PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURS

Acetylation is one of methods to alter the physicochemical properties of starch. This work aimed to investigate the effect of reaction time, glacial acetic acid/gadung flour (GAA/GF) mass ratio and pH on gadung (Dioscorea hispida dennst) flour acetylation at ambient temperature. The acetylation was...

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Main Authors: ANDRI C. KUMORO, RIZKA AMALIA, DIAH S. RETNOWATI, CATARINA S. BUDIYATI, RATNAWATI RATNAWATI
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2014-08-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
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Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201402&vol=2&aid=4143
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author ANDRI C. KUMORO
RIZKA AMALIA
DIAH S. RETNOWATI
CATARINA S. BUDIYATI
RATNAWATI RATNAWATI
author_facet ANDRI C. KUMORO
RIZKA AMALIA
DIAH S. RETNOWATI
CATARINA S. BUDIYATI
RATNAWATI RATNAWATI
author_sort ANDRI C. KUMORO
collection DOAJ
description Acetylation is one of methods to alter the physicochemical properties of starch. This work aimed to investigate the effect of reaction time, glacial acetic acid/gadung flour (GAA/GF) mass ratio and pH on gadung (Dioscorea hispida dennst) flour acetylation at ambient temperature. The acetylation was carried out by reacting gadung flour slurry with GAA under alkaline condition. The results show that degree of substitution and swelling power of the acetylated flours increased with reaction time, while the solubility was not affected by reaction time after 10 minutes acetylation. The GAA/GF mass ratio inversely affected the solubility of acetylated flour, but did not affect the swelling power and degree of substitution. Acetylation changed the structure, morphology and crystallinity of gadung flour starch granules. The swelling power and solubility of all acetylated flours obtained in this work were higher than the native one.
format Article
id doaj-art-cfbe79c07e154e3eaa69ea75465fe1e2
institution DOAJ
issn 1582-540X
1582-540X
language English
publishDate 2014-08-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
record_format Article
series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj-art-cfbe79c07e154e3eaa69ea75465fe1e22025-08-20T02:54:50ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2014-08-01152135148PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURSANDRI C. KUMORO0RIZKA AMALIA1DIAH S. RETNOWATI2CATARINA S. BUDIYATI3RATNAWATI RATNAWATI4Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Prof. H. Soedarto, SH Road-Tembalang, Semarang, 50275, Indonesia Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Prof. H. Soedarto, SH Road-Tembalang, Semarang, 50275, Indonesia Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Prof. H. Soedarto, SH Road-Tembalang, Semarang, 50275, Indonesia Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Prof. H. Soedarto, SH Road-Tembalang, Semarang, 50275, Indonesia Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Prof. H. Soedarto, SH Road-Tembalang, Semarang, 50275, Indonesia Acetylation is one of methods to alter the physicochemical properties of starch. This work aimed to investigate the effect of reaction time, glacial acetic acid/gadung flour (GAA/GF) mass ratio and pH on gadung (Dioscorea hispida dennst) flour acetylation at ambient temperature. The acetylation was carried out by reacting gadung flour slurry with GAA under alkaline condition. The results show that degree of substitution and swelling power of the acetylated flours increased with reaction time, while the solubility was not affected by reaction time after 10 minutes acetylation. The GAA/GF mass ratio inversely affected the solubility of acetylated flour, but did not affect the swelling power and degree of substitution. Acetylation changed the structure, morphology and crystallinity of gadung flour starch granules. The swelling power and solubility of all acetylated flours obtained in this work were higher than the native one.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201402&vol=2&aid=4143acetylationmorphologysolubilitystarchswelling power
spellingShingle ANDRI C. KUMORO
RIZKA AMALIA
DIAH S. RETNOWATI
CATARINA S. BUDIYATI
RATNAWATI RATNAWATI
PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURS
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
acetylation
morphology
solubility
starch
swelling power
title PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURS
title_full PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURS
title_fullStr PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURS
title_full_unstemmed PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURS
title_short PREPARATION AND PHYSICOCHEMICAL CHARACTERIZATION OF MODIFIED (ACETYLATED) GADUNG (DIOSCOREA HISPIDA DENNST) FLOURS
title_sort preparation and physicochemical characterization of modified acetylated gadung dioscorea hispida dennst flours
topic acetylation
morphology
solubility
starch
swelling power
url http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201402&vol=2&aid=4143
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