A comparative study on chemiluminescence propperties of some inorganic systems
Chemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photon emission, has been studied. The kinetics of the systems and their emission spectra have been characterised by measurements with the use of the stationary and the flow methods of CL recording. The systems studi...
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| Format: | Article |
| Language: | English |
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Wiley
2003-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/S1110662X03000382 |
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| author | Marian Elbanowski Krzysztof Staninski Malgorzata Kaczmarek Stefan Lis |
| author_facet | Marian Elbanowski Krzysztof Staninski Malgorzata Kaczmarek Stefan Lis |
| author_sort | Marian Elbanowski |
| collection | DOAJ |
| description | Chemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photon
emission, has been studied. The kinetics of the systems and their emission spectra have been characterised
by measurements with the use of the stationary and the flow methods of CL recording. The systems studied
contained cations at different oxidation degree such as Fe2+\3+, Cu+\2+, Co2+\3+, Eu2+\3+, CLO− anions and hydrogen peroxide without organic sensitisers. On the basis of the analysis of the spectra, in particular
systems emitters have been identified and mechanisms of the reactions have been proposed. The effect
of carbonate and azide ions and propylene carbonate on the yield of CL and spectral characterisation
of the systems studied has been evidenced and discussed. A possibility of the application of the systems Eu3+\N3− \H2O2 and Co2+\propylene carbonate\H2O2 for analytical purposes has been considered. |
| format | Article |
| id | doaj-art-c90152154ab944fe8fc9d6487fa098a7 |
| institution | OA Journals |
| issn | 1110-662X |
| language | English |
| publishDate | 2003-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Photoenergy |
| spelling | doaj-art-c90152154ab944fe8fc9d6487fa098a72025-08-20T02:19:44ZengWileyInternational Journal of Photoenergy1110-662X2003-01-015423924210.1155/S1110662X03000382A comparative study on chemiluminescence propperties of some inorganic systemsMarian Elbanowski0Krzysztof Staninski1Malgorzata Kaczmarek2Stefan Lis3Department of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandDepartment of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandDepartment of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandDepartment of Rare Earths, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań 60-780, PolandChemiluminescence (CL) of selected inorganic reaction systems, generating ultraweak photon emission, has been studied. The kinetics of the systems and their emission spectra have been characterised by measurements with the use of the stationary and the flow methods of CL recording. The systems studied contained cations at different oxidation degree such as Fe2+\3+, Cu+\2+, Co2+\3+, Eu2+\3+, CLO− anions and hydrogen peroxide without organic sensitisers. On the basis of the analysis of the spectra, in particular systems emitters have been identified and mechanisms of the reactions have been proposed. The effect of carbonate and azide ions and propylene carbonate on the yield of CL and spectral characterisation of the systems studied has been evidenced and discussed. A possibility of the application of the systems Eu3+\N3− \H2O2 and Co2+\propylene carbonate\H2O2 for analytical purposes has been considered.http://dx.doi.org/10.1155/S1110662X03000382 |
| spellingShingle | Marian Elbanowski Krzysztof Staninski Malgorzata Kaczmarek Stefan Lis A comparative study on chemiluminescence propperties of some inorganic systems International Journal of Photoenergy |
| title | A comparative study on chemiluminescence propperties of some inorganic systems |
| title_full | A comparative study on chemiluminescence propperties of some inorganic systems |
| title_fullStr | A comparative study on chemiluminescence propperties of some inorganic systems |
| title_full_unstemmed | A comparative study on chemiluminescence propperties of some inorganic systems |
| title_short | A comparative study on chemiluminescence propperties of some inorganic systems |
| title_sort | comparative study on chemiluminescence propperties of some inorganic systems |
| url | http://dx.doi.org/10.1155/S1110662X03000382 |
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