Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MD

At present, when CFD method is used to predict surface heat flux, it is generally assumed that the wall condition is full-catalytic wall or non-catalytic wall. Heat flux prediction can be greatly affected by different wall catalytic conditions, and a more reasonable numerical solution can be obtaine...

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Main Authors: Jiahao SONG, Fan MO, Zhenxun GAO
Format: Article
Language:zho
Published: China Astronautic Publishing CO., LTD. ; Editorial Office of Physics of Gases 2024-11-01
Series:气体物理
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Online Access:http://qtwl.xml-journal.net/cn/article/doi/10.19527/j.cnki.2096-1642.1110
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author Jiahao SONG
Fan MO
Zhenxun GAO
author_facet Jiahao SONG
Fan MO
Zhenxun GAO
author_sort Jiahao SONG
collection DOAJ
description At present, when CFD method is used to predict surface heat flux, it is generally assumed that the wall condition is full-catalytic wall or non-catalytic wall. Heat flux prediction can be greatly affected by different wall catalytic conditions, and a more reasonable numerical solution can be obtained by using finite-rate catalytic model. However, due to the nonlinear, nonequilibrium, and multiscale characteristics of the catalytic recombination process of high-enthalpy chemical reaction flows on material surfaces, it is extremely difficult to accurately describe the finite-rate catalytic model. In this paper, a finite-rate catalytic model describing the interaction of O and N atoms with SiO2 surface was constructed by ReaxFF-molecular dynamics method based on the theory and simulation at the microscale. The reentry flow fields of space shuttle orbiter under different catalytic conditions were calculated and compared. The results show that the predicted heat flux of the finite-rate catalytic model agrees well with the flight test data of STS-3 in the altitude range of 70.1 km to 57.8 km, and the model has a certain degree of accuracy.
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id doaj-art-c5530fd3da9540239d4b45a0438138dc
institution OA Journals
issn 2096-1642
language zho
publishDate 2024-11-01
publisher China Astronautic Publishing CO., LTD. ; Editorial Office of Physics of Gases
record_format Article
series 气体物理
spelling doaj-art-c5530fd3da9540239d4b45a0438138dc2025-08-20T02:01:25ZzhoChina Astronautic Publishing CO., LTD. ; Editorial Office of Physics of Gases气体物理2096-16422024-11-0196344510.19527/j.cnki.2096-1642.1110qtwl-9-6-34Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MDJiahao SONG0Fan MO1Zhenxun GAO2Guangdong Aerospace Research Academy(Nansha), Guangzhou 511458, ChinaSchool of Aeronautic Science and Engineering, Beihang University, Beijing 100191, ChinaSchool of Aeronautic Science and Engineering, Beihang University, Beijing 100191, ChinaAt present, when CFD method is used to predict surface heat flux, it is generally assumed that the wall condition is full-catalytic wall or non-catalytic wall. Heat flux prediction can be greatly affected by different wall catalytic conditions, and a more reasonable numerical solution can be obtained by using finite-rate catalytic model. However, due to the nonlinear, nonequilibrium, and multiscale characteristics of the catalytic recombination process of high-enthalpy chemical reaction flows on material surfaces, it is extremely difficult to accurately describe the finite-rate catalytic model. In this paper, a finite-rate catalytic model describing the interaction of O and N atoms with SiO2 surface was constructed by ReaxFF-molecular dynamics method based on the theory and simulation at the microscale. The reentry flow fields of space shuttle orbiter under different catalytic conditions were calculated and compared. The results show that the predicted heat flux of the finite-rate catalytic model agrees well with the flight test data of STS-3 in the altitude range of 70.1 km to 57.8 km, and the model has a certain degree of accuracy.http://qtwl.xml-journal.net/cn/article/doi/10.19527/j.cnki.2096-1642.1110hypersonicchemical nonequilibriumfinite-rate catalysisreaxff-md
spellingShingle Jiahao SONG
Fan MO
Zhenxun GAO
Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MD
气体物理
hypersonic
chemical nonequilibrium
finite-rate catalysis
reaxff-md
title Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MD
title_full Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MD
title_fullStr Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MD
title_full_unstemmed Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MD
title_short Numerical Simulation of Finite-Rate Catalytic Model Based on ReaxFF-MD
title_sort numerical simulation of finite rate catalytic model based on reaxff md
topic hypersonic
chemical nonequilibrium
finite-rate catalysis
reaxff-md
url http://qtwl.xml-journal.net/cn/article/doi/10.19527/j.cnki.2096-1642.1110
work_keys_str_mv AT jiahaosong numericalsimulationoffiniteratecatalyticmodelbasedonreaxffmd
AT fanmo numericalsimulationoffiniteratecatalyticmodelbasedonreaxffmd
AT zhenxungao numericalsimulationoffiniteratecatalyticmodelbasedonreaxffmd