Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil
Due to the shortage of energy resources and environmental issues, the study presents a sustainable approach for biodiesel production from waste cooking oil (WCO) catalyzed using magnetic catalyst-based biochar derived spent coffee ground (SCG). The added properties of magnetic and basic towards this...
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Elsevier
2025-12-01
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author | Jayaraja Silvaraja Noor Yahida Yahya Muzakkir Mohammad Zainol Yong Siang Lee |
author_facet | Jayaraja Silvaraja Noor Yahida Yahya Muzakkir Mohammad Zainol Yong Siang Lee |
author_sort | Jayaraja Silvaraja |
collection | DOAJ |
description | Due to the shortage of energy resources and environmental issues, the study presents a sustainable approach for biodiesel production from waste cooking oil (WCO) catalyzed using magnetic catalyst-based biochar derived spent coffee ground (SCG). The added properties of magnetic and basic towards this catalyst was prepared by facile carbonization of one-pot SCG with Fe(III) and potassium hydroxide as activation agent at 700 °C for 2 h The characteristics of the catalyst was analyzed through Fourier transform spectroscopy (FTIR), scanning electron microscope coupled with energy dispersive X-ray (SEM-EDX), x-ray diffraction and Brunauer–Emmett–Teller (BET) surface area analysis. The performance of the catalyst was explored by the parametric effect on biodiesel yield from WCO. The parameters included are methanol to oil molar ratio, dosage of the catalyst and reaction time. The results showed that the catalyst exhibited excellent catalytic activity, with a biodiesel yield of 92.31% under 6:1 methanol to oil molar ratio, 1 wt% of catalyst dosage and 2 h of reaction time and the magnetism observation shows the catalyst own a magnetic property. In addition, the findings suggest that this approach offers a promising contribution for the development of a circular economy in the biofuel industry based on the utilization of waste to wealth. |
format | Article |
id | doaj-art-c9e6859fb5ee4cfead928915879fbb27 |
institution | Kabale University |
issn | 2772-7823 |
language | English |
publishDate | 2025-12-01 |
publisher | Elsevier |
record_format | Article |
series | Cleaner Chemical Engineering |
spelling | doaj-art-c9e6859fb5ee4cfead928915879fbb272025-01-23T05:28:02ZengElsevierCleaner Chemical Engineering2772-78232025-12-0111100148Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oilJayaraja Silvaraja0Noor Yahida Yahya1Muzakkir Mohammad Zainol2Yong Siang Lee3Faculty of Civil Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, MalaysiaFaculty of Civil Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, Malaysia; Centre for Advanced Intelligent Materials, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, Malaysia; Corresponding author.School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, MalaysiaFaculty of Civil Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, MalaysiaDue to the shortage of energy resources and environmental issues, the study presents a sustainable approach for biodiesel production from waste cooking oil (WCO) catalyzed using magnetic catalyst-based biochar derived spent coffee ground (SCG). The added properties of magnetic and basic towards this catalyst was prepared by facile carbonization of one-pot SCG with Fe(III) and potassium hydroxide as activation agent at 700 °C for 2 h The characteristics of the catalyst was analyzed through Fourier transform spectroscopy (FTIR), scanning electron microscope coupled with energy dispersive X-ray (SEM-EDX), x-ray diffraction and Brunauer–Emmett–Teller (BET) surface area analysis. The performance of the catalyst was explored by the parametric effect on biodiesel yield from WCO. The parameters included are methanol to oil molar ratio, dosage of the catalyst and reaction time. The results showed that the catalyst exhibited excellent catalytic activity, with a biodiesel yield of 92.31% under 6:1 methanol to oil molar ratio, 1 wt% of catalyst dosage and 2 h of reaction time and the magnetism observation shows the catalyst own a magnetic property. In addition, the findings suggest that this approach offers a promising contribution for the development of a circular economy in the biofuel industry based on the utilization of waste to wealth.http://www.sciencedirect.com/science/article/pii/S2772782325000038BiodieselWaste cooking oilMagnetic catalystSpent coffee groundBiocharTransesterification |
spellingShingle | Jayaraja Silvaraja Noor Yahida Yahya Muzakkir Mohammad Zainol Yong Siang Lee Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil Cleaner Chemical Engineering Biodiesel Waste cooking oil Magnetic catalyst Spent coffee ground Biochar Transesterification |
title | Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil |
title_full | Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil |
title_fullStr | Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil |
title_full_unstemmed | Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil |
title_short | Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil |
title_sort | preliminary investigations of sustainable magnetic catalyst based biochar derived spent coffee ground for biodiesel production from waste cooking oil |
topic | Biodiesel Waste cooking oil Magnetic catalyst Spent coffee ground Biochar Transesterification |
url | http://www.sciencedirect.com/science/article/pii/S2772782325000038 |
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