Enantioselective Cleavage of meso-Nitrodiol Diacetates by an Esterase Concentrate from Fresh Pig Liver: Preparation of Useful Nitroaliphatic Building Blocks for EPC Syntheses
Diacetates of meso-2-nitro-1,3-diols, readily available from nitroalkanes and aldehydes, are saponified to crystalline monoacetates of > 97% ee by pig liver esterase (PLE). A general discussion of this type of EPC synthesis (EPC: enantiomerically pure compounds) is given, and a specific example...
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| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1986-09-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9749 |
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