Down-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal Conductivity

Highlights The down-top strategy enables large-scale production of poly(p-phenylene benzobisoxazole) nanofiber (PNF) paper with excellent intrinsic wave-transparent performance, thermal conductivity, and mechanical strength while significantly reduces the preparation time and cost. Fluorinated graph...

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Main Authors: Yuhan Lin, Lin Tang, Mingshun Jia, Mukun He, Junliang Zhang, Yusheng Tang, Junwei Gu
Format: Article
Language:English
Published: SpringerOpen 2025-08-01
Series:Nano-Micro Letters
Subjects:
Online Access:https://doi.org/10.1007/s40820-025-01878-y
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author Yuhan Lin
Lin Tang
Mingshun Jia
Mukun He
Junliang Zhang
Yusheng Tang
Junwei Gu
author_facet Yuhan Lin
Lin Tang
Mingshun Jia
Mukun He
Junliang Zhang
Yusheng Tang
Junwei Gu
author_sort Yuhan Lin
collection DOAJ
description Highlights The down-top strategy enables large-scale production of poly(p-phenylene benzobisoxazole) nanofiber (PNF) paper with excellent intrinsic wave-transparent performance, thermal conductivity, and mechanical strength while significantly reduces the preparation time and cost. Fluorinated graphene (FG)/PNF composite papers exhibit superior wave-transparent performance and thermal conductivity. When the mass fraction of FG is 40 wt%, its |T|² reaches 96.3% under 10 GHz while λ ∥ and λ ⊥ increase to 7.13 and 0.67 W m-1 K-1, respectively. FG/PNF composite paper with 40 wt% of FG also displays excellent mechanical properties, with the tensile strength and toughness reaching 197.4 MPa and 11.6 MJ m-3, respectively.
format Article
id doaj-art-cd8c0a8a8d6848d8b5f6136755206b0e
institution Kabale University
issn 2311-6706
2150-5551
language English
publishDate 2025-08-01
publisher SpringerOpen
record_format Article
series Nano-Micro Letters
spelling doaj-art-cd8c0a8a8d6848d8b5f6136755206b0e2025-08-24T11:46:41ZengSpringerOpenNano-Micro Letters2311-67062150-55512025-08-0118111710.1007/s40820-025-01878-yDown-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal ConductivityYuhan Lin0Lin Tang1Mingshun Jia2Mukun He3Junliang Zhang4Yusheng Tang5Junwei Gu6Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical UniversityChongqing Key Laboratory of Green Catalysis Materials and Technology, College of Chemistry, Chongqing Normal UniversityShaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical UniversityShaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical UniversityShaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical UniversityShaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical UniversityShaanxi Key Laboratory of Macromolecular Science and Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical UniversityHighlights The down-top strategy enables large-scale production of poly(p-phenylene benzobisoxazole) nanofiber (PNF) paper with excellent intrinsic wave-transparent performance, thermal conductivity, and mechanical strength while significantly reduces the preparation time and cost. Fluorinated graphene (FG)/PNF composite papers exhibit superior wave-transparent performance and thermal conductivity. When the mass fraction of FG is 40 wt%, its |T|² reaches 96.3% under 10 GHz while λ ∥ and λ ⊥ increase to 7.13 and 0.67 W m-1 K-1, respectively. FG/PNF composite paper with 40 wt% of FG also displays excellent mechanical properties, with the tensile strength and toughness reaching 197.4 MPa and 11.6 MJ m-3, respectively.https://doi.org/10.1007/s40820-025-01878-yPBO nanofibersFluorinated grapheneWave-transparencyThermal conductivity
spellingShingle Yuhan Lin
Lin Tang
Mingshun Jia
Mukun He
Junliang Zhang
Yusheng Tang
Junwei Gu
Down-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal Conductivity
Nano-Micro Letters
PBO nanofibers
Fluorinated graphene
Wave-transparency
Thermal conductivity
title Down-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal Conductivity
title_full Down-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal Conductivity
title_fullStr Down-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal Conductivity
title_full_unstemmed Down-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal Conductivity
title_short Down-Top Strategy Engineered Large-Scale Fluorographene/PBO Nanofibers Composite Papers with Excellent Wave-Transparent Performance and Thermal Conductivity
title_sort down top strategy engineered large scale fluorographene pbo nanofibers composite papers with excellent wave transparent performance and thermal conductivity
topic PBO nanofibers
Fluorinated graphene
Wave-transparency
Thermal conductivity
url https://doi.org/10.1007/s40820-025-01878-y
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