Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions
L-Proline derived ionic liquids (ILs) used as both solvent and catalyst were efficient for transformation of fructose and sucrose to 5-hydroxymethylfurfural (HMF) in the presence of water. Response surface methodology (RSM) was employed to optimize fructose dehydration process, and a maximum HMF yie...
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | International Journal of Chemical Engineering |
| Online Access: | http://dx.doi.org/10.1155/2014/978708 |
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| author | Hu Li Song Yang |
| author_facet | Hu Li Song Yang |
| author_sort | Hu Li |
| collection | DOAJ |
| description | L-Proline derived ionic liquids (ILs) used as both solvent and catalyst were efficient for transformation of fructose and sucrose to 5-hydroxymethylfurfural (HMF) in the presence of water. Response surface methodology (RSM) was employed to optimize fructose dehydration process, and a maximum HMF yield of 73.6% could be obtained at 90°C after 50 min. The recycling of the IL exhibited an almost constant activity during five successive trials, and a possible reaction mechanism for the dehydration of fructose to HMF was proposed. |
| format | Article |
| id | doaj-art-cce602c9f5984a89a50c77292de7377c |
| institution | DOAJ |
| issn | 1687-806X 1687-8078 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
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| series | International Journal of Chemical Engineering |
| spelling | doaj-art-cce602c9f5984a89a50c77292de7377c2025-08-20T03:19:32ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782014-01-01201410.1155/2014/978708978708Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild ConditionsHu Li0Song Yang1State-Local Joint Laboratory for Comprehensive Utilization of Biomass, State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering (Ministry of Education), Center for Research and Development of Fine Chemicals, Guizhou University, Guiyang 550025, ChinaState-Local Joint Laboratory for Comprehensive Utilization of Biomass, State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering (Ministry of Education), Center for Research and Development of Fine Chemicals, Guizhou University, Guiyang 550025, ChinaL-Proline derived ionic liquids (ILs) used as both solvent and catalyst were efficient for transformation of fructose and sucrose to 5-hydroxymethylfurfural (HMF) in the presence of water. Response surface methodology (RSM) was employed to optimize fructose dehydration process, and a maximum HMF yield of 73.6% could be obtained at 90°C after 50 min. The recycling of the IL exhibited an almost constant activity during five successive trials, and a possible reaction mechanism for the dehydration of fructose to HMF was proposed.http://dx.doi.org/10.1155/2014/978708 |
| spellingShingle | Hu Li Song Yang Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions International Journal of Chemical Engineering |
| title | Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions |
| title_full | Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions |
| title_fullStr | Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions |
| title_full_unstemmed | Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions |
| title_short | Catalytic Transformation of Fructose and Sucrose to HMF with Proline-Derived Ionic Liquids under Mild Conditions |
| title_sort | catalytic transformation of fructose and sucrose to hmf with proline derived ionic liquids under mild conditions |
| url | http://dx.doi.org/10.1155/2014/978708 |
| work_keys_str_mv | AT huli catalytictransformationoffructoseandsucrosetohmfwithprolinederivedionicliquidsundermildconditions AT songyang catalytictransformationoffructoseandsucrosetohmfwithprolinederivedionicliquidsundermildconditions |