Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solution

This study explores the effects of anodic, cathodic, and open circuit (OCP) potentials on the tribocorrosion behaviour of the UNS S32205 duplex stainless steel, which is largely used in oil, gas, and cellulose industry. For this purpose, tribocorrosion assays using a contact sphere (Si3N4) against t...

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Main Authors: Jomar José Knaip Ribeiro, Oriana Palma Calabokis, Yamid Enrique Nuñez de la Rosa, Silvio Francisco Brunatto, Paulo César Borges
Format: Article
Language:English
Published: Elsevier 2025-05-01
Series:Engineering Science and Technology, an International Journal
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Online Access:http://www.sciencedirect.com/science/article/pii/S2215098625001028
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author Jomar José Knaip Ribeiro
Oriana Palma Calabokis
Yamid Enrique Nuñez de la Rosa
Silvio Francisco Brunatto
Paulo César Borges
author_facet Jomar José Knaip Ribeiro
Oriana Palma Calabokis
Yamid Enrique Nuñez de la Rosa
Silvio Francisco Brunatto
Paulo César Borges
author_sort Jomar José Knaip Ribeiro
collection DOAJ
description This study explores the effects of anodic, cathodic, and open circuit (OCP) potentials on the tribocorrosion behaviour of the UNS S32205 duplex stainless steel, which is largely used in oil, gas, and cellulose industry. For this purpose, tribocorrosion assays using a contact sphere (Si3N4) against the specimen plane in reciprocating sliding movement in 0.5 M NaCl solution were carried out. For comparison purposes, cathodic polarization or tests without applied potential under distilled water (DW) were used to inhibit corrosion for tribocorrosion tests. Two main distinct behaviours were observed: i) high coefficients of friction and lower wear volumes at the cathodic polarization (CP) for conditions smaller or equal to –0.8 V (vs Ag/AgCl 3 M) as well as in DW; and ii) low coefficients of friction and higher wear volumes for anodic polarization (AP), OCP, and CP for –0.4 V. The tribocorrosion behaviour of both groups was directly related to the chemical characteristics inside the tracks analyzed using SEM-EDS and Raman spectroscopy. All analyzed tracks showed similar oxygen contents and chemical compositions within each group. Finally, this study allowed the determination of the great effect of the potential applied on the tribocorrosion behaviour and the identification of differences between the cathodic protection and distilled water assays as methods to inhibit corrosion.
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spelling doaj-art-c8b3ebac7b4f4f009dda33f0f750fade2025-08-20T03:03:36ZengElsevierEngineering Science and Technology, an International Journal2215-09862025-05-016510204710.1016/j.jestch.2025.102047Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solutionJomar José Knaip Ribeiro0Oriana Palma Calabokis1Yamid Enrique Nuñez de la Rosa2Silvio Francisco Brunatto3Paulo César Borges4Department of Mechanical Engineering, Federal Technological University of Paraná, Campus Ecoville, Curitiba 81280-34 Paraná, BrazilDepartment of Mechanical Engineering, Federal Technological University of Paraná, Campus Ecoville, Curitiba 81280-34 Paraná, Brazil; Fundación Universitaria Los Libertadores, Bogotá 111221, Colombia; Corresponding author at: Faculty of Engineering and Basic Sciences, Fundación Universitaria Los Libertadores, Bogotá 111221, Colombia.Department of Mechanical Engineering, Federal Technological University of Paraná, Campus Ecoville, Curitiba 81280-34 Paraná, Brazil; Fundación Universitaria Los Libertadores, Bogotá 111221, ColombiaDepartment of Mechanical Engineering, Federal University of Paraná, 81531-990 Curitiba, PR, BrazilDepartment of Mechanical Engineering, Federal Technological University of Paraná, Campus Ecoville, Curitiba 81280-34 Paraná, BrazilThis study explores the effects of anodic, cathodic, and open circuit (OCP) potentials on the tribocorrosion behaviour of the UNS S32205 duplex stainless steel, which is largely used in oil, gas, and cellulose industry. For this purpose, tribocorrosion assays using a contact sphere (Si3N4) against the specimen plane in reciprocating sliding movement in 0.5 M NaCl solution were carried out. For comparison purposes, cathodic polarization or tests without applied potential under distilled water (DW) were used to inhibit corrosion for tribocorrosion tests. Two main distinct behaviours were observed: i) high coefficients of friction and lower wear volumes at the cathodic polarization (CP) for conditions smaller or equal to –0.8 V (vs Ag/AgCl 3 M) as well as in DW; and ii) low coefficients of friction and higher wear volumes for anodic polarization (AP), OCP, and CP for –0.4 V. The tribocorrosion behaviour of both groups was directly related to the chemical characteristics inside the tracks analyzed using SEM-EDS and Raman spectroscopy. All analyzed tracks showed similar oxygen contents and chemical compositions within each group. Finally, this study allowed the determination of the great effect of the potential applied on the tribocorrosion behaviour and the identification of differences between the cathodic protection and distilled water assays as methods to inhibit corrosion.http://www.sciencedirect.com/science/article/pii/S2215098625001028Duplex stainless steelTribocorrosionCathodic protectionNaClDistilled water
spellingShingle Jomar José Knaip Ribeiro
Oriana Palma Calabokis
Yamid Enrique Nuñez de la Rosa
Silvio Francisco Brunatto
Paulo César Borges
Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solution
Engineering Science and Technology, an International Journal
Duplex stainless steel
Tribocorrosion
Cathodic protection
NaCl
Distilled water
title Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solution
title_full Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solution
title_fullStr Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solution
title_full_unstemmed Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solution
title_short Effect of polarization potential on tribocorrosion behavior of duplex stainless steel UNS S32205 in NaCl solution
title_sort effect of polarization potential on tribocorrosion behavior of duplex stainless steel uns s32205 in nacl solution
topic Duplex stainless steel
Tribocorrosion
Cathodic protection
NaCl
Distilled water
url http://www.sciencedirect.com/science/article/pii/S2215098625001028
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