Microscopic Origin of Polarity‐Dependent VTH Shift in Amorphous Chalcogenides for 3D Self‐Selecting Memory

Abstract Ovonic threshold switching (OTS) selectors based on amorphous chalcogenides can revolutionize 3D memory technology owing to their self‐selecting memory (SSM) behavior. However, the complex mechanism governing the memory writing operation limits compositional and device optimization. This st...

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Main Authors: Ha‐Jun Sung, Minwoo Choi, Zhe Wu, Hwasung Chae, Sung Heo, Youngjae Kang, Bonwon Koo, Jong‐Bong Park, Wooyoung Yang, Yongyoung Park, Yongnam Ham, Kiyeon Yang, Chang Seung Lee
Format: Article
Language:English
Published: Wiley 2024-11-01
Series:Advanced Science
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Online Access:https://doi.org/10.1002/advs.202408028
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Summary:Abstract Ovonic threshold switching (OTS) selectors based on amorphous chalcogenides can revolutionize 3D memory technology owing to their self‐selecting memory (SSM) behavior. However, the complex mechanism governing the memory writing operation limits compositional and device optimization. This study investigates the mechanism behind the polarity‐dependent threshold voltage shift (ΔVTH) through theoretical and experimental analyses. By examining the physical principles of threshold switching and conducting defect state analysis, the ΔVTH as a memory window is confirmed to be attributed to the dynamics of charged defects and their gradient near electrodes, influenced by the nonuniform electric field after threshold switching. This study provides critical insights into the operational mechanism of OTS‐based SSM, known as selector‐only memory, highlighting its advantages for developing high‐density, low‐cost, and energy‐efficient memory technologies in the artificial intelligence era.
ISSN:2198-3844