Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant Activity

<i>Rugulopteryx okamurae</i> (RO) is a species of brown seaweed that has invaded several shorelines worldwide, including the Spanish Mediterranean and the Strait of Gibraltar coasts, causing serious environmental and economic problems. This work aimed to characterize the bioactive compos...

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Main Authors: Radia N. A. Belhadj, Cristina Mellinas, Alfonso Jiménez, César Bordehore, Maria Carmen Garrigós
Format: Article
Language:English
Published: MDPI AG 2024-10-01
Series:Antioxidants
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Online Access:https://www.mdpi.com/2076-3921/13/11/1298
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author Radia N. A. Belhadj
Cristina Mellinas
Alfonso Jiménez
César Bordehore
Maria Carmen Garrigós
author_facet Radia N. A. Belhadj
Cristina Mellinas
Alfonso Jiménez
César Bordehore
Maria Carmen Garrigós
author_sort Radia N. A. Belhadj
collection DOAJ
description <i>Rugulopteryx okamurae</i> (RO) is a species of brown seaweed that has invaded several shorelines worldwide, including the Spanish Mediterranean and the Strait of Gibraltar coasts, causing serious environmental and economic problems. This work aimed to characterize the bioactive composition of RO. A high content of carbohydrates (58.7 ± 2.6 wt%), fats (17.1 ± 0.4 wt%), and ashes (14.3 ± 0.2 wt%) were found, together with lower protein content (5.5 ± 1.8 wt%). Holocellulose was the most abundant polysaccharide fraction (49.2 ± 1.3 wt%), showing 43.4 ± 2.0 wt% of cellulose and 5.8 ± 0.7 wt% of hemicellulose, followed by lignin (18.9 ± 2.5 wt%). The monosaccharides composition showed a high level of glucose (13.2 ± 1 wt%) and glucuronic acid (9.3 ± 0.5 wt%). RO contained high levels of essential nutrients (Ca, K, Na, S, Mg), trace minerals (Mn, Mo, Se, and Cu), and some toxic heavy metals (Ni, Cd, As). The main fatty acid present in RO was palmitic acid (C16:0, 30.8 ± 3.0 mg/100 g), followed by myristic acid (C14:0, 19.3 ± 2.4 mg/100 g) and eicosatetraenoic acid (C20:4, 19.2 ± 1.3 mg/100 g). The extract obtained by microwave-assisted extraction (MAE) presented significant contents of polyphenols (2.7 ± 0.2 mg GAE/g) and antioxidant activity (3.0 ± 0.4 mg TE/g DPPH, 4.5 ± 0.3 mg TE/g ABTS, 4.7 ± 0.3 mg TE/g FRAP). Six main polyphenols were identified by HPLC-MS/MS, showing higher contents of gallic acid (20.7 ± 1.5 mg/g) and chlorogenic acid (9.7 ± 0.5 mg/g). These results highlight the possibilities offered in the valorization of RO to obtain bioactive compounds with antioxidant performance in several applications.
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spelling doaj-art-cb1561d31fb345529803cd548f9764322025-08-20T01:53:42ZengMDPI AGAntioxidants2076-39212024-10-011311129810.3390/antiox13111298Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant ActivityRadia N. A. Belhadj0Cristina Mellinas1Alfonso Jiménez2César Bordehore3Maria Carmen Garrigós4Department of Analytical Chemistry, Nutrition & Food Sciences, University of Alicante, San Vicente del Raspeig, 03690 Alicante, SpainDepartment of Analytical Chemistry, Nutrition & Food Sciences, University of Alicante, San Vicente del Raspeig, 03690 Alicante, SpainDepartment of Analytical Chemistry, Nutrition & Food Sciences, University of Alicante, San Vicente del Raspeig, 03690 Alicante, SpainDepartment of Ecology, University of Alicante, 03690 Alicante, SpainDepartment of Analytical Chemistry, Nutrition & Food Sciences, University of Alicante, San Vicente del Raspeig, 03690 Alicante, Spain<i>Rugulopteryx okamurae</i> (RO) is a species of brown seaweed that has invaded several shorelines worldwide, including the Spanish Mediterranean and the Strait of Gibraltar coasts, causing serious environmental and economic problems. This work aimed to characterize the bioactive composition of RO. A high content of carbohydrates (58.7 ± 2.6 wt%), fats (17.1 ± 0.4 wt%), and ashes (14.3 ± 0.2 wt%) were found, together with lower protein content (5.5 ± 1.8 wt%). Holocellulose was the most abundant polysaccharide fraction (49.2 ± 1.3 wt%), showing 43.4 ± 2.0 wt% of cellulose and 5.8 ± 0.7 wt% of hemicellulose, followed by lignin (18.9 ± 2.5 wt%). The monosaccharides composition showed a high level of glucose (13.2 ± 1 wt%) and glucuronic acid (9.3 ± 0.5 wt%). RO contained high levels of essential nutrients (Ca, K, Na, S, Mg), trace minerals (Mn, Mo, Se, and Cu), and some toxic heavy metals (Ni, Cd, As). The main fatty acid present in RO was palmitic acid (C16:0, 30.8 ± 3.0 mg/100 g), followed by myristic acid (C14:0, 19.3 ± 2.4 mg/100 g) and eicosatetraenoic acid (C20:4, 19.2 ± 1.3 mg/100 g). The extract obtained by microwave-assisted extraction (MAE) presented significant contents of polyphenols (2.7 ± 0.2 mg GAE/g) and antioxidant activity (3.0 ± 0.4 mg TE/g DPPH, 4.5 ± 0.3 mg TE/g ABTS, 4.7 ± 0.3 mg TE/g FRAP). Six main polyphenols were identified by HPLC-MS/MS, showing higher contents of gallic acid (20.7 ± 1.5 mg/g) and chlorogenic acid (9.7 ± 0.5 mg/g). These results highlight the possibilities offered in the valorization of RO to obtain bioactive compounds with antioxidant performance in several applications.https://www.mdpi.com/2076-3921/13/11/1298<i>Rugulopteryx okamurae</i>invasive seaweedbioactive compoundsantioxidant activityvalorization
spellingShingle Radia N. A. Belhadj
Cristina Mellinas
Alfonso Jiménez
César Bordehore
Maria Carmen Garrigós
Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant Activity
Antioxidants
<i>Rugulopteryx okamurae</i>
invasive seaweed
bioactive compounds
antioxidant activity
valorization
title Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant Activity
title_full Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant Activity
title_fullStr Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant Activity
title_full_unstemmed Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant Activity
title_short Invasive Seaweed <i>Rugulopteryx okamurae</i>: A Potential Source of Bioactive Compounds with Antioxidant Activity
title_sort invasive seaweed i rugulopteryx okamurae i a potential source of bioactive compounds with antioxidant activity
topic <i>Rugulopteryx okamurae</i>
invasive seaweed
bioactive compounds
antioxidant activity
valorization
url https://www.mdpi.com/2076-3921/13/11/1298
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