Design of a chiral molecular pocket in a Ni(II) complex to improve stereoselectivity in the kinetic resolution of racemic epoxides with CO2

Design of a chiral molecular pocket in a Ni(II) complex to improve stereoselectivity in the kinetic resolution of racemic epoxides with CO2

The kinetic resolution of racemic epoxides using the carbon dioxide (CO2) molecule is of significant practical interest because the reaction yields the valuable products – enantiomerically enriched cyclic carbonates (1,3-dioxolan-2-ones), along with the remaining opposite enantiomer of the epoxide....

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Bibliographic Details
Main Authors: Mikhail A. Emelyanov, Alexander V. Bachinskiy, Yana V. Derkach, Vasiliy A. Chaliy, Alexander F. Smol'yakov, Michael G. Medvedev, Aleksei A. Titov, Victor I. Maleev, Vladimir A. Larionov
Format: Article
Language:English
Published: Elsevier 2024-12-01
Series:Tetrahedron Chem
Subjects:
Kinetic resolution
Carbon dioxide fixation
Chiral nickel(II) complex
Epoxide
Cyclic carbonate
Online Access:http://www.sciencedirect.com/science/article/pii/S2666951X24000548
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