Electrochemical deposition of tin-copper alloy coatings

Solderable tin-base alloy coatings are widely used when assembling electronic products. The reorientation of production to lead-free technologies sets the task of developing new technological processes for the formation of coatings for electrical contacts with stable electrical properties, high sold...

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Main Authors: D. Y. Gulpa, I. I. Kuzmar, L. K. Kushner, N. V. Dezhkunov, A. A. Khmyl
Format: Article
Language:Russian
Published: Educational institution «Belarusian State University of Informatics and Radioelectronics» 2021-11-01
Series:Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioèlektroniki
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Online Access:https://doklady.bsuir.by/jour/article/view/3207
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author D. Y. Gulpa
I. I. Kuzmar
L. K. Kushner
N. V. Dezhkunov
A. A. Khmyl
author_facet D. Y. Gulpa
I. I. Kuzmar
L. K. Kushner
N. V. Dezhkunov
A. A. Khmyl
author_sort D. Y. Gulpa
collection DOAJ
description Solderable tin-base alloy coatings are widely used when assembling electronic products. The reorientation of production to lead-free technologies sets the task of developing new technological processes for the formation of coatings for electrical contacts with stable electrical properties, high soldering ability, which lasts for a long time. The features of the process of electrodeposition of coatings with a tin-copper alloy were experimentally investigated and the regularities of the influence of the electrolyte composition, current density, and ultrasound intensity on the cathode current efficiency of the alloy, the deposition rate, elemental composition, structure and functional properties of the precipitation were established. For sonochemical treatment an experimental setup developed at Research Laboratory 5.2 of BSUIR, which makes it possible to vary the intensity of ultrasonic vibrations in the range of 0.058– 1.7 W/cm2 , was used. It has been established that the use of ultrasound changes the formation mechanism of the electrochemical alloy, reduces cathodic polarization, increases the value of the limiting current and makes it possible to control the composition and structure of the precipitates. With an increase in the intensity from 0.12 to 0.95 W/cm2  the amount of copper in the coating increases by 4.5 times. The spreading coefficient of the solder is 92.59–98.44 %.
format Article
id doaj-art-c84f198b9bcb4aeeae983b34acc62a93
institution Kabale University
issn 1729-7648
language Russian
publishDate 2021-11-01
publisher Educational institution «Belarusian State University of Informatics and Radioelectronics»
record_format Article
series Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioèlektroniki
spelling doaj-art-c84f198b9bcb4aeeae983b34acc62a932025-08-20T03:45:06ZrusEducational institution «Belarusian State University of Informatics and Radioelectronics»Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioèlektroniki1729-76482021-11-01197495710.35596/1729-7648-2021-19-7-49-571744Electrochemical deposition of tin-copper alloy coatingsD. Y. Gulpa0I. I. Kuzmar1L. K. Kushner2N. V. Dezhkunov3A. A. Khmyl4Belarusian State University of Informatics and RadioelectronicsBelarusian State University of Informatics and RadioelectronicsBelarusian State University of Informatics and RadioelectronicsBelarusian State University of Informatics and RadioelectronicsBelarusian State University of Informatics and RadioelectronicsSolderable tin-base alloy coatings are widely used when assembling electronic products. The reorientation of production to lead-free technologies sets the task of developing new technological processes for the formation of coatings for electrical contacts with stable electrical properties, high soldering ability, which lasts for a long time. The features of the process of electrodeposition of coatings with a tin-copper alloy were experimentally investigated and the regularities of the influence of the electrolyte composition, current density, and ultrasound intensity on the cathode current efficiency of the alloy, the deposition rate, elemental composition, structure and functional properties of the precipitation were established. For sonochemical treatment an experimental setup developed at Research Laboratory 5.2 of BSUIR, which makes it possible to vary the intensity of ultrasonic vibrations in the range of 0.058– 1.7 W/cm2 , was used. It has been established that the use of ultrasound changes the formation mechanism of the electrochemical alloy, reduces cathodic polarization, increases the value of the limiting current and makes it possible to control the composition and structure of the precipitates. With an increase in the intensity from 0.12 to 0.95 W/cm2  the amount of copper in the coating increases by 4.5 times. The spreading coefficient of the solder is 92.59–98.44 %.https://doklady.bsuir.by/jour/article/view/3207electrochemical coatingstin-copper alloyultrasonic vibrations
spellingShingle D. Y. Gulpa
I. I. Kuzmar
L. K. Kushner
N. V. Dezhkunov
A. A. Khmyl
Electrochemical deposition of tin-copper alloy coatings
Doklady Belorusskogo gosudarstvennogo universiteta informatiki i radioèlektroniki
electrochemical coatings
tin-copper alloy
ultrasonic vibrations
title Electrochemical deposition of tin-copper alloy coatings
title_full Electrochemical deposition of tin-copper alloy coatings
title_fullStr Electrochemical deposition of tin-copper alloy coatings
title_full_unstemmed Electrochemical deposition of tin-copper alloy coatings
title_short Electrochemical deposition of tin-copper alloy coatings
title_sort electrochemical deposition of tin copper alloy coatings
topic electrochemical coatings
tin-copper alloy
ultrasonic vibrations
url https://doklady.bsuir.by/jour/article/view/3207
work_keys_str_mv AT dygulpa electrochemicaldepositionoftincopperalloycoatings
AT iikuzmar electrochemicaldepositionoftincopperalloycoatings
AT lkkushner electrochemicaldepositionoftincopperalloycoatings
AT nvdezhkunov electrochemicaldepositionoftincopperalloycoatings
AT aakhmyl electrochemicaldepositionoftincopperalloycoatings