Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodology
Two new bio-adsorbents were successfully synthesized by doping method with zinc chloride salt (ZnCl2) of raw artichoke leaves (RAL) and raw orange peels waste (ROP). Different analysis techniques (i.e. BET, SEM, XRD, FTIR) were used for characterizing the synthesized materials. Ketoprofen (KTF) nons...
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Elsevier
2024-01-01
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| Series: | Desalination and Water Treatment |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S194439862400225X |
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| author | Amel Khalfaoui Abderrezzaq Benalia Zakaria Laggoun Raouf Bouchareb Imane Zaamta Rania Melloul Amina Menasria Slimane Merouani Antonio Pizzi Kerroum Derbal |
| author_facet | Amel Khalfaoui Abderrezzaq Benalia Zakaria Laggoun Raouf Bouchareb Imane Zaamta Rania Melloul Amina Menasria Slimane Merouani Antonio Pizzi Kerroum Derbal |
| author_sort | Amel Khalfaoui |
| collection | DOAJ |
| description | Two new bio-adsorbents were successfully synthesized by doping method with zinc chloride salt (ZnCl2) of raw artichoke leaves (RAL) and raw orange peels waste (ROP). Different analysis techniques (i.e. BET, SEM, XRD, FTIR) were used for characterizing the synthesized materials. Ketoprofen (KTF) nonsteroidal anti-inflammatory drug was effectively removed from water using the synthesized bio-adsorbents, under different operating conditions. The specific surface areas increased from 1009.960 and 997.816 m2/g for ROP and RAL natural materials, respectively, to 1511.278 and 3415.951 m2/g for ROP- and RAL-doped materials. More interestingly, maximum Ketoprofen removals of 90% and 96% were obtained using ROP- and RAL-doped bio-adsorbents, against null removal for natural ROP and RAL materials. The kinetic study shows that the pseudo-second order model simulated adequately the obtained Ketoprofen removal data with R2 superior to 99%. A DOE based on (23) full factorial design was used to evaluate the effect of pH, bio-adsorbent dosage and initial KTF concentration on Ketoprofen removal efficiency. The optimum conditions for KTF removal with both the activated wastes were pH= 2, bio-adsorbent dose of 0.1 g/L and C0,KTF= 5 mg/L with removal efficiency of 98.14% for ROP-ZnCl2, and pH= 2, bio-adsorbent dose of 0.3 g/L and C0,KTF = 20 mg/L with a removal efficiency of 99.84% for RAL-ZnCl2 bio-sorbent. |
| format | Article |
| id | doaj-art-cde44d5de0c74de4ae174b3092395834 |
| institution | DOAJ |
| issn | 1944-3986 |
| language | English |
| publishDate | 2024-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Desalination and Water Treatment |
| spelling | doaj-art-cde44d5de0c74de4ae174b30923958342025-08-20T03:12:47ZengElsevierDesalination and Water Treatment1944-39862024-01-0131710019710.1016/j.dwt.2024.100197Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodologyAmel Khalfaoui0Abderrezzaq Benalia1Zakaria Laggoun2Raouf Bouchareb3Imane Zaamta4Rania Melloul5Amina Menasria6Slimane Merouani7Antonio Pizzi8Kerroum Derbal9Laboratory of Environmental Process Engineering, Faculty of Process Engineering, University Salah Boubnider Constantine 3, P.O. Box 72, 25000 Constantine, AlgeriaLaboratory of Process Engineering for Sustainable Development and Health Products (GPDDPS), National Polytechnic School of Constantine, Department of Process Engineering, Constantine, Algeria; Higher Normal School of Constantine, Constantine 25000, AlgeriaLaboratory of Environmental Process Engineering, Faculty of Process Engineering, University Salah Boubnider Constantine 3, P.O. Box 72, 25000 Constantine, AlgeriaLaboratory of Process Engineering for Sustainable Development and Health Products (GPDDPS), National Polytechnic School of Constantine, Department of Process Engineering, Constantine, AlgeriaLaboratory of Process Engineering for Sustainable Development and Health Products (GPDDPS), National Polytechnic School of Constantine, Department of Process Engineering, Constantine, AlgeriaLaboratory of Environmental Process Engineering, Faculty of Process Engineering, University Salah Boubnider Constantine 3, P.O. Box 72, 25000 Constantine, AlgeriaLaboratory of Process Engineering for Sustainable Development and Health Products (GPDDPS), National Polytechnic School of Constantine, Department of Process Engineering, Constantine, AlgeriaLaboratory of Environmental Process Engineering, Faculty of Process Engineering, University Salah Boubnider Constantine 3, P.O. Box 72, 25000 Constantine, AlgeriaLaboratoire d′Etude et Recherche sur le Matériau Bois (LERMAB). Ecole Nationale Supérieure des Technologies et Industries du Bois (ENSTIB) - University of Lorraine, 27 rue Philippe Seguin, 88000 Epinal, FranceLaboratory of Process Engineering for Sustainable Development and Health Products (GPDDPS), National Polytechnic School of Constantine, Department of Process Engineering, Constantine, Algeria; Corresponding author.Two new bio-adsorbents were successfully synthesized by doping method with zinc chloride salt (ZnCl2) of raw artichoke leaves (RAL) and raw orange peels waste (ROP). Different analysis techniques (i.e. BET, SEM, XRD, FTIR) were used for characterizing the synthesized materials. Ketoprofen (KTF) nonsteroidal anti-inflammatory drug was effectively removed from water using the synthesized bio-adsorbents, under different operating conditions. The specific surface areas increased from 1009.960 and 997.816 m2/g for ROP and RAL natural materials, respectively, to 1511.278 and 3415.951 m2/g for ROP- and RAL-doped materials. More interestingly, maximum Ketoprofen removals of 90% and 96% were obtained using ROP- and RAL-doped bio-adsorbents, against null removal for natural ROP and RAL materials. The kinetic study shows that the pseudo-second order model simulated adequately the obtained Ketoprofen removal data with R2 superior to 99%. A DOE based on (23) full factorial design was used to evaluate the effect of pH, bio-adsorbent dosage and initial KTF concentration on Ketoprofen removal efficiency. The optimum conditions for KTF removal with both the activated wastes were pH= 2, bio-adsorbent dose of 0.1 g/L and C0,KTF= 5 mg/L with removal efficiency of 98.14% for ROP-ZnCl2, and pH= 2, bio-adsorbent dose of 0.3 g/L and C0,KTF = 20 mg/L with a removal efficiency of 99.84% for RAL-ZnCl2 bio-sorbent.http://www.sciencedirect.com/science/article/pii/S194439862400225XBio-sorbents synthesisWastewaterCharacterizationKetoprofen removalAdsorption enhancementFull factors design |
| spellingShingle | Amel Khalfaoui Abderrezzaq Benalia Zakaria Laggoun Raouf Bouchareb Imane Zaamta Rania Melloul Amina Menasria Slimane Merouani Antonio Pizzi Kerroum Derbal Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodology Desalination and Water Treatment Bio-sorbents synthesis Wastewater Characterization Ketoprofen removal Adsorption enhancement Full factors design |
| title | Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodology |
| title_full | Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodology |
| title_fullStr | Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodology |
| title_full_unstemmed | Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodology |
| title_short | Effective synthesis and application of artichoke and orange peels-based bio-sorbents for Ketoprofen removal from wastewater: Process optimization using Factorial methodology |
| title_sort | effective synthesis and application of artichoke and orange peels based bio sorbents for ketoprofen removal from wastewater process optimization using factorial methodology |
| topic | Bio-sorbents synthesis Wastewater Characterization Ketoprofen removal Adsorption enhancement Full factors design |
| url | http://www.sciencedirect.com/science/article/pii/S194439862400225X |
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