Simple diffusion model of cage effect
On the assumption of the initial Gaussian distribution of the inter-radical distances the dependence of the radical combination probability in a solvent cage on the viscosity and temperature was derived. The dependence describes the published data correctly and may be used for the initial inter-radi...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2014-12-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/424 |
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| _version_ | 1850027808855687168 |
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| author | E. I. Finkelshteyn |
| author_facet | E. I. Finkelshteyn |
| author_sort | E. I. Finkelshteyn |
| collection | DOAJ |
| description | On the assumption of the initial Gaussian distribution of the inter-radical distances the dependence of the radical combination probability in a solvent cage on the viscosity and temperature was derived. The dependence describes the published data correctly and may be used for the initial inter-radical distances estimation in different radical pairs. |
| format | Article |
| id | doaj-art-c7acd3e143c243108bbc8ad6c7e98797 |
| institution | DOAJ |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2014-12-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-c7acd3e143c243108bbc8ad6c7e987972025-08-20T03:00:01ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752014-12-01966974418Simple diffusion model of cage effectE. I. Finkelshteyn0M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571On the assumption of the initial Gaussian distribution of the inter-radical distances the dependence of the radical combination probability in a solvent cage on the viscosity and temperature was derived. The dependence describes the published data correctly and may be used for the initial inter-radical distances estimation in different radical pairs.https://www.finechem-mirea.ru/jour/article/view/424cage effect, viscosity, radical recombination, inter-radical distances in cage. |
| spellingShingle | E. I. Finkelshteyn Simple diffusion model of cage effect Тонкие химические технологии cage effect, viscosity, radical recombination, inter-radical distances in cage. |
| title | Simple diffusion model of cage effect |
| title_full | Simple diffusion model of cage effect |
| title_fullStr | Simple diffusion model of cage effect |
| title_full_unstemmed | Simple diffusion model of cage effect |
| title_short | Simple diffusion model of cage effect |
| title_sort | simple diffusion model of cage effect |
| topic | cage effect, viscosity, radical recombination, inter-radical distances in cage. |
| url | https://www.finechem-mirea.ru/jour/article/view/424 |
| work_keys_str_mv | AT eifinkelshteyn simplediffusionmodelofcageeffect |