High-entropy materials for sodium-ion batteries
The high-entropy concept is receiving attention as an advanced design strategy to functionalize material properties by tuning the disorderliness of the system. High-entropy materials have garnered significant recognition in the realm of energy storage due to their versatile and diverse material prop...
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| Format: | Article |
| Language: | English |
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Elsevier
2024-01-01
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| Series: | Next Sustainability |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2949823624000217 |
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| author | Greeshma Caroline Neeraja Nair Shantikumar V. Nair Prabeer Barpanda Senthilkumar Baskar |
| author_facet | Greeshma Caroline Neeraja Nair Shantikumar V. Nair Prabeer Barpanda Senthilkumar Baskar |
| author_sort | Greeshma Caroline |
| collection | DOAJ |
| description | The high-entropy concept is receiving attention as an advanced design strategy to functionalize material properties by tuning the disorderliness of the system. High-entropy materials have garnered significant recognition in the realm of energy storage due to their versatile and diverse material properties. In recent times, there has been active exploration of traditional materials as positive electrodes in sodium-ion batteries. Nevertheless, under profound sodiated conditions, these materials tend to exhibit sluggish kinetics and unfavourable phase transitions, leading to significant capacity degradation and subpar rate capability. High-entropy concepts successfully tune the configurational entropy by adjusting the stoichiometric balance of active/inactive cations to address the drawbacks. The recent developments and research progress on high-entropy materials for sodium-ion batteries are reviewed in this article, with a focus on the advantages of configurational entropy modulation for improving electrochemical performances. The positive aspects of high-entropy cathode materials as well as the key challenges are finally outlined to realize practical sodium-ion batteries. |
| format | Article |
| id | doaj-art-c92b95413bf24ac7b5a2abe3eaccadd8 |
| institution | OA Journals |
| issn | 2949-8236 |
| language | English |
| publishDate | 2024-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Next Sustainability |
| spelling | doaj-art-c92b95413bf24ac7b5a2abe3eaccadd82025-08-20T01:55:27ZengElsevierNext Sustainability2949-82362024-01-01410004410.1016/j.nxsust.2024.100044High-entropy materials for sodium-ion batteriesGreeshma Caroline0Neeraja Nair1Shantikumar V. Nair2Prabeer Barpanda3Senthilkumar Baskar4School of Nanosciences and Molecular Medicine, Amrita Institute of Medical Sciences and Research Centre, Amrita Vishwa Vidyapeetham, Kochi, Kerala 682041, IndiaSchool of Nanosciences and Molecular Medicine, Amrita Institute of Medical Sciences and Research Centre, Amrita Vishwa Vidyapeetham, Kochi, Kerala 682041, IndiaSchool of Nanosciences and Molecular Medicine, Amrita Institute of Medical Sciences and Research Centre, Amrita Vishwa Vidyapeetham, Kochi, Kerala 682041, IndiaFaraday Materials Laboratory (FaMaL), Materials Research Center, Indian Institute of Science, Bangalore 560012, India; Helmholtz Institute Ulm (HIU), Electrochemical Energy Storage, Ulm 89081, Germany; Institute of Nanotechnology, Karlsruhe Institute of Technology, Karlsruhe 76021, Germany; Corresponding author at: Faraday Materials Laboratory (FaMaL), Materials Research Center, Indian Institute of Science, Bangalore 560012, India.School of Nanosciences and Molecular Medicine, Amrita Institute of Medical Sciences and Research Centre, Amrita Vishwa Vidyapeetham, Kochi, Kerala 682041, India; Corresponding author.The high-entropy concept is receiving attention as an advanced design strategy to functionalize material properties by tuning the disorderliness of the system. High-entropy materials have garnered significant recognition in the realm of energy storage due to their versatile and diverse material properties. In recent times, there has been active exploration of traditional materials as positive electrodes in sodium-ion batteries. Nevertheless, under profound sodiated conditions, these materials tend to exhibit sluggish kinetics and unfavourable phase transitions, leading to significant capacity degradation and subpar rate capability. High-entropy concepts successfully tune the configurational entropy by adjusting the stoichiometric balance of active/inactive cations to address the drawbacks. The recent developments and research progress on high-entropy materials for sodium-ion batteries are reviewed in this article, with a focus on the advantages of configurational entropy modulation for improving electrochemical performances. The positive aspects of high-entropy cathode materials as well as the key challenges are finally outlined to realize practical sodium-ion batteries.http://www.sciencedirect.com/science/article/pii/S2949823624000217Sodium-ion batteriesCapacityHigh-entropyCathodesLayered metal oxides |
| spellingShingle | Greeshma Caroline Neeraja Nair Shantikumar V. Nair Prabeer Barpanda Senthilkumar Baskar High-entropy materials for sodium-ion batteries Next Sustainability Sodium-ion batteries Capacity High-entropy Cathodes Layered metal oxides |
| title | High-entropy materials for sodium-ion batteries |
| title_full | High-entropy materials for sodium-ion batteries |
| title_fullStr | High-entropy materials for sodium-ion batteries |
| title_full_unstemmed | High-entropy materials for sodium-ion batteries |
| title_short | High-entropy materials for sodium-ion batteries |
| title_sort | high entropy materials for sodium ion batteries |
| topic | Sodium-ion batteries Capacity High-entropy Cathodes Layered metal oxides |
| url | http://www.sciencedirect.com/science/article/pii/S2949823624000217 |
| work_keys_str_mv | AT greeshmacaroline highentropymaterialsforsodiumionbatteries AT neerajanair highentropymaterialsforsodiumionbatteries AT shantikumarvnair highentropymaterialsforsodiumionbatteries AT prabeerbarpanda highentropymaterialsforsodiumionbatteries AT senthilkumarbaskar highentropymaterialsforsodiumionbatteries |