Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil

Due to the shortage of energy resources and environmental issues, the study presents a sustainable approach for biodiesel production from waste cooking oil (WCO) catalyzed using magnetic catalyst-based biochar derived spent coffee ground (SCG). The added properties of magnetic and basic towards this...

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Main Authors: Jayaraja Silvaraja, Noor Yahida Yahya, Muzakkir Mohammad Zainol, Yong Siang Lee
Format: Article
Language:English
Published: Elsevier 2025-12-01
Series:Cleaner Chemical Engineering
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Online Access:http://www.sciencedirect.com/science/article/pii/S2772782325000038
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author Jayaraja Silvaraja
Noor Yahida Yahya
Muzakkir Mohammad Zainol
Yong Siang Lee
author_facet Jayaraja Silvaraja
Noor Yahida Yahya
Muzakkir Mohammad Zainol
Yong Siang Lee
author_sort Jayaraja Silvaraja
collection DOAJ
description Due to the shortage of energy resources and environmental issues, the study presents a sustainable approach for biodiesel production from waste cooking oil (WCO) catalyzed using magnetic catalyst-based biochar derived spent coffee ground (SCG). The added properties of magnetic and basic towards this catalyst was prepared by facile carbonization of one-pot SCG with Fe(III) and potassium hydroxide as activation agent at 700 °C for 2 h The characteristics of the catalyst was analyzed through Fourier transform spectroscopy (FTIR), scanning electron microscope coupled with energy dispersive X-ray (SEM-EDX), x-ray diffraction and Brunauer–Emmett–Teller (BET) surface area analysis. The performance of the catalyst was explored by the parametric effect on biodiesel yield from WCO. The parameters included are methanol to oil molar ratio, dosage of the catalyst and reaction time. The results showed that the catalyst exhibited excellent catalytic activity, with a biodiesel yield of 92.31% under 6:1 methanol to oil molar ratio, 1 wt% of catalyst dosage and 2 h of reaction time and the magnetism observation shows the catalyst own a magnetic property. In addition, the findings suggest that this approach offers a promising contribution for the development of a circular economy in the biofuel industry based on the utilization of waste to wealth.
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institution Kabale University
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series Cleaner Chemical Engineering
spelling doaj-art-c9e6859fb5ee4cfead928915879fbb272025-01-23T05:28:02ZengElsevierCleaner Chemical Engineering2772-78232025-12-0111100148Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oilJayaraja Silvaraja0Noor Yahida Yahya1Muzakkir Mohammad Zainol2Yong Siang Lee3Faculty of Civil Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, MalaysiaFaculty of Civil Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, Malaysia; Centre for Advanced Intelligent Materials, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, Malaysia; Corresponding author.School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, MalaysiaFaculty of Civil Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuh Persiaran Tun Khalil Yaakob, 26300 Kuatan, Pahang, MalaysiaDue to the shortage of energy resources and environmental issues, the study presents a sustainable approach for biodiesel production from waste cooking oil (WCO) catalyzed using magnetic catalyst-based biochar derived spent coffee ground (SCG). The added properties of magnetic and basic towards this catalyst was prepared by facile carbonization of one-pot SCG with Fe(III) and potassium hydroxide as activation agent at 700 °C for 2 h The characteristics of the catalyst was analyzed through Fourier transform spectroscopy (FTIR), scanning electron microscope coupled with energy dispersive X-ray (SEM-EDX), x-ray diffraction and Brunauer–Emmett–Teller (BET) surface area analysis. The performance of the catalyst was explored by the parametric effect on biodiesel yield from WCO. The parameters included are methanol to oil molar ratio, dosage of the catalyst and reaction time. The results showed that the catalyst exhibited excellent catalytic activity, with a biodiesel yield of 92.31% under 6:1 methanol to oil molar ratio, 1 wt% of catalyst dosage and 2 h of reaction time and the magnetism observation shows the catalyst own a magnetic property. In addition, the findings suggest that this approach offers a promising contribution for the development of a circular economy in the biofuel industry based on the utilization of waste to wealth.http://www.sciencedirect.com/science/article/pii/S2772782325000038BiodieselWaste cooking oilMagnetic catalystSpent coffee groundBiocharTransesterification
spellingShingle Jayaraja Silvaraja
Noor Yahida Yahya
Muzakkir Mohammad Zainol
Yong Siang Lee
Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil
Cleaner Chemical Engineering
Biodiesel
Waste cooking oil
Magnetic catalyst
Spent coffee ground
Biochar
Transesterification
title Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil
title_full Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil
title_fullStr Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil
title_full_unstemmed Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil
title_short Preliminary investigations of sustainable magnetic catalyst-based biochar derived spent coffee ground for biodiesel production from waste cooking oil
title_sort preliminary investigations of sustainable magnetic catalyst based biochar derived spent coffee ground for biodiesel production from waste cooking oil
topic Biodiesel
Waste cooking oil
Magnetic catalyst
Spent coffee ground
Biochar
Transesterification
url http://www.sciencedirect.com/science/article/pii/S2772782325000038
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AT muzakkirmohammadzainol preliminaryinvestigationsofsustainablemagneticcatalystbasedbiocharderivedspentcoffeegroundforbiodieselproductionfromwastecookingoil
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