Steric Effects of <i>N</i>-Alkyl Group on the Base-Induced Nitrogen to Carbon Rearrangement of Orthogonally Protected <i>N</i>-Alkyl Arylsulphonamides

Steric Effects of <i>N</i>-Alkyl Group on the Base-Induced Nitrogen to Carbon Rearrangement of Orthogonally Protected <i>N</i>-Alkyl Arylsulphonamides

The rearrangement of a total of 56 members of 22 series of orthogonally protected <i>N</i>-alkyl arylsulphonamides of general structure 4-XC<sub>6</sub>H<sub>4</sub>SO<sub>2</sub>NR<sup>1</sup>CO<sub>2</sub>R<sup>2</sup...

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Bibliographic Details
Main Authors: Amie Saidykhan, Jenessa Ebert, Nathan W. Fenwick, William H. C. Martin, Richard D. Bowen
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Molecules
Subjects:
sulphonamides
rearrangement
ortho metalation
steric effects
saccharins
Online Access:https://www.mdpi.com/1420-3049/30/8/1823
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