Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based Composites

Oil well cement is a brittle material, which can not ensure the long-term sealing integrity of oil and gas wells when used in cementing operations directly. As a kind of polymer emulsion material, epoxy resin emulsion has a bright future for improving the properties of the cement slurry. Epoxy resin...

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Main Authors: Miao He, Jianjian Song, Mingbiao Xu, Lei He, Peng Xu
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2020/5344866
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author Miao He
Jianjian Song
Mingbiao Xu
Lei He
Peng Xu
author_facet Miao He
Jianjian Song
Mingbiao Xu
Lei He
Peng Xu
author_sort Miao He
collection DOAJ
description Oil well cement is a brittle material, which can not ensure the long-term sealing integrity of oil and gas wells when used in cementing operations directly. As a kind of polymer emulsion material, epoxy resin emulsion has a bright future for improving the properties of the cement slurry. Epoxy resin emulsion was added to oil well cement and its workability and mechanical properties were studied, the stress-strain behavior of cement samples was evaluated, and the microstructure was observed by scanning electron microscope (SEM) and X-ray diffraction (XRD). The results show the epoxy resin emulsion used in oil well cement will affect the fluidity, but the rheological property of cement slurry with different content of resin meets the construction requirements. The resin reduces the water loss of cement paste and has no adverse effect on the thickening time. The compressive strength of cement stone decreases with the increase in resin content. When the content of resin is 6%, the flexural strength and impact strength of the cement sample are the largest, and 50.7% and 20.2% higher than that of the specimen without resin, respectively, after curing for 28 days. Further comparison shows that epoxy resin emulsion can improve the mechanical properties of oil well cement better than styrene-butadiene rubber latex. Meanwhile, the resin obviously improves the deformability and decreases the elastic modulus of cement stone. Compared with pure cement, resin cement slurry has no extra hydration products, but the formation of hydrated calcium silicate is inhibited. The microstructure shows that the resin forms a polymer film in the cement matrix and interweaves with cement hydration products, thus improving the flexibility of cement paste.
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institution Kabale University
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publishDate 2020-01-01
publisher Wiley
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spelling doaj-art-cfe80133223046f09955e050d912252b2025-02-03T05:52:28ZengWileyAdvances in Civil Engineering1687-80861687-80942020-01-01202010.1155/2020/53448665344866Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based CompositesMiao He0Jianjian Song1Mingbiao Xu2Lei He3Peng Xu4School of Petroleum Engineering, Yangtze University, Wuhan 430100, ChinaSchool of Petroleum Engineering, Yangtze University, Wuhan 430100, ChinaSchool of Petroleum Engineering, Yangtze University, Wuhan 430100, ChinaEngineering Department of Dagang Oilfield, Tianjin 300280, ChinaSchool of Petroleum Engineering, Yangtze University, Wuhan 430100, ChinaOil well cement is a brittle material, which can not ensure the long-term sealing integrity of oil and gas wells when used in cementing operations directly. As a kind of polymer emulsion material, epoxy resin emulsion has a bright future for improving the properties of the cement slurry. Epoxy resin emulsion was added to oil well cement and its workability and mechanical properties were studied, the stress-strain behavior of cement samples was evaluated, and the microstructure was observed by scanning electron microscope (SEM) and X-ray diffraction (XRD). The results show the epoxy resin emulsion used in oil well cement will affect the fluidity, but the rheological property of cement slurry with different content of resin meets the construction requirements. The resin reduces the water loss of cement paste and has no adverse effect on the thickening time. The compressive strength of cement stone decreases with the increase in resin content. When the content of resin is 6%, the flexural strength and impact strength of the cement sample are the largest, and 50.7% and 20.2% higher than that of the specimen without resin, respectively, after curing for 28 days. Further comparison shows that epoxy resin emulsion can improve the mechanical properties of oil well cement better than styrene-butadiene rubber latex. Meanwhile, the resin obviously improves the deformability and decreases the elastic modulus of cement stone. Compared with pure cement, resin cement slurry has no extra hydration products, but the formation of hydrated calcium silicate is inhibited. The microstructure shows that the resin forms a polymer film in the cement matrix and interweaves with cement hydration products, thus improving the flexibility of cement paste.http://dx.doi.org/10.1155/2020/5344866
spellingShingle Miao He
Jianjian Song
Mingbiao Xu
Lei He
Peng Xu
Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based Composites
Advances in Civil Engineering
title Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based Composites
title_full Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based Composites
title_fullStr Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based Composites
title_full_unstemmed Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based Composites
title_short Effect of Epoxy Resin Emulsion on the Mechanical Properties of Oil Well Cement-Based Composites
title_sort effect of epoxy resin emulsion on the mechanical properties of oil well cement based composites
url http://dx.doi.org/10.1155/2020/5344866
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