Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni)
Purification of soot particles from automobile exhaust has closely to do with the synergistic effect between catalyst metals. Here, several binary Ni-Fe oxide catalysts were elaborately prepared via a modified solvothermal method. A non-noble-metal (Ni)-modified hexagonal Fe<sub>2</sub>O...
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2025-02-01
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| author | Haoqi Guo Jing Xiong Peng Zhang Jian Liu Zhen Zhao Yuechang Wei |
| author_facet | Haoqi Guo Jing Xiong Peng Zhang Jian Liu Zhen Zhao Yuechang Wei |
| author_sort | Haoqi Guo |
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| description | Purification of soot particles from automobile exhaust has closely to do with the synergistic effect between catalyst metals. Here, several binary Ni-Fe oxide catalysts were elaborately prepared via a modified solvothermal method. A non-noble-metal (Ni)-modified hexagonal Fe<sub>2</sub>O<sub>3</sub> nano-sheet catalyst (Ni−Fe<sub>2</sub>O<sub>3</sub>) was prepared. The introduced heteroatoms replace some of the Fe atoms, which take up the surface of the [FeO<sub>6</sub>] octahedron, and the synergistic effect formed between the heteroatoms which are on the surface and the adjacent Fe atoms promotes the formation of coordination unsaturated ions of the activated reactants. The optimal performance was obtained with the Ni-Fe<sub>2</sub>O<sub>3</sub>-20 composition, with catalytic soot oxidation resulting in T<sub>50</sub>, SCO<sub>2</sub><sup>m</sup>, E<sub>a</sub> and TOF of 366 °C, 99.1%, 72.7 kJ mol<sup>−1</sup> and 0.156 min<sup>−1</sup> (at 310 °C), respectively. The combination of Ni and Fe<sub>2</sub>O<sub>3</sub> cells increases the ratio of Fe<sup>3+</sup>/Fe<sup>2+</sup>, making the interaction among electrons between the Ni, which was proved highly dispersed over the catalyst, and the Fe<sub>2</sub>O<sub>3</sub> strong. Both exist on the catalyst surface in the form of NiFe<sub>2</sub>O<sub>4</sub>. Ni atoms and Fe<sub>2</sub>O<sub>3</sub>, which demonstrate a synergistic effect, promoting the formation of coordination unsaturated ions of the activated reactants and generating more oxygen vacancies, thus promoting the adsorption of NO and accelerating the ignition of soot in O<sub>2</sub> at a low temperature. The novel Ni-Fe<sub>2</sub>O<sub>3</sub>-X oxide cocatalyst is an improved noble-free catalyst that promotes the synergistic effect between heteroatoms and metal oxides through surface regulation. This is of great significance for the further development of economic and efficient catalysts for soot particle removal from automobile exhaust. |
| format | Article |
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| spelling | doaj-art-c8d7b139c97845ccb1d10d6ef70c73482025-08-20T02:12:29ZengMDPI AGNanomaterials2079-49912025-02-0115323310.3390/nano15030233Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni)Haoqi Guo0Jing Xiong1Peng Zhang2Jian Liu3Zhen Zhao4Yuechang Wei5State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, ChinaState Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, ChinaState Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, ChinaState Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, ChinaState Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, ChinaState Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum, Beijing 102249, ChinaPurification of soot particles from automobile exhaust has closely to do with the synergistic effect between catalyst metals. Here, several binary Ni-Fe oxide catalysts were elaborately prepared via a modified solvothermal method. A non-noble-metal (Ni)-modified hexagonal Fe<sub>2</sub>O<sub>3</sub> nano-sheet catalyst (Ni−Fe<sub>2</sub>O<sub>3</sub>) was prepared. The introduced heteroatoms replace some of the Fe atoms, which take up the surface of the [FeO<sub>6</sub>] octahedron, and the synergistic effect formed between the heteroatoms which are on the surface and the adjacent Fe atoms promotes the formation of coordination unsaturated ions of the activated reactants. The optimal performance was obtained with the Ni-Fe<sub>2</sub>O<sub>3</sub>-20 composition, with catalytic soot oxidation resulting in T<sub>50</sub>, SCO<sub>2</sub><sup>m</sup>, E<sub>a</sub> and TOF of 366 °C, 99.1%, 72.7 kJ mol<sup>−1</sup> and 0.156 min<sup>−1</sup> (at 310 °C), respectively. The combination of Ni and Fe<sub>2</sub>O<sub>3</sub> cells increases the ratio of Fe<sup>3+</sup>/Fe<sup>2+</sup>, making the interaction among electrons between the Ni, which was proved highly dispersed over the catalyst, and the Fe<sub>2</sub>O<sub>3</sub> strong. Both exist on the catalyst surface in the form of NiFe<sub>2</sub>O<sub>4</sub>. Ni atoms and Fe<sub>2</sub>O<sub>3</sub>, which demonstrate a synergistic effect, promoting the formation of coordination unsaturated ions of the activated reactants and generating more oxygen vacancies, thus promoting the adsorption of NO and accelerating the ignition of soot in O<sub>2</sub> at a low temperature. The novel Ni-Fe<sub>2</sub>O<sub>3</sub>-X oxide cocatalyst is an improved noble-free catalyst that promotes the synergistic effect between heteroatoms and metal oxides through surface regulation. This is of great significance for the further development of economic and efficient catalysts for soot particle removal from automobile exhaust.https://www.mdpi.com/2079-4991/15/3/233Fe<sub>2</sub>O<sub>3</sub> nanosheetcooperative effectheteroatomic catalystsoot purification |
| spellingShingle | Haoqi Guo Jing Xiong Peng Zhang Jian Liu Zhen Zhao Yuechang Wei Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni) Nanomaterials Fe<sub>2</sub>O<sub>3</sub> nanosheet cooperative effect heteroatomic catalyst soot purification |
| title | Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni) |
| title_full | Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni) |
| title_fullStr | Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni) |
| title_full_unstemmed | Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni) |
| title_short | Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe<sub>2</sub>O<sub>3</sub> Nanosheets Decorated with Non-Noble Metals (Ni) |
| title_sort | efficient purification of auto exhaust soot particles using hexagonal fe sub 2 sub o sub 3 sub nanosheets decorated with non noble metals ni |
| topic | Fe<sub>2</sub>O<sub>3</sub> nanosheet cooperative effect heteroatomic catalyst soot purification |
| url | https://www.mdpi.com/2079-4991/15/3/233 |
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