Optimization on Epoxidation of Palm Olein by Using Performic Acid
The epoxidation process of palm olein (POo) was carried out by using in situ generated performic acid (HCOOOH) to produce epoxidized palm olein (EPO). HCOOOH was produced by mixing of formic acid (HCOOH) as oxygen carrier and hydrogen peroxide (H2O2) as oxygen donor in various ratio of POo: HCOOH: H...
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/384948 |
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| author | Darfizzi Derawi Jumat Salimon |
| author_facet | Darfizzi Derawi Jumat Salimon |
| author_sort | Darfizzi Derawi |
| collection | DOAJ |
| description | The epoxidation process of palm olein (POo) was carried out by using in situ generated performic acid (HCOOOH) to produce epoxidized palm olein (EPO). HCOOOH was produced by mixing of formic acid (HCOOH) as oxygen carrier and hydrogen peroxide (H2O2) as oxygen donor in various ratio of POo: HCOOH: H2O2. The effect of HCOOH and H2O2 concentration, temperature, stirring effect and reaction time were studied. The presence of oxirane ring of EPO was characterised by fourier transformation infra-red (FTIR), proton and carbon nuclear magnetic resonance (1H-NMR and (13C-NMR) spectra. The results showed that an optimum oxirane oxygen content (OOC) value was obtained by using mol ratio of 1: 5: 2 at 150 minutes. |
| format | Article |
| id | doaj-art-cb34b7c9981a4beabda6fd28e0c7f0ce |
| institution | DOAJ |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-cb34b7c9981a4beabda6fd28e0c7f0ce2025-08-20T03:19:29ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-01741440144810.1155/2010/384948Optimization on Epoxidation of Palm Olein by Using Performic AcidDarfizzi Derawi0Jumat Salimon1School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, MalaysiaSchool of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, MalaysiaThe epoxidation process of palm olein (POo) was carried out by using in situ generated performic acid (HCOOOH) to produce epoxidized palm olein (EPO). HCOOOH was produced by mixing of formic acid (HCOOH) as oxygen carrier and hydrogen peroxide (H2O2) as oxygen donor in various ratio of POo: HCOOH: H2O2. The effect of HCOOH and H2O2 concentration, temperature, stirring effect and reaction time were studied. The presence of oxirane ring of EPO was characterised by fourier transformation infra-red (FTIR), proton and carbon nuclear magnetic resonance (1H-NMR and (13C-NMR) spectra. The results showed that an optimum oxirane oxygen content (OOC) value was obtained by using mol ratio of 1: 5: 2 at 150 minutes.http://dx.doi.org/10.1155/2010/384948 |
| spellingShingle | Darfizzi Derawi Jumat Salimon Optimization on Epoxidation of Palm Olein by Using Performic Acid E-Journal of Chemistry |
| title | Optimization on Epoxidation of Palm Olein by Using Performic Acid |
| title_full | Optimization on Epoxidation of Palm Olein by Using Performic Acid |
| title_fullStr | Optimization on Epoxidation of Palm Olein by Using Performic Acid |
| title_full_unstemmed | Optimization on Epoxidation of Palm Olein by Using Performic Acid |
| title_short | Optimization on Epoxidation of Palm Olein by Using Performic Acid |
| title_sort | optimization on epoxidation of palm olein by using performic acid |
| url | http://dx.doi.org/10.1155/2010/384948 |
| work_keys_str_mv | AT darfizziderawi optimizationonepoxidationofpalmoleinbyusingperformicacid AT jumatsalimon optimizationonepoxidationofpalmoleinbyusingperformicacid |