Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizes

Spray flame synthesis (SFS) is a promising technique for the production of metal-oxide nanoparticles. However, the processes involved during the synthesis are not yet fully understood. To provide a common workbench for a wide range of investigations, the standardized SpraySyn burners have been intro...

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Main Authors: Peter Lang, Nils E. Schneider, Franz J.T. Huber, Stefan Will
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Applications in Energy and Combustion Science
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666352X25000068
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author Peter Lang
Nils E. Schneider
Franz J.T. Huber
Stefan Will
author_facet Peter Lang
Nils E. Schneider
Franz J.T. Huber
Stefan Will
author_sort Peter Lang
collection DOAJ
description Spray flame synthesis (SFS) is a promising technique for the production of metal-oxide nanoparticles. However, the processes involved during the synthesis are not yet fully understood. To provide a common workbench for a wide range of investigations, the standardized SpraySyn burners have been introduced. This work presents an in-depth investigation of the improved SpraySyn 2.0 burner, characterizing important droplet, combustion and particle features. The sizes of the droplets produced from an ignited ethanol spray are measured in a range between 20 mm and 45 mm height above the burner (HAB) employing wide-angle light scattering (WALS), revealing much smaller droplets compared to previous SpraySyn 1.0, which eventually leads to faster evaporation. Flame fluctuations are investigated using high-speed imaging of the flame chemiluminescence, indicating a change in fluctuation behaviour compared to the previous burner. WALS is also employed for single-shot in situ size measurements of produced iron-oxide and titanium-dioxide nanoparticles at various HABs ranging from 30 mm to 210 mm, allowing to observe the particle growth. To further assess the properties of the produced particles, extensive TEM measurements for both particle systems are conducted and evaluated. Finally, the influence of flame pulsations on particle size is investigated by coupling chemiluminescence imaging with WALS, yielding no correlation between both.
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spelling doaj-art-c9211a10e4dc4d0db880eca48bd85ea62025-08-20T02:37:38ZengElsevierApplications in Energy and Combustion Science2666-352X2025-06-012210032410.1016/j.jaecs.2025.100324Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizesPeter Lang0Nils E. Schneider1Franz J.T. Huber2Stefan Will3Lehrstuhl für Technische Thermodynamik (LTT), Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU), Erlangen, Germany; Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU), Erlangen, GermanyLehrstuhl für Technische Thermodynamik (LTT), Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU), Erlangen, GermanyLehrstuhl für Technische Thermodynamik (LTT), Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU), Erlangen, Germany; Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU), Erlangen, GermanyLehrstuhl für Technische Thermodynamik (LTT), Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU), Erlangen, Germany; Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich‐Alexander‐Universität Erlangen‐Nürnberg (FAU), Erlangen, Germany; Corresponding author.Spray flame synthesis (SFS) is a promising technique for the production of metal-oxide nanoparticles. However, the processes involved during the synthesis are not yet fully understood. To provide a common workbench for a wide range of investigations, the standardized SpraySyn burners have been introduced. This work presents an in-depth investigation of the improved SpraySyn 2.0 burner, characterizing important droplet, combustion and particle features. The sizes of the droplets produced from an ignited ethanol spray are measured in a range between 20 mm and 45 mm height above the burner (HAB) employing wide-angle light scattering (WALS), revealing much smaller droplets compared to previous SpraySyn 1.0, which eventually leads to faster evaporation. Flame fluctuations are investigated using high-speed imaging of the flame chemiluminescence, indicating a change in fluctuation behaviour compared to the previous burner. WALS is also employed for single-shot in situ size measurements of produced iron-oxide and titanium-dioxide nanoparticles at various HABs ranging from 30 mm to 210 mm, allowing to observe the particle growth. To further assess the properties of the produced particles, extensive TEM measurements for both particle systems are conducted and evaluated. Finally, the influence of flame pulsations on particle size is investigated by coupling chemiluminescence imaging with WALS, yielding no correlation between both.http://www.sciencedirect.com/science/article/pii/S2666352X25000068Flame spray pyrolysis (FSP)SpraySyn burnerFlame fluctuationsWide-angle light scattering (WALS)Droplet sizeParticle size
spellingShingle Peter Lang
Nils E. Schneider
Franz J.T. Huber
Stefan Will
Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizes
Applications in Energy and Combustion Science
Flame spray pyrolysis (FSP)
SpraySyn burner
Flame fluctuations
Wide-angle light scattering (WALS)
Droplet size
Particle size
title Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizes
title_full Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizes
title_fullStr Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizes
title_full_unstemmed Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizes
title_short Characterization of the SpraySyn 2.0 burner: Droplet diameters, flame stability and particle sizes
title_sort characterization of the spraysyn 2 0 burner droplet diameters flame stability and particle sizes
topic Flame spray pyrolysis (FSP)
SpraySyn burner
Flame fluctuations
Wide-angle light scattering (WALS)
Droplet size
Particle size
url http://www.sciencedirect.com/science/article/pii/S2666352X25000068
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AT franzjthuber characterizationofthespraysyn20burnerdropletdiametersflamestabilityandparticlesizes
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