Thermodynamic investigations on host/guest complexation in deep eutectic solvent/water mixtures
The development of formulations based on cyclodextrins (CDs) and deep eutectic solvents (DESs), is an interesting approach to expand the applications of host–guest chemistry. However, there is a lack of information in the literature on the complexation mechanism in these non-conventional media. The...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Académie des sciences
2024-04-01
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| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.304/ |
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| Summary: | The development of formulations based on cyclodextrins (CDs) and deep eutectic solvents (DESs), is an interesting approach to expand the applications of host–guest chemistry. However, there is a lack of information in the literature on the complexation mechanism in these non-conventional media. The aim of this study is to provide, for the first time, fundamental information on the influence of the type and the wt% (weight percent) content of DES in the mixture on the thermodynamic properties (binding strength and complexation mechanism) of a model inclusion complex, β-CD/adamantanol by means of isothermal titration calorimetry (ITC). |
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| ISSN: | 1878-1543 |