Electronic properties of stacking faults in Bernal graphite

Abstract In spite of the last century of research into the physical properties of graphite, this material regularly displays new, unexpected features enabled by the variations of stacking between van der Waals coupled layers1–6. Here, we show that a stacking fault in bulk graphite hosts a band of tw...

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Main Authors: Patrick Johansen Sarsfield, Sergey Slizovskiy, Mikito Koshino, Vladimir Fal’ko
Format: Article
Language:English
Published: Nature Portfolio 2025-05-01
Series:npj Computational Materials
Online Access:https://doi.org/10.1038/s41524-025-01641-2
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author Patrick Johansen Sarsfield
Sergey Slizovskiy
Mikito Koshino
Vladimir Fal’ko
author_facet Patrick Johansen Sarsfield
Sergey Slizovskiy
Mikito Koshino
Vladimir Fal’ko
author_sort Patrick Johansen Sarsfield
collection DOAJ
description Abstract In spite of the last century of research into the physical properties of graphite, this material regularly displays new, unexpected features enabled by the variations of stacking between van der Waals coupled layers1–6. Here, we show that a stacking fault in bulk graphite hosts a band of two-dimensional electrons clearly distinguishable from the bulk carriers. Using a self-consistent tight-binding model of graphite, incorporating all Slonczewski-Weiss-McClure parameters, we compute the dispersion and quantum topological characteristics of the two dimensional band, we calculate the Landau level spectrum in magnetic field and the related Shubnikov-de Haas oscillation parameters, as well as the cyclotron mass of the two-dimensional carriers. We also show that most of the features of the fault-bound states are inherited from another celebrated graphitic system, rhombohedral trilayer graphene7, which represents the central structural block of the stacking fault.
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institution Kabale University
issn 2057-3960
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publishDate 2025-05-01
publisher Nature Portfolio
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series npj Computational Materials
spelling doaj-art-c852fde30b0f4c7586972532962a5d9f2025-08-20T03:48:18ZengNature Portfolionpj Computational Materials2057-39602025-05-011111710.1038/s41524-025-01641-2Electronic properties of stacking faults in Bernal graphitePatrick Johansen Sarsfield0Sergey Slizovskiy1Mikito Koshino2Vladimir Fal’ko3National Graphene Institute, University of ManchesterNational Graphene Institute, University of ManchesterDepartment of Physics, Osaka UniversityNational Graphene Institute, University of ManchesterAbstract In spite of the last century of research into the physical properties of graphite, this material regularly displays new, unexpected features enabled by the variations of stacking between van der Waals coupled layers1–6. Here, we show that a stacking fault in bulk graphite hosts a band of two-dimensional electrons clearly distinguishable from the bulk carriers. Using a self-consistent tight-binding model of graphite, incorporating all Slonczewski-Weiss-McClure parameters, we compute the dispersion and quantum topological characteristics of the two dimensional band, we calculate the Landau level spectrum in magnetic field and the related Shubnikov-de Haas oscillation parameters, as well as the cyclotron mass of the two-dimensional carriers. We also show that most of the features of the fault-bound states are inherited from another celebrated graphitic system, rhombohedral trilayer graphene7, which represents the central structural block of the stacking fault.https://doi.org/10.1038/s41524-025-01641-2
spellingShingle Patrick Johansen Sarsfield
Sergey Slizovskiy
Mikito Koshino
Vladimir Fal’ko
Electronic properties of stacking faults in Bernal graphite
npj Computational Materials
title Electronic properties of stacking faults in Bernal graphite
title_full Electronic properties of stacking faults in Bernal graphite
title_fullStr Electronic properties of stacking faults in Bernal graphite
title_full_unstemmed Electronic properties of stacking faults in Bernal graphite
title_short Electronic properties of stacking faults in Bernal graphite
title_sort electronic properties of stacking faults in bernal graphite
url https://doi.org/10.1038/s41524-025-01641-2
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AT sergeyslizovskiy electronicpropertiesofstackingfaultsinbernalgraphite
AT mikitokoshino electronicpropertiesofstackingfaultsinbernalgraphite
AT vladimirfalko electronicpropertiesofstackingfaultsinbernalgraphite