Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin Compound
Presence of active functional groups on polymer chain is a suitable aspect of polymer structure which allows performing next favourite reactions on polymer molecule. In this research a novel aromatic derivative of cis-but-2-endiol was synthesized as monomer. The synthesized monomer was polymerized u...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/345713 |
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| _version_ | 1849473311777488896 |
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| author | A. H. Massoudi N. Ramazanian H. Vahedi J. Khodabakhshi |
| author_facet | A. H. Massoudi N. Ramazanian H. Vahedi J. Khodabakhshi |
| author_sort | A. H. Massoudi |
| collection | DOAJ |
| description | Presence of active functional groups on polymer chain is a suitable aspect of polymer structure which allows performing next favourite reactions on polymer molecule. In this research a novel aromatic derivative of cis-but-2-endiol was synthesized as monomer. The synthesized monomer was polymerized using diphenyl carbonate and 1,4-butandiol as second and third monomer along with organotin catalyst. Polymerization reaction performed by using melt-phase transesterification process to produce a new terpolymer of polycarbonate. During the reaction the double bonds are preserved on polymer chain and epoxidized by m-chloroperbenzoic acid (MCBPA) in good yield to demonstrate the reactivity and possibility of performing further reactions on double bonds of polymer. |
| format | Article |
| id | doaj-art-c7c00fda013a4c09850da8cb27fc8b67 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-c7c00fda013a4c09850da8cb27fc8b672025-08-20T03:24:11ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018S1S318S32210.1155/2011/345713Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin CompoundA. H. Massoudi0N. Ramazanian1H. Vahedi2J. Khodabakhshi3Chemistry Department, Payame Noor University, Tehran-19395-4697, IranChemnitz University of Technology, Institute of Chemistry, Organic Chemistry, Strasse der Nationen-62, Chemnitz-09111, GermanyChemistry Department, Payame Noor University, Tehran-19395-4697, IranKhouzestan Petrochemical Company, Mahshahr, IranPresence of active functional groups on polymer chain is a suitable aspect of polymer structure which allows performing next favourite reactions on polymer molecule. In this research a novel aromatic derivative of cis-but-2-endiol was synthesized as monomer. The synthesized monomer was polymerized using diphenyl carbonate and 1,4-butandiol as second and third monomer along with organotin catalyst. Polymerization reaction performed by using melt-phase transesterification process to produce a new terpolymer of polycarbonate. During the reaction the double bonds are preserved on polymer chain and epoxidized by m-chloroperbenzoic acid (MCBPA) in good yield to demonstrate the reactivity and possibility of performing further reactions on double bonds of polymer.http://dx.doi.org/10.1155/2011/345713 |
| spellingShingle | A. H. Massoudi N. Ramazanian H. Vahedi J. Khodabakhshi Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin Compound E-Journal of Chemistry |
| title | Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin Compound |
| title_full | Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin Compound |
| title_fullStr | Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin Compound |
| title_full_unstemmed | Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin Compound |
| title_short | Synthesis, Characterization and Epoxidation of cis-Enriched New Polycarbonates Catalyzed by Efficient Organotin Compound |
| title_sort | synthesis characterization and epoxidation of cis enriched new polycarbonates catalyzed by efficient organotin compound |
| url | http://dx.doi.org/10.1155/2011/345713 |
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