Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to Ammonia

As an important chemical raw material, ammonia is mainly produced by the traditional Haber-Bosch process, which has certain limitations such as high energy consumption, high safety responsibility, and severe pollution, thereby having negative impacts on ecosystem. The synthesis of ammonia from dinit...

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Main Authors: Lan-lan Yu, Jiang-zhou Qin, Wen-jun Zhao, Zhi-guang Zhang, Jun Ke, Bao-jun Liu
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2020/5251431
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author Lan-lan Yu
Jiang-zhou Qin
Wen-jun Zhao
Zhi-guang Zhang
Jun Ke
Bao-jun Liu
author_facet Lan-lan Yu
Jiang-zhou Qin
Wen-jun Zhao
Zhi-guang Zhang
Jun Ke
Bao-jun Liu
author_sort Lan-lan Yu
collection DOAJ
description As an important chemical raw material, ammonia is mainly produced by the traditional Haber-Bosch process, which has certain limitations such as high energy consumption, high safety responsibility, and severe pollution, thereby having negative impacts on ecosystem. The synthesis of ammonia from dinitrogen at ambient temperature and pressure is one of the most attractive topics in the field of chemistry. As a new two-dimensional nanomaterial, MXene has excellent electrochemical properties and is a potential catalytic material for electrocatalytic nitrogen fixation. In this review, we firstly introduce the crystal, electronic structures of two-dimensional MXenes and summarize the synthesis methods, N2 reduction, and simulation computation, as well as have insight into the challenges of MXenes, which shed light on the development of highly efficient MXene-based electrocatalysts in the reduction of N2 to ammonia.
format Article
id doaj-art-c68b9030a607483280ac88144c154bff
institution Kabale University
issn 1110-662X
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language English
publishDate 2020-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-c68b9030a607483280ac88144c154bff2025-02-03T06:04:37ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2020-01-01202010.1155/2020/52514315251431Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to AmmoniaLan-lan Yu0Jiang-zhou Qin1Wen-jun Zhao2Zhi-guang Zhang3Jun Ke4Bao-jun Liu5College of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, ChinaCollege of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, ChinaCollege of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, ChinaSchool of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, ChinaSchool of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, ChinaCollege of Resource and Environmental Engineering, Guizhou University, Guiyang 550025, ChinaAs an important chemical raw material, ammonia is mainly produced by the traditional Haber-Bosch process, which has certain limitations such as high energy consumption, high safety responsibility, and severe pollution, thereby having negative impacts on ecosystem. The synthesis of ammonia from dinitrogen at ambient temperature and pressure is one of the most attractive topics in the field of chemistry. As a new two-dimensional nanomaterial, MXene has excellent electrochemical properties and is a potential catalytic material for electrocatalytic nitrogen fixation. In this review, we firstly introduce the crystal, electronic structures of two-dimensional MXenes and summarize the synthesis methods, N2 reduction, and simulation computation, as well as have insight into the challenges of MXenes, which shed light on the development of highly efficient MXene-based electrocatalysts in the reduction of N2 to ammonia.http://dx.doi.org/10.1155/2020/5251431
spellingShingle Lan-lan Yu
Jiang-zhou Qin
Wen-jun Zhao
Zhi-guang Zhang
Jun Ke
Bao-jun Liu
Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to Ammonia
International Journal of Photoenergy
title Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to Ammonia
title_full Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to Ammonia
title_fullStr Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to Ammonia
title_full_unstemmed Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to Ammonia
title_short Advances in Two-Dimensional MXenes for Nitrogen Electrocatalytic Reduction to Ammonia
title_sort advances in two dimensional mxenes for nitrogen electrocatalytic reduction to ammonia
url http://dx.doi.org/10.1155/2020/5251431
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AT wenjunzhao advancesintwodimensionalmxenesfornitrogenelectrocatalyticreductiontoammonia
AT zhiguangzhang advancesintwodimensionalmxenesfornitrogenelectrocatalyticreductiontoammonia
AT junke advancesintwodimensionalmxenesfornitrogenelectrocatalyticreductiontoammonia
AT baojunliu advancesintwodimensionalmxenesfornitrogenelectrocatalyticreductiontoammonia