All-polymer piezo-ionic-electric electronics

Abstract Piezoelectric electronics possess great potential in flexible sensing and energy harvesting applications. However, they suffer from low electromechanical performance in all-organic piezoelectric systems due to the disordered and weakly-polarized interfaces. Here, we demonstrated an all-poly...

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Main Authors: Tianpei Xu, Long Jin, Yong Ao, Jieling Zhang, Yue Sun, Shenglong Wang, Yuanxiao Qu, Longchao Huang, Tao Yang, Weili Deng, Weiqing Yang
Format: Article
Language:English
Published: Nature Portfolio 2024-12-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-024-55177-y
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author Tianpei Xu
Long Jin
Yong Ao
Jieling Zhang
Yue Sun
Shenglong Wang
Yuanxiao Qu
Longchao Huang
Tao Yang
Weili Deng
Weiqing Yang
author_facet Tianpei Xu
Long Jin
Yong Ao
Jieling Zhang
Yue Sun
Shenglong Wang
Yuanxiao Qu
Longchao Huang
Tao Yang
Weili Deng
Weiqing Yang
author_sort Tianpei Xu
collection DOAJ
description Abstract Piezoelectric electronics possess great potential in flexible sensing and energy harvesting applications. However, they suffer from low electromechanical performance in all-organic piezoelectric systems due to the disordered and weakly-polarized interfaces. Here, we demonstrated an all-polymer piezo-ionic-electric electronics with PVDF/Nafion/PVDF (polyvinylidene difluoride) sandwich structure and regularized ion-electron interfaces. The piezoelectric effect and piezoionic effect mutually couple based on such ion-electron interfaces, endowing this electronics with the unique piezo-ionic-electric working mechanism. Further, owing to the massive interfacial accumulation of ion and electron charges, the electronics obtains a remarkable force-electric coupling enhancement. Experiments show that the electronics presents a high d33 of ~80.70 pC N−1, a pressure sensitivity of 51.50 mV kPa−1 and a maximum peak power of 34.66 mW m−2. It is applicable to be a transducer to light LEDs, and a sensor to detect weak physiological signals or mechanical vibration. This work shows the piezo-ionic-electric electronics as a paradigm of highly-optimized all-polymer piezo-generators.
format Article
id doaj-art-cc26143cc19c453189ad5100d299121f
institution Kabale University
issn 2041-1723
language English
publishDate 2024-12-01
publisher Nature Portfolio
record_format Article
series Nature Communications
spelling doaj-art-cc26143cc19c453189ad5100d299121f2025-01-05T12:36:39ZengNature PortfolioNature Communications2041-17232024-12-0115111110.1038/s41467-024-55177-yAll-polymer piezo-ionic-electric electronicsTianpei Xu0Long Jin1Yong Ao2Jieling Zhang3Yue Sun4Shenglong Wang5Yuanxiao Qu6Longchao Huang7Tao Yang8Weili Deng9Weiqing Yang10Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityKey Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong UniversityAbstract Piezoelectric electronics possess great potential in flexible sensing and energy harvesting applications. However, they suffer from low electromechanical performance in all-organic piezoelectric systems due to the disordered and weakly-polarized interfaces. Here, we demonstrated an all-polymer piezo-ionic-electric electronics with PVDF/Nafion/PVDF (polyvinylidene difluoride) sandwich structure and regularized ion-electron interfaces. The piezoelectric effect and piezoionic effect mutually couple based on such ion-electron interfaces, endowing this electronics with the unique piezo-ionic-electric working mechanism. Further, owing to the massive interfacial accumulation of ion and electron charges, the electronics obtains a remarkable force-electric coupling enhancement. Experiments show that the electronics presents a high d33 of ~80.70 pC N−1, a pressure sensitivity of 51.50 mV kPa−1 and a maximum peak power of 34.66 mW m−2. It is applicable to be a transducer to light LEDs, and a sensor to detect weak physiological signals or mechanical vibration. This work shows the piezo-ionic-electric electronics as a paradigm of highly-optimized all-polymer piezo-generators.https://doi.org/10.1038/s41467-024-55177-y
spellingShingle Tianpei Xu
Long Jin
Yong Ao
Jieling Zhang
Yue Sun
Shenglong Wang
Yuanxiao Qu
Longchao Huang
Tao Yang
Weili Deng
Weiqing Yang
All-polymer piezo-ionic-electric electronics
Nature Communications
title All-polymer piezo-ionic-electric electronics
title_full All-polymer piezo-ionic-electric electronics
title_fullStr All-polymer piezo-ionic-electric electronics
title_full_unstemmed All-polymer piezo-ionic-electric electronics
title_short All-polymer piezo-ionic-electric electronics
title_sort all polymer piezo ionic electric electronics
url https://doi.org/10.1038/s41467-024-55177-y
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AT yuesun allpolymerpiezoionicelectricelectronics
AT shenglongwang allpolymerpiezoionicelectricelectronics
AT yuanxiaoqu allpolymerpiezoionicelectricelectronics
AT longchaohuang allpolymerpiezoionicelectricelectronics
AT taoyang allpolymerpiezoionicelectricelectronics
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