Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAV

The yak milk Lala (YMLL) from four regions of Tibet were used as the research object, and the headspace-solid phase microextraction combined with gas chromatography-mass spectrometry (HS-SPME-GC-MS) and odor activity value (OAV) were used to identify the key aromatic substances. Additionally, partia...

Full description

Saved in:
Bibliographic Details
Main Authors: Chuang DONG, Hui XU, Yahui ZHU, Lin YANG
Format: Article
Language:zho
Published: The editorial department of Science and Technology of Food Industry 2025-05-01
Series:Shipin gongye ke-ji
Subjects:
Online Access:http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2024060151
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849312040221409280
author Chuang DONG
Hui XU
Yahui ZHU
Lin YANG
author_facet Chuang DONG
Hui XU
Yahui ZHU
Lin YANG
author_sort Chuang DONG
collection DOAJ
description The yak milk Lala (YMLL) from four regions of Tibet were used as the research object, and the headspace-solid phase microextraction combined with gas chromatography-mass spectrometry (HS-SPME-GC-MS) and odor activity value (OAV) were used to identify the key aromatic substances. Additionally, partial least squares discriminant analysis (OPLS-DA) was utilized to explore the key aroma and different components of Lala at different regions, which aimed to analyze the key aroma substances of YMLL in Tibet. The results revealed that 88 volatile components were detected in YMLL at the four regions, which were primarily acids, alcohols, aldehydes, esters, ketones and aromatic compounds. Twenty-nine volatile components with OAV≥1 by threshold value were screened. Furthermore, through a combination of OAV≥1 and impact analysis of projection variables (VIP)>1, 9 characteristic volatile substances as the difference markers of YMLL flavor in the four regions were further identified, that included 2R,3R-butanediol, nonone, butanediol, isovaleric acid, n-methyl-2-pyrrolidine, acetic acid, isobutyric acid, maltol and myristic acid, respectively. The OAV, cluster heat map and OPLS-DA was used to indicate differences in key aroma components of YMLL at different altitudes. The characteristic flavors of Lala in four regions were well distinguished according to these 9 characteristic volatile substances selected by VIP, 2R,3R-butanediol, nonone, butanediol, n-methyl-2-pyrrole formaldehyde and acetic acid gave DXLL sweet taste with grassy notes along with roasted nuts and light sweet-and-sour taste respectively. Isovaleric acid, acetic acid, maltol and myristic acid gave DLLL special sour taste, burnt cream and coco nut aroma respectively. Isovaleric acid and isobutyric acid gave BGLL sour taste. The key aroma composition of YMLL was unveiled in this study, while data support was provided for the elucidation of its characteristic aroma formation, theoretical guidance was additionally offered for the industrial-scale production of YMLL through systematic biochemical characterization.
format Article
id doaj-art-c6f2e7f8246746c0ada5cac33595606c
institution Kabale University
issn 1002-0306
language zho
publishDate 2025-05-01
publisher The editorial department of Science and Technology of Food Industry
record_format Article
series Shipin gongye ke-ji
spelling doaj-art-c6f2e7f8246746c0ada5cac33595606c2025-08-20T03:53:12ZzhoThe editorial department of Science and Technology of Food IndustryShipin gongye ke-ji1002-03062025-05-01461028129010.13386/j.issn1002-0306.20240601512024060151-10Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAVChuang DONG0Hui XU1Yahui ZHU2Lin YANG3College of Food Science, Tibet Agricultural and Animal Husbandry University, Nyingchi 860000, ChinaCollege of Food Science, Tibet Agricultural and Animal Husbandry University, Nyingchi 860000, ChinaCollege of Food Science, Tibet Agricultural and Animal Husbandry University, Nyingchi 860000, ChinaCollege of Food Science, Tibet Agricultural and Animal Husbandry University, Nyingchi 860000, ChinaThe yak milk Lala (YMLL) from four regions of Tibet were used as the research object, and the headspace-solid phase microextraction combined with gas chromatography-mass spectrometry (HS-SPME-GC-MS) and odor activity value (OAV) were used to identify the key aromatic substances. Additionally, partial least squares discriminant analysis (OPLS-DA) was utilized to explore the key aroma and different components of Lala at different regions, which aimed to analyze the key aroma substances of YMLL in Tibet. The results revealed that 88 volatile components were detected in YMLL at the four regions, which were primarily acids, alcohols, aldehydes, esters, ketones and aromatic compounds. Twenty-nine volatile components with OAV≥1 by threshold value were screened. Furthermore, through a combination of OAV≥1 and impact analysis of projection variables (VIP)>1, 9 characteristic volatile substances as the difference markers of YMLL flavor in the four regions were further identified, that included 2R,3R-butanediol, nonone, butanediol, isovaleric acid, n-methyl-2-pyrrolidine, acetic acid, isobutyric acid, maltol and myristic acid, respectively. The OAV, cluster heat map and OPLS-DA was used to indicate differences in key aroma components of YMLL at different altitudes. The characteristic flavors of Lala in four regions were well distinguished according to these 9 characteristic volatile substances selected by VIP, 2R,3R-butanediol, nonone, butanediol, n-methyl-2-pyrrole formaldehyde and acetic acid gave DXLL sweet taste with grassy notes along with roasted nuts and light sweet-and-sour taste respectively. Isovaleric acid, acetic acid, maltol and myristic acid gave DLLL special sour taste, burnt cream and coco nut aroma respectively. Isovaleric acid and isobutyric acid gave BGLL sour taste. The key aroma composition of YMLL was unveiled in this study, while data support was provided for the elucidation of its characteristic aroma formation, theoretical guidance was additionally offered for the industrial-scale production of YMLL through systematic biochemical characterization.http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2024060151lalaheadspace-solid phase microextraction-gas chromatography-mass spectrometry (hs-spme-gc-ms)odor activity value (oav)partial least squares discriminant analysis (opls-da)
spellingShingle Chuang DONG
Hui XU
Yahui ZHU
Lin YANG
Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAV
Shipin gongye ke-ji
lala
headspace-solid phase microextraction-gas chromatography-mass spectrometry (hs-spme-gc-ms)
odor activity value (oav)
partial least squares discriminant analysis (opls-da)
title Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAV
title_full Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAV
title_fullStr Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAV
title_full_unstemmed Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAV
title_short Analysis of Key Aroma Presenting Substances in Yak Milk Lala from Different Regions of Tibet Based on HS-SPME-GC-MS and OAV
title_sort analysis of key aroma presenting substances in yak milk lala from different regions of tibet based on hs spme gc ms and oav
topic lala
headspace-solid phase microextraction-gas chromatography-mass spectrometry (hs-spme-gc-ms)
odor activity value (oav)
partial least squares discriminant analysis (opls-da)
url http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2024060151
work_keys_str_mv AT chuangdong analysisofkeyaromapresentingsubstancesinyakmilklalafromdifferentregionsoftibetbasedonhsspmegcmsandoav
AT huixu analysisofkeyaromapresentingsubstancesinyakmilklalafromdifferentregionsoftibetbasedonhsspmegcmsandoav
AT yahuizhu analysisofkeyaromapresentingsubstancesinyakmilklalafromdifferentregionsoftibetbasedonhsspmegcmsandoav
AT linyang analysisofkeyaromapresentingsubstancesinyakmilklalafromdifferentregionsoftibetbasedonhsspmegcmsandoav