Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory

Abstract Ovonic threshold switching (OTS) selectors based on amorphous chalcogenides can revolutionize 3D memory technology owing to their self‐selecting memory (SSM) behavior. However, the complex mechanism governing the memory writing operation limits compositional and device optimization. This st...

Full description

Saved in:
Bibliographic Details
Main Authors: Ha‐Jun Sung, Minwoo Choi, Zhe Wu, Hwasung Chae, Sung Heo, Youngjae Kang, Bonwon Koo, Jong‐Bong Park, Wooyoung Yang, Yongyoung Park, Yongnam Ham, Kiyeon Yang, Chang Seung Lee
Format: Article
Language:English
Published: Wiley 2024-11-01
Series:Advanced Science
Subjects:
Online Access:https://doi.org/10.1002/advs.202408028
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850145982482743296
author Ha‐Jun Sung
Minwoo Choi
Zhe Wu
Hwasung Chae
Sung Heo
Youngjae Kang
Bonwon Koo
Jong‐Bong Park
Wooyoung Yang
Yongyoung Park
Yongnam Ham
Kiyeon Yang
Chang Seung Lee
author_facet Ha‐Jun Sung
Minwoo Choi
Zhe Wu
Hwasung Chae
Sung Heo
Youngjae Kang
Bonwon Koo
Jong‐Bong Park
Wooyoung Yang
Yongyoung Park
Yongnam Ham
Kiyeon Yang
Chang Seung Lee
author_sort Ha‐Jun Sung
collection DOAJ
description Abstract Ovonic threshold switching (OTS) selectors based on amorphous chalcogenides can revolutionize 3D memory technology owing to their self‐selecting memory (SSM) behavior. However, the complex mechanism governing the memory writing operation limits compositional and device optimization. This study investigates the mechanism behind the polarity‐dependent threshold voltage shift (ΔVTH) through theoretical and experimental analyses. By examining the physical principles of threshold switching and conducting defect state analysis, the ΔVTH as a memory window is confirmed to be attributed to the dynamics of charged defects and their gradient near electrodes, influenced by the nonuniform electric field after threshold switching. This study provides critical insights into the operational mechanism of OTS‐based SSM, known as selector‐only memory, highlighting its advantages for developing high‐density, low‐cost, and energy‐efficient memory technologies in the artificial intelligence era.
format Article
id doaj-art-c7dd65adda154ea9b6fc8eb11864de02
institution OA Journals
issn 2198-3844
language English
publishDate 2024-11-01
publisher Wiley
record_format Article
series Advanced Science
spelling doaj-art-c7dd65adda154ea9b6fc8eb11864de022025-08-20T02:27:57ZengWileyAdvanced Science2198-38442024-11-011144n/an/a10.1002/advs.202408028Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting MemoryHa‐Jun Sung0Minwoo Choi1Zhe Wu2Hwasung Chae3Sung Heo4Youngjae Kang5Bonwon Koo6Jong‐Bong Park7Wooyoung Yang8Yongyoung Park9Yongnam Ham10Kiyeon Yang11Chang Seung Lee12Thin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaAdvanced Process Development TeamSemiconductor R&D CenterSamsung ElectronicsHwaseong‐si 18448 South KoreaAdvanced Process Development TeamSemiconductor R&D CenterSamsung ElectronicsHwaseong‐si 18448 South KoreaAnalytical Engineering GroupSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaThin Film Technical UnitSamsung Advanced Institute of TechnologySamsung ElectronicsSuwon‐si 16677 South KoreaAbstract Ovonic threshold switching (OTS) selectors based on amorphous chalcogenides can revolutionize 3D memory technology owing to their self‐selecting memory (SSM) behavior. However, the complex mechanism governing the memory writing operation limits compositional and device optimization. This study investigates the mechanism behind the polarity‐dependent threshold voltage shift (ΔVTH) through theoretical and experimental analyses. By examining the physical principles of threshold switching and conducting defect state analysis, the ΔVTH as a memory window is confirmed to be attributed to the dynamics of charged defects and their gradient near electrodes, influenced by the nonuniform electric field after threshold switching. This study provides critical insights into the operational mechanism of OTS‐based SSM, known as selector‐only memory, highlighting its advantages for developing high‐density, low‐cost, and energy‐efficient memory technologies in the artificial intelligence era.https://doi.org/10.1002/advs.202408028amorphous chalcogenidesself‐selecting memoryovonic threshold switching
spellingShingle Ha‐Jun Sung
Minwoo Choi
Zhe Wu
Hwasung Chae
Sung Heo
Youngjae Kang
Bonwon Koo
Jong‐Bong Park
Wooyoung Yang
Yongyoung Park
Yongnam Ham
Kiyeon Yang
Chang Seung Lee
Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory
Advanced Science
amorphous chalcogenides
self‐selecting memory
ovonic threshold switching
title Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory
title_full Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory
title_fullStr Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory
title_full_unstemmed Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory
title_short Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory
title_sort microscopic origin of polarity dependent vth shift in amorphous chalcogenides for 3d self selecting memory
topic amorphous chalcogenides
self‐selecting memory
ovonic threshold switching
url https://doi.org/10.1002/advs.202408028
work_keys_str_mv AT hajunsung microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT minwoochoi microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT zhewu microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT hwasungchae microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT sungheo microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT youngjaekang microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT bonwonkoo microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT jongbongpark microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT wooyoungyang microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT yongyoungpark microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT yongnamham microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT kiyeonyang microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory
AT changseunglee microscopicoriginofpolaritydependentvthshiftinamorphouschalcogenidesfor3dselfselectingmemory