Tribological behavior of ammonium-based protic ionic liquid as lubricant additive
Abstract In this study, the tribological behavior of an ammonium-based protic ionic liquid (PIL) as an additive in a base mineral oil (MO) is investigated on a steel-steel contact at room temperature and 100 °C. Tri-[bis(2-hydroxyethylammonium)] citrate (DCi) was synthesized in a simple and low-cost...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Tsinghua University Press
2020-08-01
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| Series: | Friction |
| Subjects: | |
| Online Access: | https://doi.org/10.1007/s40544-020-0378-z |
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| Summary: | Abstract In this study, the tribological behavior of an ammonium-based protic ionic liquid (PIL) as an additive in a base mineral oil (MO) is investigated on a steel-steel contact at room temperature and 100 °C. Tri-[bis(2-hydroxyethylammonium)] citrate (DCi) was synthesized in a simple and low-cost way, and the ionic structure of DCi was confirmed by proton nuclear magnetic resonance (1H NMR). The stability measurement of 1 wt% DCi to a MO was investigated, and the lubricating ability and anti-wear properties of DCi as an additive in MO were also examined using a custom-designed reciprocating ball-on-flat tribometer. Optical microscope and profilometry were used to obtain the worn morphology of the steel disks. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) were carried out to investigate the wear mechanism and to analyze the surface interactions between the rubbing components. When 1 wt% DCi is added into the base MO, frictional performance is improved at both temperatures studied with a friction reduction of 29.0% and 35.5%, respectively. Moreover, the addition of 1 wt% DCi to MO reduced the wear volume 59.4% compared to the use of MO. An oxygen-richened tribolayer is confirmed by EDS on the disk surface when DCi was used as additive under 100 °C. |
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| ISSN: | 2223-7690 2223-7704 |