Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient Predictors

Natural carbonate stones such as limestones and marbles are widely used in heritage and contemporary architecture, yet their durability is increasingly threatened by wildfire-related thermal stress. Since water transport plays a key role in stone deterioration, understanding how high temperatures af...

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Main Authors: Roberta Lobarinhas, Amélia Dionísio, Gustavo Paneiro
Format: Article
Language:English
Published: MDPI AG 2025-08-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/15/8567
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author Roberta Lobarinhas
Amélia Dionísio
Gustavo Paneiro
author_facet Roberta Lobarinhas
Amélia Dionísio
Gustavo Paneiro
author_sort Roberta Lobarinhas
collection DOAJ
description Natural carbonate stones such as limestones and marbles are widely used in heritage and contemporary architecture, yet their durability is increasingly threatened by wildfire-related thermal stress. Since water transport plays a key role in stone deterioration, understanding how high temperatures affect hydric behavior is critical for conservation. This study investigates thirteen Portuguese carbonate lithotypes (including marbles, limestones, a travertine, and a breccia) exposed to temperatures of 300 °C and 600 °C. Capillary absorption and open porosity were measured, alongside Leeb hardness (HL) and ultrasonic pulse velocity (UPV), to evaluate their predictive capacity for post-fire moisture behavior. Results show that thermal exposure increases porosity and capillary uptake while reducing mechanical cohesion. Strong correlations between UPV and hydric parameters across temperature ranges highlight its reliability as a non-invasive diagnostic tool. HL performed well in compact stones but was less consistent in porous or heterogeneous lithologies. The findings support the use of NDT tests, like UPV and HL, for rapid post-fire assessments and emphasize the need for lithology-specific conservation strategies.
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spelling doaj-art-cb94597d1bbf43228674e8d8453595cf2025-08-20T03:02:55ZengMDPI AGApplied Sciences2076-34172025-08-011515856710.3390/app15158567Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient PredictorsRoberta Lobarinhas0Amélia Dionísio1Gustavo Paneiro2CERENA, Técnico Lisboa, ULisboa, 1049-001 Lisboa, PortugalDER/CERENA, Técnico Lisboa, ULisboa, 1049-001 Lisboa, PortugalDER/CERENA, Técnico Lisboa, ULisboa, 1049-001 Lisboa, PortugalNatural carbonate stones such as limestones and marbles are widely used in heritage and contemporary architecture, yet their durability is increasingly threatened by wildfire-related thermal stress. Since water transport plays a key role in stone deterioration, understanding how high temperatures affect hydric behavior is critical for conservation. This study investigates thirteen Portuguese carbonate lithotypes (including marbles, limestones, a travertine, and a breccia) exposed to temperatures of 300 °C and 600 °C. Capillary absorption and open porosity were measured, alongside Leeb hardness (HL) and ultrasonic pulse velocity (UPV), to evaluate their predictive capacity for post-fire moisture behavior. Results show that thermal exposure increases porosity and capillary uptake while reducing mechanical cohesion. Strong correlations between UPV and hydric parameters across temperature ranges highlight its reliability as a non-invasive diagnostic tool. HL performed well in compact stones but was less consistent in porous or heterogeneous lithologies. The findings support the use of NDT tests, like UPV and HL, for rapid post-fire assessments and emphasize the need for lithology-specific conservation strategies.https://www.mdpi.com/2076-3417/15/15/8567natural stonefire-induced damagehydric behaviornon-destructive testingcarbonate lithotypesLeeb hardness
spellingShingle Roberta Lobarinhas
Amélia Dionísio
Gustavo Paneiro
Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient Predictors
Applied Sciences
natural stone
fire-induced damage
hydric behavior
non-destructive testing
carbonate lithotypes
Leeb hardness
title Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient Predictors
title_full Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient Predictors
title_fullStr Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient Predictors
title_full_unstemmed Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient Predictors
title_short Unveiling the Fire Effects on Hydric Dynamics of Carbonate Stones: Leeb Hardness and Ultrasonic Pulse Velocity as Capillary Coefficient Predictors
title_sort unveiling the fire effects on hydric dynamics of carbonate stones leeb hardness and ultrasonic pulse velocity as capillary coefficient predictors
topic natural stone
fire-induced damage
hydric behavior
non-destructive testing
carbonate lithotypes
Leeb hardness
url https://www.mdpi.com/2076-3417/15/15/8567
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AT ameliadionisio unveilingthefireeffectsonhydricdynamicsofcarbonatestonesleebhardnessandultrasonicpulsevelocityascapillarycoefficientpredictors
AT gustavopaneiro unveilingthefireeffectsonhydricdynamicsofcarbonatestonesleebhardnessandultrasonicpulsevelocityascapillarycoefficientpredictors