Skeletal isomerization of heptanes over superacid catalysts of different nature
The sequence of the formation of multi-branched heptane isomers was studied in liquid and gaseous phases over different liquid and solid superacid catalysts. It was found that this sequence does not depend on the phase state, catalyst nature, and conditions, evidencing in favor of common reaction me...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2011-06-01
|
| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/836 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849253196419039232 |
|---|---|
| author | A. S. Berenblum E. A. Katsman V. Ya. Danyushevskiy B. P. Krymov |
| author_facet | A. S. Berenblum E. A. Katsman V. Ya. Danyushevskiy B. P. Krymov |
| author_sort | A. S. Berenblum |
| collection | DOAJ |
| description | The sequence of the formation of multi-branched heptane isomers was studied in liquid and gaseous phases over different liquid and solid superacid catalysts. It was found that this sequence does not depend on the phase state, catalyst nature, and conditions, evidencing in favor of common reaction mechanism. The 2,4-dimethylpentane transformation into 2,2-dimethylpentane can be explained by the intermediate formation of cyclobutyl carbocation. |
| format | Article |
| id | doaj-art-ca0ee993bd434234bd2c86fb4d2c7919 |
| institution | Kabale University |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2011-06-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-ca0ee993bd434234bd2c86fb4d2c79192025-08-20T03:56:24ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752011-06-01634043830Skeletal isomerization of heptanes over superacid catalysts of different natureA. S. Berenblum0E. A. Katsman1V. Ya. Danyushevskiy2B. P. Krymov3МИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86МИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86ООО «ВНИИОС-Наука»ООО «ВНИИОС-Наука»The sequence of the formation of multi-branched heptane isomers was studied in liquid and gaseous phases over different liquid and solid superacid catalysts. It was found that this sequence does not depend on the phase state, catalyst nature, and conditions, evidencing in favor of common reaction mechanism. The 2,4-dimethylpentane transformation into 2,2-dimethylpentane can be explained by the intermediate formation of cyclobutyl carbocation.https://www.finechem-mirea.ru/jour/article/view/836paraffinisomerizationreaction mechanismcatalysissuperacids |
| spellingShingle | A. S. Berenblum E. A. Katsman V. Ya. Danyushevskiy B. P. Krymov Skeletal isomerization of heptanes over superacid catalysts of different nature Тонкие химические технологии paraffin isomerization reaction mechanism catalysis superacids |
| title | Skeletal isomerization of heptanes over superacid catalysts of different nature |
| title_full | Skeletal isomerization of heptanes over superacid catalysts of different nature |
| title_fullStr | Skeletal isomerization of heptanes over superacid catalysts of different nature |
| title_full_unstemmed | Skeletal isomerization of heptanes over superacid catalysts of different nature |
| title_short | Skeletal isomerization of heptanes over superacid catalysts of different nature |
| title_sort | skeletal isomerization of heptanes over superacid catalysts of different nature |
| topic | paraffin isomerization reaction mechanism catalysis superacids |
| url | https://www.finechem-mirea.ru/jour/article/view/836 |
| work_keys_str_mv | AT asberenblum skeletalisomerizationofheptanesoversuperacidcatalystsofdifferentnature AT eakatsman skeletalisomerizationofheptanesoversuperacidcatalystsofdifferentnature AT vyadanyushevskiy skeletalisomerizationofheptanesoversuperacidcatalystsofdifferentnature AT bpkrymov skeletalisomerizationofheptanesoversuperacidcatalystsofdifferentnature |