Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamide
The coordination compound EuL3Phen (where L– = N-{bis[methyl(phenyl)amino]phosphoryl}-benzenesulfoneamidate anion) has been synthesized and studied by laser-desorption and temperature-programmed mass spectrometry in the condensed phase and on the surface of a standard metal substrate. The temperatur...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Chuiko Institute of Surface Chemistry of NAS of Ukraine
2014-11-01
|
| Series: | Хімія, фізика та технологія поверхні |
| Subjects: | |
| Online Access: | https://cpts.com.ua/index.php/cpts/article/view/308 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849710096867655680 |
|---|---|
| author | O. V. Severinovskaya A. V. Mischanchuk V. A. Trush A. Yu. Prytula V. M. Amirkhanov V. A. Pokrovskiy |
| author_facet | O. V. Severinovskaya A. V. Mischanchuk V. A. Trush A. Yu. Prytula V. M. Amirkhanov V. A. Pokrovskiy |
| author_sort | O. V. Severinovskaya |
| collection | DOAJ |
| description | The coordination compound EuL3Phen (where L– = N-{bis[methyl(phenyl)amino]phosphoryl}-benzenesulfoneamidate anion) has been synthesized and studied by laser-desorption and temperature-programmed mass spectrometry in the condensed phase and on the surface of a standard metal substrate. The temperature dependence of the main mass spectrum components in the method of temperature-programmed desorption mass spectrometry (TPD MS) is defined and interpreted, components of the laser desorption/ionization (LDI) mass spectrum of the synthesized substance have been identified. A comparative analysis of mass spectra obtained by both methods for the studied coordination compound has been carried out. A possibility of both mass spectrometric methods using for the investigation of metal-containing polymer components is discussed. |
| format | Article |
| id | doaj-art-cffc0922bb114b48baa4842521e4e414 |
| institution | DOAJ |
| issn | 2079-1704 2518-1238 |
| language | English |
| publishDate | 2014-11-01 |
| publisher | Chuiko Institute of Surface Chemistry of NAS of Ukraine |
| record_format | Article |
| series | Хімія, фізика та технологія поверхні |
| spelling | doaj-art-cffc0922bb114b48baa4842521e4e4142025-08-20T03:15:03ZengChuiko Institute of Surface Chemistry of NAS of UkraineХімія, фізика та технологія поверхні2079-17042518-12382014-11-015410.15407/hftp05.04.467Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamideO. V. Severinovskaya0A. V. Mischanchuk1V. A. Trush2A. Yu. Prytula3V. M. Amirkhanov4V. A. Pokrovskiy5Chuiko Institute of Surface Chemistry of National Academy of Sciences of UkraineChuiko Institute of Surface Chemistry of National Academy of Sciences of UkraineTaras Shevchenko National University of KyivTaras Shevchenko National University of KyivTaras Shevchenko National University of KyivChuiko Institute of Surface Chemistry of National Academy of Sciences of UkraineThe coordination compound EuL3Phen (where L– = N-{bis[methyl(phenyl)amino]phosphoryl}-benzenesulfoneamidate anion) has been synthesized and studied by laser-desorption and temperature-programmed mass spectrometry in the condensed phase and on the surface of a standard metal substrate. The temperature dependence of the main mass spectrum components in the method of temperature-programmed desorption mass spectrometry (TPD MS) is defined and interpreted, components of the laser desorption/ionization (LDI) mass spectrum of the synthesized substance have been identified. A comparative analysis of mass spectra obtained by both methods for the studied coordination compound has been carried out. A possibility of both mass spectrometric methods using for the investigation of metal-containing polymer components is discussed.https://cpts.com.ua/index.php/cpts/article/view/308laser desorption/ionization (LDI MS)temperature-programmed desorption mass spectrometry (TPD MS)lanthanidesphosphorylic ligands |
| spellingShingle | O. V. Severinovskaya A. V. Mischanchuk V. A. Trush A. Yu. Prytula V. M. Amirkhanov V. A. Pokrovskiy Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamide Хімія, фізика та технологія поверхні laser desorption/ionization (LDI MS) temperature-programmed desorption mass spectrometry (TPD MS) lanthanides phosphorylic ligands |
| title | Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamide |
| title_full | Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamide |
| title_fullStr | Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamide |
| title_full_unstemmed | Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamide |
| title_short | Laser desorption/ionization (LDI MS) and thermoprogrammed desorption mass spectrometry (TPD MS) of Europium(III) coordination compound with n-{bis[methyl(Phenyl)amino]phosphorYl}-benzenesulfoneamide |
| title_sort | laser desorption ionization ldi ms and thermoprogrammed desorption mass spectrometry tpd ms of europium iii coordination compound with n bis methyl phenyl amino phosphoryl benzenesulfoneamide |
| topic | laser desorption/ionization (LDI MS) temperature-programmed desorption mass spectrometry (TPD MS) lanthanides phosphorylic ligands |
| url | https://cpts.com.ua/index.php/cpts/article/view/308 |
| work_keys_str_mv | AT ovseverinovskaya laserdesorptionionizationldimsandthermoprogrammeddesorptionmassspectrometrytpdmsofeuropiumiiicoordinationcompoundwithnbismethylphenylaminophosphorylbenzenesulfoneamide AT avmischanchuk laserdesorptionionizationldimsandthermoprogrammeddesorptionmassspectrometrytpdmsofeuropiumiiicoordinationcompoundwithnbismethylphenylaminophosphorylbenzenesulfoneamide AT vatrush laserdesorptionionizationldimsandthermoprogrammeddesorptionmassspectrometrytpdmsofeuropiumiiicoordinationcompoundwithnbismethylphenylaminophosphorylbenzenesulfoneamide AT ayuprytula laserdesorptionionizationldimsandthermoprogrammeddesorptionmassspectrometrytpdmsofeuropiumiiicoordinationcompoundwithnbismethylphenylaminophosphorylbenzenesulfoneamide AT vmamirkhanov laserdesorptionionizationldimsandthermoprogrammeddesorptionmassspectrometrytpdmsofeuropiumiiicoordinationcompoundwithnbismethylphenylaminophosphorylbenzenesulfoneamide AT vapokrovskiy laserdesorptionionizationldimsandthermoprogrammeddesorptionmassspectrometrytpdmsofeuropiumiiicoordinationcompoundwithnbismethylphenylaminophosphorylbenzenesulfoneamide |