A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar Cells

Granular ZnO nanostructures of single-crystalline wurtzite hexagonal phases were synthesized by a facile and low-cost chemical method in aqueous condition. The average size of ZnO nanograin increased with reflux time, and it significantly affected the open circuit potential (Voc) while the short cir...

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Main Authors: Md. Mahbubur Rahman, Narayan Chandra Deb Nath, Kwang-Mo Noh, Jaecheon Kim, Jae-Joon Lee
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2013/563170
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author Md. Mahbubur Rahman
Narayan Chandra Deb Nath
Kwang-Mo Noh
Jaecheon Kim
Jae-Joon Lee
author_facet Md. Mahbubur Rahman
Narayan Chandra Deb Nath
Kwang-Mo Noh
Jaecheon Kim
Jae-Joon Lee
author_sort Md. Mahbubur Rahman
collection DOAJ
description Granular ZnO nanostructures of single-crystalline wurtzite hexagonal phases were synthesized by a facile and low-cost chemical method in aqueous condition. The average size of ZnO nanograin increased with reflux time, and it significantly affected the open circuit potential (Voc) while the short circuit current density (Jsc) was not changed much. The overall energy conversion efficiency was 1.82% with the smaller grain size of ca. 250 nm when it was used as photoelectrode of DSSCs. The positive shifting of the Fermi energy (EF) and low density of surface states (DOS) were consistent with the reduction of the recombination of excited electron with electrolyte for smaller grains.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-c6a4bb352ecb4a1fbdb08751787ba2222025-02-03T06:13:47ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2013-01-01201310.1155/2013/563170563170A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar CellsMd. Mahbubur Rahman0Narayan Chandra Deb Nath1Kwang-Mo Noh2Jaecheon Kim3Jae-Joon Lee4Department of Advanced Technology Fusion, Konkuk University, Seoul 143-701, Republic of KoreaDepartment of Advanced Technology Fusion, Konkuk University, Seoul 143-701, Republic of KoreaNanotechnology Research Center and Department of Nano Science and Mechanical Engineering, Konkuk University, Chungju 380-701, Republic of KoreaNanotechnology Research Center and Department of Applied Chemistry, Konkuk University, Chungju 380-701, Republic of KoreaDepartment of Advanced Technology Fusion, Konkuk University, Seoul 143-701, Republic of KoreaGranular ZnO nanostructures of single-crystalline wurtzite hexagonal phases were synthesized by a facile and low-cost chemical method in aqueous condition. The average size of ZnO nanograin increased with reflux time, and it significantly affected the open circuit potential (Voc) while the short circuit current density (Jsc) was not changed much. The overall energy conversion efficiency was 1.82% with the smaller grain size of ca. 250 nm when it was used as photoelectrode of DSSCs. The positive shifting of the Fermi energy (EF) and low density of surface states (DOS) were consistent with the reduction of the recombination of excited electron with electrolyte for smaller grains.http://dx.doi.org/10.1155/2013/563170
spellingShingle Md. Mahbubur Rahman
Narayan Chandra Deb Nath
Kwang-Mo Noh
Jaecheon Kim
Jae-Joon Lee
A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar Cells
International Journal of Photoenergy
title A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar Cells
title_full A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar Cells
title_fullStr A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar Cells
title_full_unstemmed A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar Cells
title_short A Facile Synthesis of Granular ZnO Nanostructures for Dye-Sensitized Solar Cells
title_sort facile synthesis of granular zno nanostructures for dye sensitized solar cells
url http://dx.doi.org/10.1155/2013/563170
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