The influence of Pb vacancies on the properties of PZT-type ceramic transducers

This article is dedicated to prof. J. Ranachowski The result of investigations of the influence of lead vacancies on the crystalline structure of PZT-type ceramic piezoelectric materials is presented. The solid solution of [...] characterized by the perovskite-type structure (ABO3), is the basis...

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Main Authors: Z. SUROWIAK, L. KOZIELSKI, B. WODECKA-DUŚ, E.G. FESENKO, O.N. RAZUMOVSKAYA, L.A. REZNICHENKO, I.N. ZAKHARCHENKO
Format: Article
Language:English
Published: Institute of Fundamental Technological Research Polish Academy of Sciences 2000-01-01
Series:Archives of Acoustics
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Online Access:https://acoustics.ippt.pan.pl/index.php/aa/article/view/368
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author Z. SUROWIAK
L. KOZIELSKI
B. WODECKA-DUŚ
E.G. FESENKO
O.N. RAZUMOVSKAYA
L.A. REZNICHENKO
I.N. ZAKHARCHENKO
author_facet Z. SUROWIAK
L. KOZIELSKI
B. WODECKA-DUŚ
E.G. FESENKO
O.N. RAZUMOVSKAYA
L.A. REZNICHENKO
I.N. ZAKHARCHENKO
author_sort Z. SUROWIAK
collection DOAJ
description This article is dedicated to prof. J. Ranachowski The result of investigations of the influence of lead vacancies on the crystalline structure of PZT-type ceramic piezoelectric materials is presented. The solid solution of [...] characterized by the perovskite-type structure (ABO3), is the basis of those materials. The lead vacancies (VPb) was originated by a thermal treatment. Investigations of the influence of the lead deficiency on the crystalline structure of PZT-type ceramics have been performed for solid solutions characterized by compositions corresponding to the tetragonal or rhombohedral boundary of the morphotropic region (PCR-1, PCR-8: Piezoelectric Ceramics of Rostov) and to tetragonal phase region compositions (ceramics of Pb1-x(Zr0.39Ti0.59W0.01Cd0.01) O3). It has been found that the deficiency in lead causes a reconstruction of the perovskite phase crystalline structure or a change of the elementary cell parameters of that phase. The solid solutions on the basis of Pb(Zr,Ti)O3 resolve themselves into PbTiO3, ZrO2 and PbO when the lead deficiency caused by thermal treatment increases.
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record_format Article
series Archives of Acoustics
spelling doaj-art-cb35d78f059c40679ee49eee6437be2a2025-08-20T03:27:51ZengInstitute of Fundamental Technological Research Polish Academy of SciencesArchives of Acoustics0137-50752300-262X2000-01-01252The influence of Pb vacancies on the properties of PZT-type ceramic transducersZ. SUROWIAK0L. KOZIELSKI1B. WODECKA-DUŚ2E.G. FESENKO3O.N. RAZUMOVSKAYA4L.A. REZNICHENKO5I.N. ZAKHARCHENKO6Silesian University, Department of Materials SciencesSilesian University, Department of Materials SciencesSilesian University, Department of Materials SciencesRostov State University, Faculty of PhysicsRostov State University, Faculty of PhysicsRostov State University, Faculty of PhysicsRostov State University, Faculty of PhysicsThis article is dedicated to prof. J. Ranachowski The result of investigations of the influence of lead vacancies on the crystalline structure of PZT-type ceramic piezoelectric materials is presented. The solid solution of [...] characterized by the perovskite-type structure (ABO3), is the basis of those materials. The lead vacancies (VPb) was originated by a thermal treatment. Investigations of the influence of the lead deficiency on the crystalline structure of PZT-type ceramics have been performed for solid solutions characterized by compositions corresponding to the tetragonal or rhombohedral boundary of the morphotropic region (PCR-1, PCR-8: Piezoelectric Ceramics of Rostov) and to tetragonal phase region compositions (ceramics of Pb1-x(Zr0.39Ti0.59W0.01Cd0.01) O3). It has been found that the deficiency in lead causes a reconstruction of the perovskite phase crystalline structure or a change of the elementary cell parameters of that phase. The solid solutions on the basis of Pb(Zr,Ti)O3 resolve themselves into PbTiO3, ZrO2 and PbO when the lead deficiency caused by thermal treatment increases.https://acoustics.ippt.pan.pl/index.php/aa/article/view/368piezoelectrics ceramicPZT-type solid solutionlead vacanciesstructureelectro-acoustic propertiestransducers
spellingShingle Z. SUROWIAK
L. KOZIELSKI
B. WODECKA-DUŚ
E.G. FESENKO
O.N. RAZUMOVSKAYA
L.A. REZNICHENKO
I.N. ZAKHARCHENKO
The influence of Pb vacancies on the properties of PZT-type ceramic transducers
Archives of Acoustics
piezoelectrics ceramic
PZT-type solid solution
lead vacancies
structure
electro-acoustic properties
transducers
title The influence of Pb vacancies on the properties of PZT-type ceramic transducers
title_full The influence of Pb vacancies on the properties of PZT-type ceramic transducers
title_fullStr The influence of Pb vacancies on the properties of PZT-type ceramic transducers
title_full_unstemmed The influence of Pb vacancies on the properties of PZT-type ceramic transducers
title_short The influence of Pb vacancies on the properties of PZT-type ceramic transducers
title_sort influence of pb vacancies on the properties of pzt type ceramic transducers
topic piezoelectrics ceramic
PZT-type solid solution
lead vacancies
structure
electro-acoustic properties
transducers
url https://acoustics.ippt.pan.pl/index.php/aa/article/view/368
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