Rapid Synthesis of Fast-Charging TiNb<sub>2</sub>O<sub>7</sub> for Lithium-Ion Storage via Ultrafast Carbothermal Shock
The development of fast-charging lithium-ion batteries urgently requires high-performance anode materials. In this paper, through an ultrafast carbothermal shock (CTS) strategy, titanium niobium oxide (TiNb<sub>2</sub>O<sub>7</sub>, TNO) with an optimized structure was succes...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-04-01
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| Series: | Micromachines |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2072-666X/16/5/490 |
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| Summary: | The development of fast-charging lithium-ion batteries urgently requires high-performance anode materials. In this paper, through an ultrafast carbothermal shock (CTS) strategy, titanium niobium oxide (TiNb<sub>2</sub>O<sub>7</sub>, TNO) with an optimized structure was successfully synthesized within 30 s. By regulating the synthesis temperature to 1200 °C, the TNO-1200 material was obtained. Its lattice parameters (a-axis: 17.6869 Å) and unit-cell volume (796.83 Å<sup>3</sup>) were significantly expanded compared to the standard structure (a-axis: 17.51 Å, volume ~790 Å<sup>3</sup>), which widened the lithium-ion migration channels. Rietveld refinement and atomic position analysis indicated that the partial overlap of Ti/Nb atoms and the cooperative displacement of oxygen atoms induced by CTS reduced the lithium-ion diffusion energy barrier. Meanwhile, the cation disorder suppressed the polarization effect. Electrochemical tests showed that after 3000 cycles at a current density of 10 C, the specific capacity of TNO-1200 reached 125 mAh/g, with a capacity retention rate of 98%. EDS mapping confirmed the uniform distribution of elements and the absence of impurity phases. This study provides an efficient synthesis strategy and theoretical basis for the design of high-performance fast-charging battery materials through atomic-scale structural engineering. |
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| ISSN: | 2072-666X |