New Aspects of Polymer Characterization by Dynamic Light Scattering

Can macromolecules be seen moving? No doubt, twenty years ago the answer would have been a definite «No». Today we are more inclined to answer positively, assuming we accept the observation of scattered light as a kind of seeing. The new capability of watching the motion of molecules, without exert...

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Main Author: Walther Burchard
Format: Article
Language:deu
Published: Swiss Chemical Society 1985-01-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9640
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author Walther Burchard
author_facet Walther Burchard
author_sort Walther Burchard
collection DOAJ
description Can macromolecules be seen moving? No doubt, twenty years ago the answer would have been a definite «No». Today we are more inclined to answer positively, assuming we accept the observation of scattered light as a kind of seeing. The new capability of watching the motion of molecules, without exerting an external force on the system, is a typical feature of our time with its high technology in electronics and the construction of fast digital computers. Once the new technique was understood, the various aspects and possibilities were immediately anticipated by scientists. These ideas remained fairly speculative for several years, but now a stage has been reached where some of the experiments suggested earlier have since been tested and where further applications can be foreseen. Most exciting is probably the prospect of determining viscoelastic properties in some favourable cases. The present article provides an introduction to the principles of this fairly new technique. The power of the method is illustrated by two simple examples and, finally, some problems of practical interest are discussed.
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spelling doaj-art-c4a1ba1fcb0d4f6fbc1349ba2f43c41d2025-08-20T02:20:26ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241985-01-0139110.2533/chimia.1985.10New Aspects of Polymer Characterization by Dynamic Light ScatteringWalther Burchard0Institut für Makromolekulare Chemie der Universität Stefan-Meier-Strasse 31, D-7800 Freiburg i.Br. (Bundesrepublik Deutschland) Can macromolecules be seen moving? No doubt, twenty years ago the answer would have been a definite «No». Today we are more inclined to answer positively, assuming we accept the observation of scattered light as a kind of seeing. The new capability of watching the motion of molecules, without exerting an external force on the system, is a typical feature of our time with its high technology in electronics and the construction of fast digital computers. Once the new technique was understood, the various aspects and possibilities were immediately anticipated by scientists. These ideas remained fairly speculative for several years, but now a stage has been reached where some of the experiments suggested earlier have since been tested and where further applications can be foreseen. Most exciting is probably the prospect of determining viscoelastic properties in some favourable cases. The present article provides an introduction to the principles of this fairly new technique. The power of the method is illustrated by two simple examples and, finally, some problems of practical interest are discussed. https://www.chimia.ch/chimia/article/view/9640
spellingShingle Walther Burchard
New Aspects of Polymer Characterization by Dynamic Light Scattering
CHIMIA
title New Aspects of Polymer Characterization by Dynamic Light Scattering
title_full New Aspects of Polymer Characterization by Dynamic Light Scattering
title_fullStr New Aspects of Polymer Characterization by Dynamic Light Scattering
title_full_unstemmed New Aspects of Polymer Characterization by Dynamic Light Scattering
title_short New Aspects of Polymer Characterization by Dynamic Light Scattering
title_sort new aspects of polymer characterization by dynamic light scattering
url https://www.chimia.ch/chimia/article/view/9640
work_keys_str_mv AT waltherburchard newaspectsofpolymercharacterizationbydynamiclightscattering