Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature Review

Geopolymers are prepared by alkali solution-activated natural minerals or industrial waste materials, which have been widely used as new sustainable building and construction materials for their excellent thermal and mechanical properties. The thermal and mechanical properties of geopolymers at high...

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Main Authors: Rui He, Nan Dai, Zhenjun Wang
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2020/7532703
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author Rui He
Nan Dai
Zhenjun Wang
author_facet Rui He
Nan Dai
Zhenjun Wang
author_sort Rui He
collection DOAJ
description Geopolymers are prepared by alkali solution-activated natural minerals or industrial waste materials, which have been widely used as new sustainable building and construction materials for their excellent thermal and mechanical properties. The thermal and mechanical properties of geopolymers at high temperature have attracted great attention from many researchers. However, there are few systematic works concerning these two issues. Therefore, this work reviewed the thermal and mechanical behaviors of geopolymers at high temperature. Firstly, the thermal properties of geopolymers in terms of mass loss, thermal expansion, and thermal conductivity after high temperature were explained. Secondly, the mechanical properties of residual compressive strength and stress-strain relationship of fly ash geopolymers and metakaolin geopolymers after high temperature were analyzed. Finally, the microstructure and mineralogical characteristics of geopolymers upon heating were interpreted according to the changes of microstructures and compositions. The results show that the thermal properties of geopolymers are superior to cement concrete. The geopolymers possess few mass loss and a low expansion ratio and thermal conductivity at high temperature. The thermal and mechanical properties of the geopolymers are usually closely related to the raw materials and the constituents of the geopolymers. Preparation and testing conditions can affect the mechanical properties of the geopolymers. The stress-strain curves of geopolymer are changed by the composition of geopolymers and the high temperature. The silicon-type fillers not only improve the thermal expansion of the geopolymers but also enhance mechanical properties of the geopolymers. But, they do not contribute to reducing the thermal conductivity. the different raw materials, aluminosilicate precursor and reinforcement materials, result in different geopolymer damage during the heating. However, phase transitions can occur during the process of heating regardless of the raw materials. The additional performance enhancements can be achieved by optimizing the paste formulation, adjusting the inner structure, changing the alkali type, and incorporating reinforcements.
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spelling doaj-art-c4a7d3424183456c83a84f91cae8dee22025-08-20T03:23:06ZengWileyAdvances in Civil Engineering1687-80861687-80942020-01-01202010.1155/2020/75327037532703Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature ReviewRui He0Nan Dai1Zhenjun Wang2School of Materials Science and Engineering, Chang’an University, Xi’an 710061, ChinaSchool of Materials Science and Engineering, Chang’an University, Xi’an 710061, ChinaSchool of Materials Science and Engineering, Chang’an University, Xi’an 710061, ChinaGeopolymers are prepared by alkali solution-activated natural minerals or industrial waste materials, which have been widely used as new sustainable building and construction materials for their excellent thermal and mechanical properties. The thermal and mechanical properties of geopolymers at high temperature have attracted great attention from many researchers. However, there are few systematic works concerning these two issues. Therefore, this work reviewed the thermal and mechanical behaviors of geopolymers at high temperature. Firstly, the thermal properties of geopolymers in terms of mass loss, thermal expansion, and thermal conductivity after high temperature were explained. Secondly, the mechanical properties of residual compressive strength and stress-strain relationship of fly ash geopolymers and metakaolin geopolymers after high temperature were analyzed. Finally, the microstructure and mineralogical characteristics of geopolymers upon heating were interpreted according to the changes of microstructures and compositions. The results show that the thermal properties of geopolymers are superior to cement concrete. The geopolymers possess few mass loss and a low expansion ratio and thermal conductivity at high temperature. The thermal and mechanical properties of the geopolymers are usually closely related to the raw materials and the constituents of the geopolymers. Preparation and testing conditions can affect the mechanical properties of the geopolymers. The stress-strain curves of geopolymer are changed by the composition of geopolymers and the high temperature. The silicon-type fillers not only improve the thermal expansion of the geopolymers but also enhance mechanical properties of the geopolymers. But, they do not contribute to reducing the thermal conductivity. the different raw materials, aluminosilicate precursor and reinforcement materials, result in different geopolymer damage during the heating. However, phase transitions can occur during the process of heating regardless of the raw materials. The additional performance enhancements can be achieved by optimizing the paste formulation, adjusting the inner structure, changing the alkali type, and incorporating reinforcements.http://dx.doi.org/10.1155/2020/7532703
spellingShingle Rui He
Nan Dai
Zhenjun Wang
Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature Review
Advances in Civil Engineering
title Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature Review
title_full Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature Review
title_fullStr Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature Review
title_full_unstemmed Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature Review
title_short Thermal and Mechanical Properties of Geopolymers Exposed to High Temperature: A Literature Review
title_sort thermal and mechanical properties of geopolymers exposed to high temperature a literature review
url http://dx.doi.org/10.1155/2020/7532703
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AT nandai thermalandmechanicalpropertiesofgeopolymersexposedtohightemperaturealiteraturereview
AT zhenjunwang thermalandmechanicalpropertiesofgeopolymersexposedtohightemperaturealiteraturereview