Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structure
Data concerning the synthesis, IR-spectra, and single crystal X-ray studies for neodymium iodide and gadolinium iodide - thiourea complexes of the general composition [Ln(H2O)9]I3 · 2CS(NH2)2 (Ln = Nd, Gd) are presented. It has been demonstrated that in the solid state the title compounds are compos...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | Russian |
| Published: |
MIREA - Russian Technological University
2010-06-01
|
| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/969 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1849253194705666048 |
|---|---|
| author | L. Yu. Alikberova D. V. Albov T. A. Antonenko I. M. Kochetova N. S. Rukk |
| author_facet | L. Yu. Alikberova D. V. Albov T. A. Antonenko I. M. Kochetova N. S. Rukk |
| author_sort | L. Yu. Alikberova |
| collection | DOAJ |
| description | Data concerning the synthesis, IR-spectra, and single crystal X-ray studies for neodymium iodide and gadolinium iodide - thiourea complexes of the general composition [Ln(H2O)9]I3 · 2CS(NH2)2 (Ln = Nd, Gd) are presented. It has been demonstrated that in the solid state the title compounds are composed from [Ln(H2O)9]3+cations (polyhedron: monocapped tetragonal antiprism) as well as from non-coordinated thiourea molecules and iodide ions. Due to hydrogen bond formation mutually perpendicular flat molecules of thiourea are combined into goffered layers, nonaaquacations of lanthanides and iodide-ions being located in the cavities between these layers. The existence of hydrogen bonding between the mentioned species has been underlined. |
| format | Article |
| id | doaj-art-c627483687c944ae8e7be882a5be6146 |
| institution | Kabale University |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2010-06-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-c627483687c944ae8e7be882a5be61462025-08-20T03:56:24ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752010-06-01533033963Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structureL. Yu. Alikberova0D. V. Albov1T. A. Antonenko2I. M. Kochetova3N. S. Rukk4МИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86МГУ им. М.В. ЛомоносоваМИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86МИТХТ им. М.В. Ломоносова, 119571, Москва, пр-т Вернадского, д. 86M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571Data concerning the synthesis, IR-spectra, and single crystal X-ray studies for neodymium iodide and gadolinium iodide - thiourea complexes of the general composition [Ln(H2O)9]I3 · 2CS(NH2)2 (Ln = Nd, Gd) are presented. It has been demonstrated that in the solid state the title compounds are composed from [Ln(H2O)9]3+cations (polyhedron: monocapped tetragonal antiprism) as well as from non-coordinated thiourea molecules and iodide ions. Due to hydrogen bond formation mutually perpendicular flat molecules of thiourea are combined into goffered layers, nonaaquacations of lanthanides and iodide-ions being located in the cavities between these layers. The existence of hydrogen bonding between the mentioned species has been underlined.https://www.finechem-mirea.ru/jour/article/view/969neodymium(iii) iodidegadolinium(iii) iodidethioureacomplexescrystal structureir spectrasynthesis |
| spellingShingle | L. Yu. Alikberova D. V. Albov T. A. Antonenko I. M. Kochetova N. S. Rukk Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structure Тонкие химические технологии neodymium(iii) iodide gadolinium(iii) iodide thiourea complexes crystal structure ir spectra synthesis |
| title | Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structure |
| title_full | Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structure |
| title_fullStr | Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structure |
| title_full_unstemmed | Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structure |
| title_short | Thiourea complexes of neodymium(III) and gadolinium(III) iodides. synthesis and structure |
| title_sort | thiourea complexes of neodymium iii and gadolinium iii iodides synthesis and structure |
| topic | neodymium(iii) iodide gadolinium(iii) iodide thiourea complexes crystal structure ir spectra synthesis |
| url | https://www.finechem-mirea.ru/jour/article/view/969 |
| work_keys_str_mv | AT lyualikberova thioureacomplexesofneodymiumiiiandgadoliniumiiiiodidessynthesisandstructure AT dvalbov thioureacomplexesofneodymiumiiiandgadoliniumiiiiodidessynthesisandstructure AT taantonenko thioureacomplexesofneodymiumiiiandgadoliniumiiiiodidessynthesisandstructure AT imkochetova thioureacomplexesofneodymiumiiiandgadoliniumiiiiodidessynthesisandstructure AT nsrukk thioureacomplexesofneodymiumiiiandgadoliniumiiiiodidessynthesisandstructure |