Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based Films

Hole-doped manganese oxides exhibit a gigantic negative magnetoresistance, referred to as colossal magnetoresistance (CMR), owing to the interplay between double-exchange (DE) ferromagnetic metal and charge-ordered antiferromagnetic insulator/semiconductor phases. Magnetoresistive manganites display...

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Main Authors: Navjyoti Boora, Rafiq Ahmad, Shafaque Rahman, Nguyen Quoc Dung, Akil Ahmad, Mohammed B. Alshammari, Byeong-Il Lee
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Magnetochemistry
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Online Access:https://www.mdpi.com/2312-7481/11/1/5
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author Navjyoti Boora
Rafiq Ahmad
Shafaque Rahman
Nguyen Quoc Dung
Akil Ahmad
Mohammed B. Alshammari
Byeong-Il Lee
author_facet Navjyoti Boora
Rafiq Ahmad
Shafaque Rahman
Nguyen Quoc Dung
Akil Ahmad
Mohammed B. Alshammari
Byeong-Il Lee
author_sort Navjyoti Boora
collection DOAJ
description Hole-doped manganese oxides exhibit a gigantic negative magnetoresistance, referred to as colossal magnetoresistance (CMR), owing to the interplay between double-exchange (DE) ferromagnetic metal and charge-ordered antiferromagnetic insulator/semiconductor phases. Magnetoresistive manganites display a sharp resistivity drop at the metal–insulator transition temperature (T<sup>MI</sup>). CMR effects in perovskite manganites, specifically La<sub>0.67</sub>Ca<sub>0.33</sub>MnO<sub>3</sub> (La-Ca-Mn-O or LCMO), have been extensively investigated. This review paper provides a comprehensive introduction to the crystallographic structure, as well as the electronic and magnetic properties, of LCMO films. Furthermore, we delve into a detailed discussion of the effects of epitaxial strain induced by different substrates on LCMO films. Additionally, we review the early findings and diverse applications of LCMO thin films. Finally, we outline potential challenges and prospects for achieving superior LCMO film properties.
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institution Kabale University
issn 2312-7481
language English
publishDate 2025-01-01
publisher MDPI AG
record_format Article
series Magnetochemistry
spelling doaj-art-c47f2311d83c4e83922cc219847ff0902025-01-24T13:39:24ZengMDPI AGMagnetochemistry2312-74812025-01-01111510.3390/magnetochemistry11010005Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based FilmsNavjyoti Boora0Rafiq Ahmad1Shafaque Rahman2Nguyen Quoc Dung3Akil Ahmad4Mohammed B. Alshammari5Byeong-Il Lee6Centre for Nanoscience and Nanotechnology, Jamia Millia Islamia, New Delhi 110025, India‘New-Senior’ Oriented Smart Health Care Education Center, Pukyong National University, Busan 48513, Republic of KoreaCentre for Nanoscience and Nanotechnology, Jamia Millia Islamia, New Delhi 110025, IndiaIndustry 4.0 Convergence Bionics Engineering, Pukyong National University, Busan 48513, Republic of KoreaDepartment of Chemistry, College of Science and Humanities in Al-Kharj, Prince Sattam Bin Abdulaziz University, Al-Kharj 11942, Saudi ArabiaDepartment of Chemistry, College of Science and Humanities in Al-Kharj, Prince Sattam Bin Abdulaziz University, Al-Kharj 11942, Saudi ArabiaIndustry 4.0 Convergence Bionics Engineering, Pukyong National University, Busan 48513, Republic of KoreaHole-doped manganese oxides exhibit a gigantic negative magnetoresistance, referred to as colossal magnetoresistance (CMR), owing to the interplay between double-exchange (DE) ferromagnetic metal and charge-ordered antiferromagnetic insulator/semiconductor phases. Magnetoresistive manganites display a sharp resistivity drop at the metal–insulator transition temperature (T<sup>MI</sup>). CMR effects in perovskite manganites, specifically La<sub>0.67</sub>Ca<sub>0.33</sub>MnO<sub>3</sub> (La-Ca-Mn-O or LCMO), have been extensively investigated. This review paper provides a comprehensive introduction to the crystallographic structure, as well as the electronic and magnetic properties, of LCMO films. Furthermore, we delve into a detailed discussion of the effects of epitaxial strain induced by different substrates on LCMO films. Additionally, we review the early findings and diverse applications of LCMO thin films. Finally, we outline potential challenges and prospects for achieving superior LCMO film properties.https://www.mdpi.com/2312-7481/11/1/5La-Ca-Mn-Othin filmsmanganitemagnetron sputteringcolossal magnetoresistance
spellingShingle Navjyoti Boora
Rafiq Ahmad
Shafaque Rahman
Nguyen Quoc Dung
Akil Ahmad
Mohammed B. Alshammari
Byeong-Il Lee
Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based Films
Magnetochemistry
La-Ca-Mn-O
thin films
manganite
magnetron sputtering
colossal magnetoresistance
title Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based Films
title_full Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based Films
title_fullStr Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based Films
title_full_unstemmed Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based Films
title_short Recent Advances of Colossal Magnetoresistance in Versatile La-Ca-Mn-O Material-Based Films
title_sort recent advances of colossal magnetoresistance in versatile la ca mn o material based films
topic La-Ca-Mn-O
thin films
manganite
magnetron sputtering
colossal magnetoresistance
url https://www.mdpi.com/2312-7481/11/1/5
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