Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °C

Recent advancements have been made in understanding the mechanisms and perspectives of fuel cells operating at elevated temperatures. However, the changes in electrochemical processes within the membrane electrode assembly remain unclear. This study aims to investigate the performance variation laws...

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Main Authors: Yunfei Zhang, Zhengrui Xiao, Xiaoyang Zhao, Jian Wang, Yadong Wang, Jun Yu
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Membranes
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Online Access:https://www.mdpi.com/2077-0375/15/3/72
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author Yunfei Zhang
Zhengrui Xiao
Xiaoyang Zhao
Jian Wang
Yadong Wang
Jun Yu
author_facet Yunfei Zhang
Zhengrui Xiao
Xiaoyang Zhao
Jian Wang
Yadong Wang
Jun Yu
author_sort Yunfei Zhang
collection DOAJ
description Recent advancements have been made in understanding the mechanisms and perspectives of fuel cells operating at elevated temperatures. However, the changes in electrochemical processes within the membrane electrode assembly remain unclear. This study aims to investigate the performance variation laws of membrane electrode assemblies composed of Gore12 during operation at an increasing temperature ranging from 80 to 120 °C, utilizing overpotential decomposition and electrochemical impedance analysis. The experimental results indicate that increasing back pressure can improve the performance of fuel cells, particularly at higher temperatures. The charge transfer resistance initially decreases and then increases with temperature. Furthermore, combined with the simulation results, it is demonstrated that Gore12’s thin membrane structure provides excellent self-humidification, which ensures efficient proton conduction at low relative humidity. These findings offer new insights into improving the performance of PEMFCs and enabling stable operation at high temperatures.
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series Membranes
spelling doaj-art-ca180df53f614433a0c9b40b102c0b782025-08-20T01:48:41ZengMDPI AGMembranes2077-03752025-03-011537210.3390/membranes15030072Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °CYunfei Zhang0Zhengrui Xiao1Xiaoyang Zhao2Jian Wang3Yadong Wang4Jun Yu5State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, ChinaState Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, ChinaRecent advancements have been made in understanding the mechanisms and perspectives of fuel cells operating at elevated temperatures. However, the changes in electrochemical processes within the membrane electrode assembly remain unclear. This study aims to investigate the performance variation laws of membrane electrode assemblies composed of Gore12 during operation at an increasing temperature ranging from 80 to 120 °C, utilizing overpotential decomposition and electrochemical impedance analysis. The experimental results indicate that increasing back pressure can improve the performance of fuel cells, particularly at higher temperatures. The charge transfer resistance initially decreases and then increases with temperature. Furthermore, combined with the simulation results, it is demonstrated that Gore12’s thin membrane structure provides excellent self-humidification, which ensures efficient proton conduction at low relative humidity. These findings offer new insights into improving the performance of PEMFCs and enabling stable operation at high temperatures.https://www.mdpi.com/2077-0375/15/3/72PEMFCincreasing temperatureelectrochemical impedanceself-humidification3D model
spellingShingle Yunfei Zhang
Zhengrui Xiao
Xiaoyang Zhao
Jian Wang
Yadong Wang
Jun Yu
Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °C
Membranes
PEMFC
increasing temperature
electrochemical impedance
self-humidification
3D model
title Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °C
title_full Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °C
title_fullStr Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °C
title_full_unstemmed Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °C
title_short Experimental and Simulation Study of Proton Exchange Membrane Fuel Cell with 12 µm Thick Membrane over the Temperature Range of 80 °C to 120 °C
title_sort experimental and simulation study of proton exchange membrane fuel cell with 12 µm thick membrane over the temperature range of 80 °c to 120 °c
topic PEMFC
increasing temperature
electrochemical impedance
self-humidification
3D model
url https://www.mdpi.com/2077-0375/15/3/72
work_keys_str_mv AT yunfeizhang experimentalandsimulationstudyofprotonexchangemembranefuelcellwith12μmthickmembraneoverthetemperaturerangeof80cto120c
AT zhengruixiao experimentalandsimulationstudyofprotonexchangemembranefuelcellwith12μmthickmembraneoverthetemperaturerangeof80cto120c
AT xiaoyangzhao experimentalandsimulationstudyofprotonexchangemembranefuelcellwith12μmthickmembraneoverthetemperaturerangeof80cto120c
AT jianwang experimentalandsimulationstudyofprotonexchangemembranefuelcellwith12μmthickmembraneoverthetemperaturerangeof80cto120c
AT yadongwang experimentalandsimulationstudyofprotonexchangemembranefuelcellwith12μmthickmembraneoverthetemperaturerangeof80cto120c
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