Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast Photonics
Abstract As a typical transition metal oxide, α‐Fe2O3 has garnered significant attention due to its advantages in nonlinear optical applications, such as strong third‐order nonlinearity and fast carrier recovery time. To delve into the nonlinear optical properties of α‐Fe2O3, crystalline α‐Fe2O3 mat...
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Wiley
2025-05-01
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| Online Access: | https://doi.org/10.1002/advs.202500896 |
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| author | Qingxi Zhao Qingling Tang Hongwei Chu Zhongben Pan Han Pan Shengzhi Zhao Dechun Li |
| author_facet | Qingxi Zhao Qingling Tang Hongwei Chu Zhongben Pan Han Pan Shengzhi Zhao Dechun Li |
| author_sort | Qingxi Zhao |
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| description | Abstract As a typical transition metal oxide, α‐Fe2O3 has garnered significant attention due to its advantages in nonlinear optical applications, such as strong third‐order nonlinearity and fast carrier recovery time. To delve into the nonlinear optical properties of α‐Fe2O3, crystalline α‐Fe2O3 materials with different microstructures are prepared. The nonlinear optical features of α‐Fe2O3 calcined at the previously unexplored ultra‐high temperature of >1100°C are emphasized. It is found that α‐Fe2O3 exposed to ultra‐high temperatures undergoes the phase transition, leading to the formation of Fe3O4. Subsequently, the nonlinear absorption coefficient is measured as −0.6280 cm GW−1 at 1.5 µm. The modulation depth and saturation intensity for the Fe2O3‐based saturable absorber at 1.5 µm are 4.20% and 13.94 MW cm−2, respectively. Ultimately, the incorporation of the Fe2O3‐based saturable absorber into an Er‐doped fiber laser cavity resulted in the achievement of both conventional soliton mode‐locking operation with a central wavelength of 1560.3 nm and a pulse duration of 1.13 ps, as well as the dissipative soliton resonance mode‐locking operation with a central wavelength near 1564.0 nm. Overall, the phase transition and the nonlinear optical features in iron oxides under ultra‐high temperatures are revealed, indicating the great potential in advanced ultrafast photonic applications. |
| format | Article |
| id | doaj-art-c69c0209eef045f1b007ccb83d3bb9b2 |
| institution | Kabale University |
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| language | English |
| publishDate | 2025-05-01 |
| publisher | Wiley |
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| spelling | doaj-art-c69c0209eef045f1b007ccb83d3bb9b22025-08-20T03:25:16ZengWileyAdvanced Science2198-38442025-05-011218n/an/a10.1002/advs.202500896Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast PhotonicsQingxi Zhao0Qingling Tang1Hongwei Chu2Zhongben Pan3Han Pan4Shengzhi Zhao5Dechun Li6School of Information Science and Engineering and Key Laboratory of Laser and Infrared System of Ministry of Education Shandong University Qingdao 266237 ChinaSchool of Information Science and Engineering and Key Laboratory of Laser and Infrared System of Ministry of Education Shandong University Qingdao 266237 ChinaSchool of Information Science and Engineering and Key Laboratory of Laser and Infrared System of Ministry of Education Shandong University Qingdao 266237 ChinaSchool of Information Science and Engineering and Key Laboratory of Laser and Infrared System of Ministry of Education Shandong University Qingdao 266237 ChinaSchool of Information Science and Engineering and Key Laboratory of Laser and Infrared System of Ministry of Education Shandong University Qingdao 266237 ChinaSchool of Information Science and Engineering and Key Laboratory of Laser and Infrared System of Ministry of Education Shandong University Qingdao 266237 ChinaSchool of Information Science and Engineering and Key Laboratory of Laser and Infrared System of Ministry of Education Shandong University Qingdao 266237 ChinaAbstract As a typical transition metal oxide, α‐Fe2O3 has garnered significant attention due to its advantages in nonlinear optical applications, such as strong third‐order nonlinearity and fast carrier recovery time. To delve into the nonlinear optical properties of α‐Fe2O3, crystalline α‐Fe2O3 materials with different microstructures are prepared. The nonlinear optical features of α‐Fe2O3 calcined at the previously unexplored ultra‐high temperature of >1100°C are emphasized. It is found that α‐Fe2O3 exposed to ultra‐high temperatures undergoes the phase transition, leading to the formation of Fe3O4. Subsequently, the nonlinear absorption coefficient is measured as −0.6280 cm GW−1 at 1.5 µm. The modulation depth and saturation intensity for the Fe2O3‐based saturable absorber at 1.5 µm are 4.20% and 13.94 MW cm−2, respectively. Ultimately, the incorporation of the Fe2O3‐based saturable absorber into an Er‐doped fiber laser cavity resulted in the achievement of both conventional soliton mode‐locking operation with a central wavelength of 1560.3 nm and a pulse duration of 1.13 ps, as well as the dissipative soliton resonance mode‐locking operation with a central wavelength near 1564.0 nm. Overall, the phase transition and the nonlinear optical features in iron oxides under ultra‐high temperatures are revealed, indicating the great potential in advanced ultrafast photonic applications.https://doi.org/10.1002/advs.202500896mode‐lockingnonlinear optical propertiesphase transitionultra‐high temperatureα‐Fe2O3 |
| spellingShingle | Qingxi Zhao Qingling Tang Hongwei Chu Zhongben Pan Han Pan Shengzhi Zhao Dechun Li Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast Photonics Advanced Science mode‐locking nonlinear optical properties phase transition ultra‐high temperature α‐Fe2O3 |
| title | Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast Photonics |
| title_full | Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast Photonics |
| title_fullStr | Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast Photonics |
| title_full_unstemmed | Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast Photonics |
| title_short | Ultra‐High Temperature Calcination of Crystalline α‐Fe2O3 and Its Nonlinear Optical Properties for Ultrafast Photonics |
| title_sort | ultra high temperature calcination of crystalline α fe2o3 and its nonlinear optical properties for ultrafast photonics |
| topic | mode‐locking nonlinear optical properties phase transition ultra‐high temperature α‐Fe2O3 |
| url | https://doi.org/10.1002/advs.202500896 |
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