Simple diffusion model of cage effect
On the assumption of the initial Gaussian distribution of the inter-radical distances the dependence of the radical combination probability in a solvent cage on the viscosity and temperature was derived. The dependence describes the published data correctly and may be used for the initial inter-radi...
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| Main Author: | |
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| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2014-12-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/424 |
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| Summary: | On the assumption of the initial Gaussian distribution of the inter-radical distances the dependence of the radical combination probability in a solvent cage on the viscosity and temperature was derived. The dependence describes the published data correctly and may be used for the initial inter-radical distances estimation in different radical pairs. |
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| ISSN: | 2410-6593 2686-7575 |