Electrorefining of aluminum alloy in ionic liquids at low temperatures

The electrorefining of aluminum alloy (A360) in ionic liquids at low temperatures has been investigated. The ionic liquid electrolyte was prepared by mixing anhydrous AlCl3 and 1-Butyl-3- methylimidazolium chloride (BMIC) in appropriate proportions. The effect of the cell voltage temperature, and th...

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Main Authors: Kamavaram V., Mantha D., Reddy R.G.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2003-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302043K.pdf
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author Kamavaram V.
Mantha D.
Reddy R.G.
author_facet Kamavaram V.
Mantha D.
Reddy R.G.
author_sort Kamavaram V.
collection DOAJ
description The electrorefining of aluminum alloy (A360) in ionic liquids at low temperatures has been investigated. The ionic liquid electrolyte was prepared by mixing anhydrous AlCl3 and 1-Butyl-3- methylimidazolium chloride (BMIC) in appropriate proportions. The effect of the cell voltage temperature, and the composition of the electrolyte on the electrorefining process has been studied. The characterization of the deposited aluminum was performed using scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. The influence of experimental parameters such as cell voltage and concentration of AlCl3 in the electrolyte on the deposit morphology was discussed. The composition of the aluminum deposits was analyzed using X-ray fluorescence spectrometer (XRF). Aluminum deposits with purity higher than 99.89 % were obtained. At a cell voltage of 1.0 V vs. Al/Al(III), the energy consumption was about 3 kWh/kg-Al. The main advantage of the process is low energy consumption compared to the existing industrial aluminum refining process.
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series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-c9e71b1f6db24e8bbebba1035623e7d82025-02-02T19:43:17ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392003-01-01391-2435810.2298/JMMB0302043KElectrorefining of aluminum alloy in ionic liquids at low temperaturesKamavaram V.Mantha D.Reddy R.G.The electrorefining of aluminum alloy (A360) in ionic liquids at low temperatures has been investigated. The ionic liquid electrolyte was prepared by mixing anhydrous AlCl3 and 1-Butyl-3- methylimidazolium chloride (BMIC) in appropriate proportions. The effect of the cell voltage temperature, and the composition of the electrolyte on the electrorefining process has been studied. The characterization of the deposited aluminum was performed using scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. The influence of experimental parameters such as cell voltage and concentration of AlCl3 in the electrolyte on the deposit morphology was discussed. The composition of the aluminum deposits was analyzed using X-ray fluorescence spectrometer (XRF). Aluminum deposits with purity higher than 99.89 % were obtained. At a cell voltage of 1.0 V vs. Al/Al(III), the energy consumption was about 3 kWh/kg-Al. The main advantage of the process is low energy consumption compared to the existing industrial aluminum refining process.http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302043K.pdfelectrorefiningionic liquidsaluminium alloy
spellingShingle Kamavaram V.
Mantha D.
Reddy R.G.
Electrorefining of aluminum alloy in ionic liquids at low temperatures
Journal of Mining and Metallurgy. Section B: Metallurgy
electrorefining
ionic liquids
aluminium alloy
title Electrorefining of aluminum alloy in ionic liquids at low temperatures
title_full Electrorefining of aluminum alloy in ionic liquids at low temperatures
title_fullStr Electrorefining of aluminum alloy in ionic liquids at low temperatures
title_full_unstemmed Electrorefining of aluminum alloy in ionic liquids at low temperatures
title_short Electrorefining of aluminum alloy in ionic liquids at low temperatures
title_sort electrorefining of aluminum alloy in ionic liquids at low temperatures
topic electrorefining
ionic liquids
aluminium alloy
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2003/1450-53390302043K.pdf
work_keys_str_mv AT kamavaramv electrorefiningofaluminumalloyinionicliquidsatlowtemperatures
AT manthad electrorefiningofaluminumalloyinionicliquidsatlowtemperatures
AT reddyrg electrorefiningofaluminumalloyinionicliquidsatlowtemperatures