Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) Starch

Sweet potato (Ipomoea batatas L.) is an underutilized tuber in Nigerian industries. Its starch has diverse culinary and non-food applications. In this study, locally sourced sweet potato starch was isolated and hydroxypropylated using propylene oxide. The percentage of hydroxypropyl groups added and...

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Main Authors: Ogundiran Abimbola Aina, Ayisat Temitayo Tijani, Olusegun Olafimihan Ogundiran, Oyesolape Basirat Akinsipo, Ali El Gamal, Talha Bin Emran, Mohamed Hefnawy
Format: Article
Language:English
Published: North Carolina State University 2025-06-01
Series:BioResources
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Online Access:https://ojs.bioresources.com/index.php/BRJ/article/view/24633
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author Ogundiran Abimbola Aina
Ayisat Temitayo Tijani
Olusegun Olafimihan Ogundiran
Oyesolape Basirat Akinsipo
Ali El Gamal
Talha Bin Emran
Mohamed Hefnawy
author_facet Ogundiran Abimbola Aina
Ayisat Temitayo Tijani
Olusegun Olafimihan Ogundiran
Oyesolape Basirat Akinsipo
Ali El Gamal
Talha Bin Emran
Mohamed Hefnawy
author_sort Ogundiran Abimbola Aina
collection DOAJ
description Sweet potato (Ipomoea batatas L.) is an underutilized tuber in Nigerian industries. Its starch has diverse culinary and non-food applications. In this study, locally sourced sweet potato starch was isolated and hydroxypropylated using propylene oxide. The percentage of hydroxypropyl groups added and the degree of substitution were determined. Functional groups and morphological characteristics of both native and modified starches were analyzed using FT-IR and scanning electron microscopy (SEM). Functional and pasting properties were also examined. The degree of substitution and hydroxypropyl content fell within acceptable food application limits. SEM showed that granule structure remained intact after surface modification. Hydroxypropylated starches exhibited higher swelling and solubility than native starch from 50 to 90 °C. Both properties increased with greater molar substitution. Hydroxypropylation reduced storage turbidity and syneresis. Peak viscosity increased, while pasting and peak temperatures decreased after modification. Hydroxypropylated starches also had lower setback values. These results indicate enhanced functional properties in modified starch. The modified starch showed industrial potential for use in confectioneries, salad cream, mayonnaise, as well as in roles such as texturizers, thickeners, stabilizers, fillers, flavor carriers, and ingredients in beverages and bakery products, all with energy-efficient processing advantages.
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institution Kabale University
issn 1930-2126
language English
publishDate 2025-06-01
publisher North Carolina State University
record_format Article
series BioResources
spelling doaj-art-cdf6072f5c2e43a385818a07b742592d2025-08-20T03:45:02ZengNorth Carolina State UniversityBioResources1930-21262025-06-01203678868042939Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) StarchOgundiran Abimbola Aina0Ayisat Temitayo Tijani1Olusegun Olafimihan Ogundiran2Oyesolape Basirat Akinsipo3Ali El Gamal4Talha Bin Emran5Mohamed Hefnawy6Department of Chemical Sciences, Tai solarin University of Education, Ijagun, Ogun State, NigeriaDepartment of Chemical Sciences, Tai solarin University of Education, Ijagun, Ogun State, NigeriaDepartment of Chemistry, Sikiru Adetona College of Education, Science and Technology, Ije-Omu, Ogun StateDepartment of Chemical Sciences, Tai solarin University of Education, Ijagun, Ogun State, NigeriaDepartment of Pharmacognosy, College of Pharmacy, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Pathology and Laboratory Medicine, Warren Alpert Medical School, Brown University, Providence, RI 02912, USA; Department of Pharmacy, Faculty of Health and Life Science, Daffodil International University, Dhaka 1207, BangladeshDepartment of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, Riyadh 11451, Saudi ArabiaSweet potato (Ipomoea batatas L.) is an underutilized tuber in Nigerian industries. Its starch has diverse culinary and non-food applications. In this study, locally sourced sweet potato starch was isolated and hydroxypropylated using propylene oxide. The percentage of hydroxypropyl groups added and the degree of substitution were determined. Functional groups and morphological characteristics of both native and modified starches were analyzed using FT-IR and scanning electron microscopy (SEM). Functional and pasting properties were also examined. The degree of substitution and hydroxypropyl content fell within acceptable food application limits. SEM showed that granule structure remained intact after surface modification. Hydroxypropylated starches exhibited higher swelling and solubility than native starch from 50 to 90 °C. Both properties increased with greater molar substitution. Hydroxypropylation reduced storage turbidity and syneresis. Peak viscosity increased, while pasting and peak temperatures decreased after modification. Hydroxypropylated starches also had lower setback values. These results indicate enhanced functional properties in modified starch. The modified starch showed industrial potential for use in confectioneries, salad cream, mayonnaise, as well as in roles such as texturizers, thickeners, stabilizers, fillers, flavor carriers, and ingredients in beverages and bakery products, all with energy-efficient processing advantages.https://ojs.bioresources.com/index.php/BRJ/article/view/24633hydroxypropylationpasting propertiessweet potatostarchviscosity
spellingShingle Ogundiran Abimbola Aina
Ayisat Temitayo Tijani
Olusegun Olafimihan Ogundiran
Oyesolape Basirat Akinsipo
Ali El Gamal
Talha Bin Emran
Mohamed Hefnawy
Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) Starch
BioResources
hydroxypropylation
pasting properties
sweet potato
starch
viscosity
title Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) Starch
title_full Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) Starch
title_fullStr Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) Starch
title_full_unstemmed Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) Starch
title_short Preparation and Functional Properties of Hydroxy-propylated Sweet Potato (Ipomoea batatas L.) Starch
title_sort preparation and functional properties of hydroxy propylated sweet potato ipomoea batatas l starch
topic hydroxypropylation
pasting properties
sweet potato
starch
viscosity
url https://ojs.bioresources.com/index.php/BRJ/article/view/24633
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