectrum antibiotics for treating both humans and livestock infections. However, when improperly disposed of, OTC poses a significant risk to water bodies due to its inhibitory effect on water nitrification and its impact on the microbiota. Therefore, various treatments are being investigated to find a sustainable solution for removing oxytetracycline from water. In this sense, adsorption and advanced oxidation processes (AOP) over structured catalytic materials have drawn great attention for their efficiency and selectivity. Important concerns regarding these technical applications are catalyst stability and the proper disposal of adsorbents or catalysts following treatment cycles. Moreover, the elucidation of the underlaying kinetic and thermodynamic mechanisms governing these processes are also of paramount importance for process design and optimization. Accordingly, here we provide a complete dataset on the synthesis and characterization of a novel MOF@Biomass layered hybrid (MIL-53(Al)@RH) for the removal of OTC from water bodies via adsorption and LED-driven photocatalysis. The MIL-53(Al)@RH was synthetized by a microwave-assisted solvothermal method enabling the in-situ hybridization of MIL-53(Al) on rice husk (RH) as a biomass support. The dataset contains information on the physicochemical properties of pristine materials (MIL-53(Al) and rice husk), MIL-53(Al)@RH, and a Carbon-Al obtained via pyrolysis of the saturated MIL-53(Al)@RH (after adsorption). Moreover, data on BATCH adsorption experiments and photocatalytic elimination of oxytetracycline with MIL-53(Al)@RH is also provided. Adsorption data include information on the effect of MIL-53(Al)@RH dosage, solution pH, and kinetics measurements at different initial concentrations of OTC. In addition, data on the photocatalytic activity of MIL-53(Al)@RH is included for different oxidant doses (H2O2), OTC concentrations using a Led-light source.http://www.sciencedirect.com/science/article/pii/S2352340925003592AntibioticsAdsorptionMetal-organic frameworkBiomass adsorbentEnvironmental photocatalysis |
| spellingShingle | Kevin Jhon Fernández-Andrade Alex Ariel Fernández-Andrade Luis E. Arteaga-Pérez Joan Manuel Rodriguez-Diaz Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley Data Data in Brief Antibiotics Adsorption Metal-organic framework Biomass adsorbent Environmental photocatalysis |
| title | Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley Data |
| title_full | Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley Data |
| title_fullStr | Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley Data |
| title_full_unstemmed | Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley Data |
| title_short | Dataset on the synthesis, characterization, and application of MIL-53(Al)@Biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysisMendeley Data |
| title_sort | dataset on the synthesis characterization and application of mil 53 al biomass hybrid for efficient oxytetracycline elimination via adsorption and photocatalysismendeley data |
| topic | Antibiotics Adsorption Metal-organic framework Biomass adsorbent Environmental photocatalysis |
| url | http://www.sciencedirect.com/science/article/pii/S2352340925003592 |
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