pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significance

Oral drug delivery systems designed for antitumor drug administration in colorectal cancer treatment encounter substantial challenges regarding effective delivery, controlled release, and intestinal microbiota homeostasis. In this study, dual-stimulation (pH + magnetic) responsive chitosan nanoparti...

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Main Authors: Songlin Guo, Xia Qiao, Lu Ding, Jiayue Liu, Yanan Xu, Jia Cao, Weidong Tian, Duan Ma, Xu Zhang, Bingren Tian
Format: Article
Language:English
Published: Elsevier 2025-10-01
Series:Materials Today Bio
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590006425007215
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author Songlin Guo
Xia Qiao
Lu Ding
Jiayue Liu
Yanan Xu
Jia Cao
Weidong Tian
Duan Ma
Xu Zhang
Bingren Tian
author_facet Songlin Guo
Xia Qiao
Lu Ding
Jiayue Liu
Yanan Xu
Jia Cao
Weidong Tian
Duan Ma
Xu Zhang
Bingren Tian
author_sort Songlin Guo
collection DOAJ
description Oral drug delivery systems designed for antitumor drug administration in colorectal cancer treatment encounter substantial challenges regarding effective delivery, controlled release, and intestinal microbiota homeostasis. In this study, dual-stimulation (pH + magnetic) responsive chitosan nanoparticles (Fe3O4/chitosan (CS)/TPP) loaded with hops β-acids were synthesized for colorectal cancer treatment. In vitro experiments revealed that the fabricated nanoparticles demonstrated sizes ranging from 233 to 381 nm, with zeta potential values exceeding 10 mV. Release studies indicated that β-acids release was pH-dependent. Notably, the β-acids-loaded nanoparticles proved antimicrobial activity through membrane protein interactions. Cell proliferation assays confirmed that these nanoparticles effectively eliminated HCT116 cells while showing minimal toxicity toward NCM460 cells. Following oral administration to mice with in situ colorectal cancer, histopathological evaluation demonstrated that the nanoparticles induced apoptosis at the tumor site, leading to reduced tumor growth. Additionally, the drug-loaded nanoparticles showed enhanced antitumor efficacy compared to free 5-FU. The findings suggest that these nanoparticles significantly increase beneficial bacterial populations while decreasing levels of harmful bacteria. These dual-function nanoparticles, which exhibit both chemotherapeutic and antimicrobial properties, present a promising novel strategy for treating colorectal cancer.
format Article
id doaj-art-c63ad20fc6cf420db037f5f244e1ef3f
institution Kabale University
issn 2590-0064
language English
publishDate 2025-10-01
publisher Elsevier
record_format Article
series Materials Today Bio
spelling doaj-art-c63ad20fc6cf420db037f5f244e1ef3f2025-08-20T03:38:59ZengElsevierMaterials Today Bio2590-00642025-10-013410215110.1016/j.mtbio.2025.102151pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significanceSonglin Guo0Xia Qiao1Lu Ding2Jiayue Liu3Yanan Xu4Jia Cao5Weidong Tian6Duan Ma7Xu Zhang8Bingren Tian9Surgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, ChinaSurgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, ChinaSurgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, ChinaState Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences, University of Macau, Macao, ChinaSurgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, ChinaSurgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, ChinaState Key Laboratory of Genetic Engineering and Collaborative Innovation Center for Genetics and Development, School of Life Sciences, Fudan University, Shanghai, China; Corresponding author.Surgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, China; Department of Biochemistry and Molecular Biology, Research Center for Birth Defects, Institutes of Biomedical Sciences, Key Laboratory of Metabolism and Molecular Medicine, Ministry of Education, School of Basic Medical Sciences, Fudan University, Shanghai, China; Corresponding author.Surgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, China; Corresponding author.Surgery Laboratory, Institute of Medical Sciences, General Hospital of Ningxia Medical University, Yinchuan, Ningxia, China; Corresponding author.Oral drug delivery systems designed for antitumor drug administration in colorectal cancer treatment encounter substantial challenges regarding effective delivery, controlled release, and intestinal microbiota homeostasis. In this study, dual-stimulation (pH + magnetic) responsive chitosan nanoparticles (Fe3O4/chitosan (CS)/TPP) loaded with hops β-acids were synthesized for colorectal cancer treatment. In vitro experiments revealed that the fabricated nanoparticles demonstrated sizes ranging from 233 to 381 nm, with zeta potential values exceeding 10 mV. Release studies indicated that β-acids release was pH-dependent. Notably, the β-acids-loaded nanoparticles proved antimicrobial activity through membrane protein interactions. Cell proliferation assays confirmed that these nanoparticles effectively eliminated HCT116 cells while showing minimal toxicity toward NCM460 cells. Following oral administration to mice with in situ colorectal cancer, histopathological evaluation demonstrated that the nanoparticles induced apoptosis at the tumor site, leading to reduced tumor growth. Additionally, the drug-loaded nanoparticles showed enhanced antitumor efficacy compared to free 5-FU. The findings suggest that these nanoparticles significantly increase beneficial bacterial populations while decreasing levels of harmful bacteria. These dual-function nanoparticles, which exhibit both chemotherapeutic and antimicrobial properties, present a promising novel strategy for treating colorectal cancer.http://www.sciencedirect.com/science/article/pii/S2590006425007215ChitosanHops β-acidsFe3O4pH+magnetic nanoparticleAntibacterialColorectal cancer
spellingShingle Songlin Guo
Xia Qiao
Lu Ding
Jiayue Liu
Yanan Xu
Jia Cao
Weidong Tian
Duan Ma
Xu Zhang
Bingren Tian
pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significance
Materials Today Bio
Chitosan
Hops β-acids
Fe3O4
pH+magnetic nanoparticle
Antibacterial
Colorectal cancer
title pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significance
title_full pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significance
title_fullStr pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significance
title_full_unstemmed pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significance
title_short pH-responsive magnetic Fe3O4 modified chitosan nanoparticles loaded with β-acids to improve colorectal cancer treatmentStatement of significance
title_sort ph responsive magnetic fe3o4 modified chitosan nanoparticles loaded with β acids to improve colorectal cancer treatmentstatement of significance
topic Chitosan
Hops β-acids
Fe3O4
pH+magnetic nanoparticle
Antibacterial
Colorectal cancer
url http://www.sciencedirect.com/science/article/pii/S2590006425007215
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