Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate
In the lanthanide complexes with some organic ligands, the use of pyridine-2,6-dicarboxylic acid derivatives as sensitizers was better than using others. In this paper, dimethyl 4-(2-(2,6-bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate (DVDPA) was synthesized starting from dimethy...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2018-01-01
|
| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2018/9536838 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832564852623671296 |
|---|---|
| author | Xiaobing Liu Yulin Hu Wei Fu |
| author_facet | Xiaobing Liu Yulin Hu Wei Fu |
| author_sort | Xiaobing Liu |
| collection | DOAJ |
| description | In the lanthanide complexes with some organic ligands, the use of pyridine-2,6-dicarboxylic acid derivatives as sensitizers was better than using others. In this paper, dimethyl 4-(2-(2,6-bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate (DVDPA) was synthesized starting from dimethyl 4-(chloromethyl)pyridine-2,6-dicarboxylate (CMDPA) catalyzed by ionic liquid [bmim]OH. The results indicated that the catalytic system presented the highest catalytic activity in the case of 60°C and 40 min and DVDPA yield of 83% can be obtained when ionic liquid dosage is 10% of reactant. The ionic liquid [bmim]OH can be recycled five times without obviously decreasing the catalytic activity after vacuum drying dehydration and the stability of the yield of DVDPA can be maintained. |
| format | Article |
| id | doaj-art-c72c347b362c40dfac968ecdce10dbed |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-c72c347b362c40dfac968ecdce10dbed2025-02-03T01:10:09ZengWileyJournal of Chemistry2090-90632090-90712018-01-01201810.1155/2018/95368389536838Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylateXiaobing Liu0Yulin Hu1Wei Fu2School of Chemistry and Chemical Engineering, Jinggangshan University, Ji’an 343009, ChinaCollege of Materials and Chemical Engineering, China Three Gorges University, Yichang 443002, ChinaSchool of Mathematics and Physics, Jinggangshan University, Ji’an 343009, ChinaIn the lanthanide complexes with some organic ligands, the use of pyridine-2,6-dicarboxylic acid derivatives as sensitizers was better than using others. In this paper, dimethyl 4-(2-(2,6-bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate (DVDPA) was synthesized starting from dimethyl 4-(chloromethyl)pyridine-2,6-dicarboxylate (CMDPA) catalyzed by ionic liquid [bmim]OH. The results indicated that the catalytic system presented the highest catalytic activity in the case of 60°C and 40 min and DVDPA yield of 83% can be obtained when ionic liquid dosage is 10% of reactant. The ionic liquid [bmim]OH can be recycled five times without obviously decreasing the catalytic activity after vacuum drying dehydration and the stability of the yield of DVDPA can be maintained.http://dx.doi.org/10.1155/2018/9536838 |
| spellingShingle | Xiaobing Liu Yulin Hu Wei Fu Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate Journal of Chemistry |
| title | Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate |
| title_full | Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate |
| title_fullStr | Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate |
| title_full_unstemmed | Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate |
| title_short | Basic Ionic Liquid as Catalyst in Synthesis of Dimethyl 4-(2-(2,6-Bis(methoxycarbonyl)pyridine-4-yl)vinyl)pyridine-2,6-dicarboxylate |
| title_sort | basic ionic liquid as catalyst in synthesis of dimethyl 4 2 2 6 bis methoxycarbonyl pyridine 4 yl vinyl pyridine 2 6 dicarboxylate |
| url | http://dx.doi.org/10.1155/2018/9536838 |
| work_keys_str_mv | AT xiaobingliu basicionicliquidascatalystinsynthesisofdimethyl4226bismethoxycarbonylpyridine4ylvinylpyridine26dicarboxylate AT yulinhu basicionicliquidascatalystinsynthesisofdimethyl4226bismethoxycarbonylpyridine4ylvinylpyridine26dicarboxylate AT weifu basicionicliquidascatalystinsynthesisofdimethyl4226bismethoxycarbonylpyridine4ylvinylpyridine26dicarboxylate |