Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticles

Fe3O4 (NPS-M) and FePO4 (NPS-P) nanoparticles, as representative magnetic materials, have been widely used in the industrial and biomedical fields, although their use in agriculture still needs to be evaluated. The effect of NPS-M and NPS-P in tomato plants was investigated by a combination of pheno...

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Main Authors: Valerio Petruccelli, Emanuele Vaccarella, Emma Cocco, Francesco Mura, Domenico Rosa, Alessio Talone, Martina Iazzetta, Chiara Dal Bosco, Alessandra Gentili, Luca Di Palma, Silvia Canepari, Gabriella Pasqua, Elisa Brasili, Lorenzo Massimi
Format: Article
Language:English
Published: Elsevier 2025-08-01
Series:Plant Nano Biology
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Online Access:http://www.sciencedirect.com/science/article/pii/S277311112500049X
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author Valerio Petruccelli
Emanuele Vaccarella
Emma Cocco
Francesco Mura
Domenico Rosa
Alessio Talone
Martina Iazzetta
Chiara Dal Bosco
Alessandra Gentili
Luca Di Palma
Silvia Canepari
Gabriella Pasqua
Elisa Brasili
Lorenzo Massimi
author_facet Valerio Petruccelli
Emanuele Vaccarella
Emma Cocco
Francesco Mura
Domenico Rosa
Alessio Talone
Martina Iazzetta
Chiara Dal Bosco
Alessandra Gentili
Luca Di Palma
Silvia Canepari
Gabriella Pasqua
Elisa Brasili
Lorenzo Massimi
author_sort Valerio Petruccelli
collection DOAJ
description Fe3O4 (NPS-M) and FePO4 (NPS-P) nanoparticles, as representative magnetic materials, have been widely used in the industrial and biomedical fields, although their use in agriculture still needs to be evaluated. The effect of NPS-M and NPS-P in tomato plants was investigated by a combination of phenotypic and metabolic approaches. Tomato plants were grown in soil treated with NPS-M and NPS-P at 0, 5, 50, 100, 500 and 1000 ppm for 8 months. Plant biomass, phenolics and carotenoids in leaves and fruits, soil pH, chlorophyll, and ionome of soil, fruits, roots and leaves, were analysed. NPS-M and NPS-P at higher concentrations increased biomass, total chlorophyll and carotenoid levels in leaves compared to controls. NPS-P caused the major soil acidification, making some nutrients more available to the roots. Although no significant differences were observed in fruit carotenoids, a significant increase in chlorogenic and luteone hexoside levels was observed after NPs treatment at low concentrations compared to controls. Inductively coupled plasma mass spectrometry (ICP-MS) revealed that both NPs compared to EDTA-based chelators resulted in differential element accumulation in roots, leaves/fruits. EDTA-based treatments increased leaf accumulation of Cr, As, K, P, while both NPs increased leaf accumulation of Ca, Co, Sr, Ti, V. Fruit accumulation of Ca, K, and Rb was higher with NPs, while Na, Mg, and P were higher with EDTA-based chelators. The obtained results offer new insights into the response of tomato plants to NPS-M and NPS-P exposure and could be useful for designing alternative strategies to the use of commercial fertilizers.
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spelling doaj-art-c747ae5e9fb648e891aa2e0fda9a336b2025-08-20T03:41:26ZengElsevierPlant Nano Biology2773-11112025-08-011310018210.1016/j.plana.2025.100182Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticlesValerio Petruccelli0Emanuele Vaccarella1Emma Cocco2Francesco Mura3Domenico Rosa4Alessio Talone5Martina Iazzetta6Chiara Dal Bosco7Alessandra Gentili8Luca Di Palma9Silvia Canepari10Gabriella Pasqua11Elisa Brasili12Lorenzo Massimi13Department of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Chemical Engineering Materials Environment & UdR INSTM, Sapienza-Università di Roma, Via Eudossiana 18, Roma 00184, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Chemistry, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Chemistry, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Chemical Engineering Materials Environment & UdR INSTM, Sapienza-Università di Roma, Via Eudossiana 18, Roma 00184, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyDepartment of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, Italy; Corresponding author.Department of Environmental Biology, Sapienza-Università di Roma, Piazzale Aldo Moro 5, Roma 00185, ItalyFe3O4 (NPS-M) and FePO4 (NPS-P) nanoparticles, as representative magnetic materials, have been widely used in the industrial and biomedical fields, although their use in agriculture still needs to be evaluated. The effect of NPS-M and NPS-P in tomato plants was investigated by a combination of phenotypic and metabolic approaches. Tomato plants were grown in soil treated with NPS-M and NPS-P at 0, 5, 50, 100, 500 and 1000 ppm for 8 months. Plant biomass, phenolics and carotenoids in leaves and fruits, soil pH, chlorophyll, and ionome of soil, fruits, roots and leaves, were analysed. NPS-M and NPS-P at higher concentrations increased biomass, total chlorophyll and carotenoid levels in leaves compared to controls. NPS-P caused the major soil acidification, making some nutrients more available to the roots. Although no significant differences were observed in fruit carotenoids, a significant increase in chlorogenic and luteone hexoside levels was observed after NPs treatment at low concentrations compared to controls. Inductively coupled plasma mass spectrometry (ICP-MS) revealed that both NPs compared to EDTA-based chelators resulted in differential element accumulation in roots, leaves/fruits. EDTA-based treatments increased leaf accumulation of Cr, As, K, P, while both NPs increased leaf accumulation of Ca, Co, Sr, Ti, V. Fruit accumulation of Ca, K, and Rb was higher with NPs, while Na, Mg, and P were higher with EDTA-based chelators. The obtained results offer new insights into the response of tomato plants to NPS-M and NPS-P exposure and could be useful for designing alternative strategies to the use of commercial fertilizers.http://www.sciencedirect.com/science/article/pii/S277311112500049XNanoparticlesSolanum lycopersicumIonomicsMetabolic profiling
spellingShingle Valerio Petruccelli
Emanuele Vaccarella
Emma Cocco
Francesco Mura
Domenico Rosa
Alessio Talone
Martina Iazzetta
Chiara Dal Bosco
Alessandra Gentili
Luca Di Palma
Silvia Canepari
Gabriella Pasqua
Elisa Brasili
Lorenzo Massimi
Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticles
Plant Nano Biology
Nanoparticles
Solanum lycopersicum
Ionomics
Metabolic profiling
title Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticles
title_full Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticles
title_fullStr Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticles
title_full_unstemmed Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticles
title_short Physiological, metabolic and ionomic responses of Solanum lycopersicum plants to Fe3O4 and FePO4 nanoparticles
title_sort physiological metabolic and ionomic responses of solanum lycopersicum plants to fe3o4 and fepo4 nanoparticles
topic Nanoparticles
Solanum lycopersicum
Ionomics
Metabolic profiling
url http://www.sciencedirect.com/science/article/pii/S277311112500049X
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