Extraction of Major Groundwater Ions from Total Dissolved Solids and Mineralization Using Artificial Neural Networks: A Case Study of the Aflou Syncline Region, Algeria
Global water demand due to population growth and agricultural development has led to widespread overexploitation of groundwater, particularly in semi-arid regions. The traditional hydrochemistry monitoring system still suffers from limited laboratory accessibility and high costs. This study aims to...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-04-01
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| Series: | Hydrology |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2306-5338/12/5/103 |
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| Summary: | Global water demand due to population growth and agricultural development has led to widespread overexploitation of groundwater, particularly in semi-arid regions. The traditional hydrochemistry monitoring system still suffers from limited laboratory accessibility and high costs. This study aims to predict the major ions of groundwater, including Ca<sup>2+</sup>, Mg<sup>2+</sup>, Na<sup>+</sup>, SO<sub>4</sub><sup>2−</sup>, Cl<sup>−</sup>, K<sup>+</sup>, HCO<sub>3</sub><sup>−</sup>, and NO<sub>3</sub><sup>−</sup>, utilizing two field-measurable parameters (i.e., total dissolved solids (TDS) and mineralization (MIN)) in the Aflou syncline region, Algeria. A multilayer perceptron (MLP) model optimized with Levenberg–Marquardt backpropagation (LMBP) provided the greatest predictive accuracy for the different ions of SO<sub>4</sub><sup>2−</sup>, Mg<sup>2+</sup>, Na<sup>+</sup>, Ca<sup>2+</sup>, and Cl<sup>−</sup> with R<sup>2</sup> = (0.842, 0.980, 0.759, 0.945, 0.895), RMSE = (53.660, 12.840, 14.960, 36.460, 30.530) (mg/L), and NSE = (0.840, 0.978, 0.754, 0.941, 0.892) in the testing phase, respectively. However, the predictive accuracy for the remaining ions of K<sup>+</sup>, HCO<sub>3</sub><sup>−</sup>, and NO<sub>3</sub><sup>−</sup> was supplied as R<sup>2</sup> = (0.045, 0.366, 0.004), RMSE = (6.480, 41.720, 40.460) (mg/L), and NSE = (0.003, 0.361, −0.933), respectively. The performance of our model (LMBP-MLP) was validated in adjacent and similar geological locations, including Aflou, Madna, and Ain Madhi. In addition, LMBP-MLP showed very promising results, with performance similar to that in the original research region. |
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| ISSN: | 2306-5338 |