Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet
Coordination polymers are attractive materials for various fields of practical application. The high degree of freedom of choice of metal ions and organic ligands plays a critical role in functional diversification. In the present study, we report the liquid–liquid interfacial synthesis of a 2D bis(...
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| Format: | Article |
| Language: | English |
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MDPI AG
2025-05-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/30/9/2044 |
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| author | Kenji Takada Joe Komeda Hiroaki Maeda Naoya Fukui Hiroyasu Masunaga Sono Sasaki Hiroshi Nishihara |
| author_facet | Kenji Takada Joe Komeda Hiroaki Maeda Naoya Fukui Hiroyasu Masunaga Sono Sasaki Hiroshi Nishihara |
| author_sort | Kenji Takada |
| collection | DOAJ |
| description | Coordination polymers are attractive materials for various fields of practical application. The high degree of freedom of choice of metal ions and organic ligands plays a critical role in functional diversification. In the present study, we report the liquid–liquid interfacial synthesis of a 2D bis(terpyridine)copper(II) polymer thin film, Cu-tpy. The synthesized Cu-tpy was characterized by various microscopic observations such as TEM, SEM, and AFM, and spectroscopic measurements such as XPS, Raman spectroscopy, SEM/EDS, and UV–Vis spectroscopy. Synchrotron-radiated X-ray scattering confirmed that Cu-tpy was oriented crystalline films. Moreover, Cu-tpy showed electrochemical micro-supercapacitor behavior in the solid-state owing to its ionic nature. This study expands the potential of bis(terpyridine)metal(II) polymers as electro-functional materials. |
| format | Article |
| id | doaj-art-ca80f5f56b4743a9a70f6330d55a9a2d |
| institution | Kabale University |
| issn | 1420-3049 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-ca80f5f56b4743a9a70f6330d55a9a2d2025-08-20T03:52:57ZengMDPI AGMolecules1420-30492025-05-01309204410.3390/molecules30092044Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer NanosheetKenji Takada0Joe Komeda1Hiroaki Maeda2Naoya Fukui3Hiroyasu Masunaga4Sono Sasaki5Hiroshi Nishihara6Research Institute for Science and Technology, Tokyo University of Science, 2641, Yamazaki, Noda, Chiba 278-8510, JapanResearch Institute for Science and Technology, Tokyo University of Science, 2641, Yamazaki, Noda, Chiba 278-8510, JapanResearch Institute for Science and Technology, Tokyo University of Science, 2641, Yamazaki, Noda, Chiba 278-8510, JapanResearch Institute for Science and Technology, Tokyo University of Science, 2641, Yamazaki, Noda, Chiba 278-8510, JapanJapan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, JapanFaculty of Fiber Science and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, JapanResearch Institute for Science and Technology, Tokyo University of Science, 2641, Yamazaki, Noda, Chiba 278-8510, JapanCoordination polymers are attractive materials for various fields of practical application. The high degree of freedom of choice of metal ions and organic ligands plays a critical role in functional diversification. In the present study, we report the liquid–liquid interfacial synthesis of a 2D bis(terpyridine)copper(II) polymer thin film, Cu-tpy. The synthesized Cu-tpy was characterized by various microscopic observations such as TEM, SEM, and AFM, and spectroscopic measurements such as XPS, Raman spectroscopy, SEM/EDS, and UV–Vis spectroscopy. Synchrotron-radiated X-ray scattering confirmed that Cu-tpy was oriented crystalline films. Moreover, Cu-tpy showed electrochemical micro-supercapacitor behavior in the solid-state owing to its ionic nature. This study expands the potential of bis(terpyridine)metal(II) polymers as electro-functional materials.https://www.mdpi.com/1420-3049/30/9/2044coordination chemistrycoordination nanosheetsterpyridine complexesinterfacial synthesisionic polymerredox |
| spellingShingle | Kenji Takada Joe Komeda Hiroaki Maeda Naoya Fukui Hiroyasu Masunaga Sono Sasaki Hiroshi Nishihara Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet Molecules coordination chemistry coordination nanosheets terpyridine complexes interfacial synthesis ionic polymer redox |
| title | Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet |
| title_full | Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet |
| title_fullStr | Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet |
| title_full_unstemmed | Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet |
| title_short | Interfacial Synthesis of an Electro-Functional 2D Bis(terpyridine)copper(II) Polymer Nanosheet |
| title_sort | interfacial synthesis of an electro functional 2d bis terpyridine copper ii polymer nanosheet |
| topic | coordination chemistry coordination nanosheets terpyridine complexes interfacial synthesis ionic polymer redox |
| url | https://www.mdpi.com/1420-3049/30/9/2044 |
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